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Within the self-energy embedding theory (SEET) framework, we study coupled cluster Green's function (GFCC) method in two different contexts: as a method to treat either the system or environment present in the embedding construction. Our…

Chemical Physics · Physics 2022-07-05 Avijit Shee , Chia-Nan Yeh , Dominika Zgid

We apply the Green's function coupled cluster singles and doubles (GFCCSD) impurity solver to realistic impurity problems arising for strongly correlated solids within the self-energy embedding theory (SEET) framework. We describe the…

Strongly Correlated Electrons · Physics 2021-05-05 Chia-Nan Yeh , Avijit Shee , Sergei Iskakov , Dominika Zgid

Embedding theories became important approaches used for accurate calculations of both molecules and solids. In these theories, a small chosen subset of orbitals is treated with an accurate method, called an impurity solver, capable of…

Chemical Physics · Physics 2023-03-20 Avijit Shee , Chia-Nan Yeh , Bo Peng , Karol Kowalski , Dominika Zgid

We describe the use of coupled-cluster theory as an impurity solver in dynamical mean-field theory (DMFT) and its cluster extensions. We present numerical results at the level of coupled-cluster theory with single and double excitations…

Strongly Correlated Electrons · Physics 2019-10-01 Tianyu Zhu , Carlos A. Jimenez-Hoyos , James McClain , Timothy C. Berkelbach , Garnet Kin-Lic Chan

We study the single-band Hubbard model under the action of an external magnetic field using the cumulant Green's functions method (CGFM). The starting point of the method is to diagonalize a cluster containing N correlated sites (seed) and…

Strongly Correlated Electrons · Physics 2023-04-12 Renan Lira , Peter Riseborough , Jereson Silva-Valencia , Marcos Figueira

We demonstrate that coupled-cluster singles-and-doubles Green's function (GFCCSD) method is a powerful and prominent tool drawing the electronic band structures and the total energies, which many theoretical techniques struggle to…

Materials Science · Physics 2018-05-29 Yoritaka Furukawa , Taichi Kosugi , Hirofumi Nishi , Yu-ichiro Matsushita

We investigate the ground-state properties of the Anderson single impurity model (finite Coulomb impurity repulsion) with the Coupled Cluster Method. We consider different CCM reference states and approximation schemes and make comparison…

Strongly Correlated Electrons · Physics 2009-06-26 Jin-Jun Liang , Clive Emary , Tobias Brandes

In this study, we introduce a novel approach to coupled-cluster Green's function (CCGF) embedding by seamlessly integrating conventional CCGF theory with the state-of-the-art sub-system embedding sub-algebras coupled cluster (SES-CC)…

Quantum Physics · Physics 2023-12-21 Bo Peng , Karol Kowalski

The Green's function coupled cluster (GFCC) method is a powerful many-body tool for computing the electronic structure of molecular and periodic systems, especially when electrons of the system are strongly correlated. However, for the GFCC…

Computational Physics · Physics 2019-04-18 Bo Peng , Roel Van Beeumen , David B. Williams-Young , Karol Kowalski , Chao Yang

By introducing multipe-site correlation functions, we propose a hierarchical Green function approach, and apply it to study the characteristic properties of a 2D square lattice Hubbard model by solving the equation of motions of a…

Strongly Correlated Electrons · Physics 2018-09-26 Yu-Liang Liu

Coupled cluster Green's function (CCGF) approach has drawn much attention in recent years for targeting the molecular and material electronic structure problems from a many-body perspective in a systematically improvable way. Here, we will…

Chemical Physics · Physics 2021-11-01 Bo Peng , Nicholas P. Bauman , Sahil Gulania , Karol Kowalski

We demonstrate that the effective Hamiltonians obtained with the downfolding procedure based on double unitary coupled cluster (DUCC) ansatz can be used in the context of Greens function coupled cluster (GFCC) formalism to calculate…

Computational Physics · Physics 2020-12-02 Nicholas P Bauman , Bo Peng , Karol Kowalski

We present a molecular extension of our recently proposed Green's function embedding method, interacting-bath dynamical embedding theory (ibDET), for computing charged excitation energies at the $GW$ and EOM-CCSD levels. Starting from…

Chemical Physics · Physics 2026-04-06 Christian Venturella , Jiachen Li , Tianyu Zhu

Green's function methods within many-body perturbation theory provide a general framework for treating electronic correlations in excited states. Here we investigate the cumulant form of the one-electron Green's function based on the…

Chemical Physics · Physics 2021-04-23 F. D. Vila , J. J. Rehr , J. J. Kas , K. Kowalski , B. Peng

The pair-coupled-cluster doubles (pCCD) method has emerged as a viable approach for quantum-chemical studies of strongly correlated systems. Despite its lower formal scaling (O(N$^4$)) compared to other versions of coupled cluster (CC)…

Chemical Physics · Physics 2026-04-17 Rahul Chakraborty , Paweł Tecmer

Using the cumulant Green's functions method (CGFM), we study the single impurity Anderson model (SIAM). The CGFM starting point is a diagonalization of the SIAM Hamiltonian expressed in a semi-chain form, containing N sites, viz., a…

Strongly Correlated Electrons · Physics 2024-09-26 T. M. Sobreira , T. O. Puel , M. A. Manya , S. E. Ulloa , G. B. Martins , J. Silva-Valencia , R. N. Lira , M. S. Figueira

We develop a static quantum embedding scheme that utilizes different levels of approximations to coupled cluster (CC) theory for an active fragment region and its environment. To reduce the computational cost, we solve the local fragment…

Chemical Physics · Physics 2024-11-13 Avijit Shee , Fabian M. Faulstich , Birgitta Whaley , Lin Lin , Martin Head-Gordon

In this study, we have calculated single-electron energy spectra via the Green's function based on the coupled-cluster singles and doubles (GFCCSD) method for isolated atoms from H to Ne. In order to check the accuracy of the GFCCSD method,…

Materials Science · Physics 2018-07-26 Hirofumi Nishi , Taichi Kosugi , Yoritaka Furukawa , Yu-ichiro Matsushita

We study the Hubbard model using the Cellular Dynamical Mean-Field Theory (CDMFT) with quantum Monte Carlo (QMC) simulations. We present the algorithmic details of CDMFT with the Hirsch-Fye QMC method for the solution of the…

Strongly Correlated Electrons · Physics 2009-11-11 B. Kyung , G. Kotliar , A. -M. S. Tremblay

Quantum embedding methods have recently developed significantly to model large molecular structures. This work proposes a novel wave function theory in density functional theory (WTF-in-DFT) embedding scheme based on pair-coupled cluster…

Chemical Physics · Physics 2024-01-10 Rahul Chakraborty , Katharina Boguslawski , Paweł Tecmer
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