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Recent experiments have observed that the chemical and photophysical properties of molecules can be modified inside an optical Fabry-Perot microcavity under collective vibrational strong coupling (VSC) conditions, and such modification is…

Mesoscale and Nanoscale Physics · Physics 2021-03-09 Tao E. Li , Abraham Nitzan , Joseph E. Subotnik

The simple resonant Rabi oscillation of a two-level system in a single-mode coherent field reveals complex features at the mesoscopic scale, with oscillation collapses and revivals. Using slow circular Rydberg atoms interacting with a…

Quantum Physics · Physics 2019-10-09 F. Assemat , D. Grosso , A. Signoles , A. Facon , I. Dotsenko , S. Haroche , J. M. Raimond , M. Brune , S. Gleyzes

We develop the theoretical formalism to calculate second-order correlations in dissipative exciton-polariton system and we propose intensity-intensity correlation experiments to reveal the physics of exciton-light coupling in semiconductor…

Mesoscale and Nanoscale Physics · Physics 2016-04-01 Yuri G. Rubo , Alexandra Sheremet , Alexey Kavokin

We report the experimental study of a hybrid quantum solid state system comprising two-level artificial atoms coupled to cavity confined optical and vibrational modes. In this system combining cavity quantum electrodynamics and cavity…

When internal states of atoms are manipulated using coherent optical or radio-frequency (RF) radiation, it is essential to know the polarization of the radiation with respect to the quantization axis of the atom. We first present a…

Atomic Physics · Physics 2017-06-28 J. Koepsell , T. Thiele , J. Deiglmayr , A. Wallraff , F. Merkt

We study the two-qubit asymmetric quantum Rabi model (AQRM) and find its dark-state solution. Such solutions have at most one photon and constant eigenenergy in the whole coupling regime, causing level crossings in the spectrum, although…

Quantum Physics · Physics 2024-06-11 Ze-Feng Lei , Junlong Tian , Jie Peng

We present a microscopic theory for nonlinear optical spectroscopy of N molecules in an optical cavity. A quantum Langevin analytical expression is derived for the time- and frequency-resolved signals accounting for arbitrary numbers of…

Quantum Physics · Physics 2023-03-29 Zhedong Zhang , Xiaoyu Nie , Dangyuan Lei , Shaul Mukame

Dressing quantum states of matter with virtual photons can create exotic effects ranging from vacuum-field modified transport to polaritonic chemistry, and may drive strong squeezing or entanglement of light and matter modes. The…

Quantum Physics · Physics 2023-09-14 J. Mornhinweg , L. Diebel , M. Halbhuber , M. Prager , J. Riepl , T. Inzenhofer , D. Bougeard , R. Huber , C. Lange

We propose free-electron Rabi oscillation by creating an isolated two-level system in a synthetic energy space induced by laser. The {\pi}/2-pulse and {\pi}-pulse in synthetic Rabi dynamics can function as 'beam splitters' and 'mirrors' for…

Quantum Physics · Physics 2023-04-25 Yiming Pan , Bin Zhang , Daniel Podolsky

We report the first experimental two-dimensional infrared (2D IR) spectra of novel molecular photonic excitations - vibrational-polaritons. The application of advanced 2D IR spectroscopy onto novel vibrational-polariton challenges and…

Systems of strongly interacting atoms and photons, that can be realized wiring up individual cavity QED systems into lattices, are perceived as a new platform for quantum simulation. While sharing important properties with other systems of…

Other Condensed Matter · Physics 2012-11-07 M. Schiró , M. Bordyuh , B. Öztop , H. E. Türeci

The 1996 Brune {\it et al.} experiment on vacuum Rabi oscillation is analyzed by means of alternative models of atom-reservoir interaction. Agreement with experimental Rabi oscillation data can be obtained if one defines jump operators in…

Quantum Physics · Physics 2009-12-08 Marcin Wilczewski , Marek Czachor

The rate of non-radiative decay between two molecular electronic states is succinctly described by the energy gap law, which suggests an approximately-exponential dependence of the rate on the electronic energy gap. Here, we inquire whether…

Chemical Physics · Physics 2023-04-14 Yong Rui Poh , Sindhana Pannir-Sivajothi , Joel Yuen-Zhou

The experimental access to ultra-strong couplings in light-matter interactions has made the quantum phase transition (QPT) in the quantum Rabi model practically relevant, while the physics of the QPT has not yet been fully explored. The…

Quantum Physics · Physics 2025-12-29 Feng Qiao , Qiu-Yi Chen , Zu-Jian Ying

The strong interaction of individual quantum emitters with resonant cavities is of fundamental interest for understanding light matter interactions. Plasmonic cavities hold the promise of attaining the strong coupling regime even under…

Optics · Physics 2016-06-28 Kotni Santhosh , Ora Bitton , Lev Chuntonov , Gilad Haran

Following our recent numerical study [arXiv:2601.16299 (2026)], we investigate vibrational excitation induced by transient optical driving in molecular ensembles strongly coupled to a cavity mode using the field-driven…

Room temperature cavity quantum electrodynamics with molecular materials in optical cavities offers exciting prospects for controlling electronic, nuclear and photonic degrees of freedom for applications in physics, chemistry and materials…

Quantum Physics · Physics 2025-01-15 Felipe Herrera , William L. Barnes

The quantum dynamics of vibrational polaritonic states arising from the interaction of a bistable molecule with the quantized mode of a Fabry-Perot microcavity is investigated using an asymmetric double-well potential as a simplified…

Chemical Physics · Physics 2024-01-11 Loïse Attal , Florent Calvo , Cyril Falvo , Pascal Parneix

Molecular polaritons arise when molecules interact so strongly with light that they become entangled with each other. This light-matter hybridization alters the chemical and physical properties of the molecular system and allows chemical…

Chemical Physics · Physics 2023-07-28 Tor S. Haugland , John P. Philbin , Tushar K. Ghosh , Ming Chen , Henrik Koch , Prineha Narang

We investigate a granular aluminium quantum circuit with an anharmonicity of the order of its decoherence rate in a 3-dimensional microwave cavity. We perform single qubit-like manipulations such as Rabi oscillations and Ramsey fringes. Our…

Mesoscale and Nanoscale Physics · Physics 2024-01-10 A. Théry , B. Neukelmance , B. Hue , W. Legrand , L. Jarjat , J. Craquelin , M. Villiers , A. Cottet , M. R. Delbecq , T. Kontos