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We present a new physical model resolving a long-standing mystery of the power-law distributions of the blinking times in single colloidal quantum dot fluorescence. The model considers the non-radiative relaxation of the exciton through…

Statistical Mechanics · Physics 2009-11-16 Pavel A. Frantsuzov , Sandor Volkan-Kacso , Bolizsar Janko

Intermittent photoluminescence of colloidal core/shell semiconductor nanocrystals of spherical and branched shape was studied under CW-laser excitation. Luminescent multichannel registration system was applied for the fluorescence detection…

Optics · Physics 2011-12-13 A. G. Vitukhnovsky , M. M. Kovalev , V. V. Lidsky , E. M. Khokhlov

Single photon emitters are core building blocks of quantum technologies, with established and emerging applications ranging from quantum computing and communication to metrology and sensing. Regardless of their nature, quantum emitters…

Quantum Physics · Physics 2023-08-28 G. Landry , C. Bradac

We present an unbiased and robust analysis method for power-law blinking statistics in the photoluminescence of single nano-emitters, allowing us to extract both the bright- and dark-state power-law exponents from the emitters' intensity…

Data Analysis, Statistics and Probability · Physics 2015-01-06 J. Houel , Q. T. Doan , T. Cajgfinger , G. Ledoux , D. Amans , A. Aubret , A. Dominjon , S. Ferriol , R. Barbier , M. Nasilowski , E. Lhuillier , B. Dubertret , C. Dujardin , F. Kulzer

We quantify nonergodic and aging behaviors of nanocrystals (or quantum dots) based on stochastic model. Ergodicity breaking is characterized based on time average intensity and time average correlation function, which remain random even in…

Statistical Mechanics · Physics 2007-05-23 Gennady Margolin , Vladimir Protasenko , Masaru Kuno , Eli Barkai

Fluctuations in the fluorescence from macroscopic ensembles of colloidal semiconductor quantum dots have the spectral form of 1/f noise. The measured power spectral density reflects the fluorescence intermittency of individual dots with…

Materials Science · Physics 2009-11-10 Matthew Pelton , David Grier , Philippe Guyot-Sionnest

Single quantum light-emitters are valuable resources for engineered quantum systems. They can function as robust single-photon generators, allow optical control of single spins, provide readout capabilities for atomic-scale sensors, and…

Quantum Physics · Physics 2019-09-04 Jemy Geordy , Lachlan J. Rogers , Cameron M Rogers , Thomas Volz , Alexei Gilchrist

Three models of single colloidal quantum dot emission fluctuations (blinking) based on spectral diffusion were considered analytically and numerically. It was shown that the only one of them, namely the Frantsuzov and Marcus model…

Statistical Mechanics · Physics 2019-07-24 Vladislav K. Busov , Pavel A. Frantsuzov

The observed intermittent light emission from colloidal semiconductor nanocrystals has long been associated with Auger recombination assisted quenching. We test this view by observing transient emission dynamics of CdSe/CdS/ZnS…

Mesoscale and Nanoscale Physics · Physics 2010-02-23 Shamir Rosen , Osip Schwartz , Dan Oron

Semiconductor nano-crystals, known as quantum dots (QDs), have attracted significant attention for their unique fluorescence properties. Under continuous excitation, QDs emit photons with intricate intensity fluctuation: the intensity of…

Applied Physics · Physics 2025-04-28 Xin Yang , Hawi Nyiera , Yonglei Sun , Jing Zhao , Kun Chen

Colloidal semiconductor quantum dots (QDs) are excellent luminescent nanomaterials for a broad range of optoelectronic applications. Their photoluminescence blinking, however, hinders their practical use in many aspects. It has been shown…

Optics · Physics 2024-02-27 Zhiyuan Wang , Jianwei Tang , Jiahao Han , Juan Xia , Tianzi Ma , Xue-Wen Chen

We report fluorescence blinking statistics measured from single CdSe nanorods (NRs) of seven different sizes with aspect ratio ranging from 3 to 11. This study included core/shell CdSe/ZnSe NRs and core NRs with two different surface…

Materials Science · Physics 2007-05-23 Siying Wang , Claudia Querner , Thomas Emmons , Marija Drndic , Catherine H. Crouch

Photoluminescence (PL) intermittency is a ubiquitous phenomenon detrimentally reducing the temporal emission intensity stability of single colloidal quantum dots (CQDs) and the emission quantum yield of their ensembles. Despite efforts for…

The photoluminescence intermittency (blinking) of quantum dots is interesting because it is an easily-measured quantum process whose transition statistics cannot be explained by Fermi's Golden Rule. Commonly, the transition statistics are…

Mesoscale and Nanoscale Physics · Physics 2023-01-23 Roberto N. Munoz , Laszlo Frazer , Gangcheng Yuan , Paul Mulvaney , Felix A. Pollock , Kavan Modi

We examine quantitatively the transition process from emitting to not-emitting states of fluorescent molecules with a machine learning technique. In a fluorescently labeled DNA, the fluorescence occurs continuously under irradiation, but it…

We study theoretically the quantum optical properties of hybrid molecules composed of an individual quantum dot and a metallic nanoparticle. We calculate the resonance fluorescence of this hybrid system. Its incoherent part, the one arising…

Quantum Physics · Physics 2010-04-12 A. Ridolfo , O. Di Stefano , N. Fina , R. Saija , S. Savasta

We present a study of residence time statistics for $N$ blinking quantum dots. With numerical simulations and exact calculations we show sharp transitions for a critical number of dots. In contrast to expectation the fluctuations in the…

Statistical Mechanics · Physics 2013-05-29 S. Burov , E. Barkai

Long-term observations of photoluminescence at the single-molecule level were until recently very diffcult, due to the photobleaching of organic ?uorophore molecules. Although inorganic semiconductor nanocrystals can overcome this diffculty…

The relation between single particle and ensemble measurements is adressed for semiconductor CdSe nanocrystals. We record their fluorescence at the single molecule level and analyse their emission intermittency, which is governed by unusual…

Materials Science · Physics 2009-03-13 X. Brokmann , J. -P. Hermier , G. Messin , P. Desbiolles , J. -P. Bouchaud , M. Dahan

Abrupt fluorescence intermittency or blinking is long recognized to be characteristic of single nano-emitters. Extended quantum-confined nanostructures also undergo spatially heterogeneous blinking, however, there is no such precedence in…

Mesoscale and Nanoscale Physics · Physics 2018-08-27 Nithin Pathoor , Ansuman Halder , Amitrajit Mukherjee , Jaladhar Mahato , Shaibal K. Sarkar , Arindam Chowdhury
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