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Using molecular dynamics simulations, we have determined that the nature of dynamical heterogeneity in jammed liquids is very sensitive to short-ranged attractions. Weakly attractive systems differ little from dense hard-sphere and…

Soft Condensed Matter · Physics 2007-05-23 David R. Reichman , Eran Rabani , Phillip L. Geissler

We theoretically study the non-monotonic (re-entrant) activated dynamics associated with a repulsive glass to fluid to attractive glass transition in high density particle suspensions interacting via strong short range attractive forces.…

Soft Condensed Matter · Physics 2020-01-29 Ashesh Ghosh , Kenneth S. Schweizer

The bare Coulomb interaction between two like-charges is repulsive. When these charges are immersed in an electrolyte, the thermal fluctuations of the ions turn the bare Coulomb interaction into an effective interaction between the two…

Statistical Mechanics · Physics 2023-03-15 Gabriel Tellez

We investigate glassy dynamical properties of one component three-dimensional system of particles interacting via pair repulsive potential by the molecular dynamic simulation in the wide region of densities. The glass state is superfragile…

Soft Condensed Matter · Physics 2013-01-11 R. E. Ryltsev , N. M. Chtchelkatchev , V. N. Ryzhov

We present a model for glassy dynamics in supercooled liquid mixtures. Given the relaxation behavior of individual supercooled liquids, the model predicts the relaxation times of their mixtures as temperature is decreased. The model is…

Statistical Mechanics · Physics 2019-09-11 Shachi Katira , Juan P. Garrahan , Kranthi K. Mandadapu

Systems in which a short-ranged attraction and long-ranged repulsion compete are intrinsically frustrated, leading their structure and dynamics to be dominated either by mesoscopic order or by metastable disorder. Here we report the latter…

Soft Condensed Matter · Physics 2017-12-27 Christian L. Klix , C. Patrick Royall , Hajime Tanaka

The dynamical properties of the site frustrated percolation model are investigated and compared with those of glass forming liquids. When the density of the particles on the lattice becomes high enough, the dynamics of the model becomes…

Statistical Mechanics · Physics 2009-10-30 S. Scarpetta , A. de Candia , A. Coniglio

The interplay of slow dynamics and thermodynamic features of dense liquids is studied by examinining how the glass transition changes depending on the presence or absence of Lennard-Jones-like attractions. Quite different thermodynamic…

Materials Science · Physics 2009-11-13 Th. Voigtmann

We demonstrate that an extended picture of kinetic constraints in glass-forming liquids is sufficient to explain dynamic anomalies observed in dense suspensions of strongly attracting colloidal particles. We augment a simple model of…

Statistical Mechanics · Physics 2009-11-10 Phillip L. Geissler , David R. Reichman

The predictions of a class of phenomenological trap models of supercooled liquids are tested via computer simulation of a model glass-forming liquid. It is found that a model with a Gaussian distribution of trap energies provides a good…

Soft Condensed Matter · Physics 2007-05-23 R. Aldrin Denny , David R. Reichman , Jean-Philippe Bouchaud

We theoretically study thermally activated elementary dynamical processes that precede full structural relaxation in ultra-dense particle liquids interacting via strong short range attractive forces. Our approach is based on a microscopic…

Soft Condensed Matter · Physics 2020-07-01 Ashesh Ghosh , Kenneth S. Schweizer

Supercooled liquids display fascinating properties upon cooling such as the emergence of dynamic length scales. Different models strongly vary with respect to the choice of the elementary subsystems (CRR) as well as their mutual coupling.…

Disordered Systems and Neural Networks · Physics 2015-05-18 C. Rehwald , O. Rubner , A. Heuer

Despite the diversity of materials designated as active matter, virtually all active systems undergo a form of dynamic arrest when crowding and activity compete, reminiscent of the dynamic arrest observed in colloidal and molecular fluids…

Soft Condensed Matter · Physics 2019-05-28 Ludovic Berthier , Elijah Flenner , Grzegorz Szamel

There is growing evidence that slow dynamics and dynamic heterogeneity possess structural signatures in glass-forming liquids. However, even in the weakly frustrated glass-forming liquids, whether or not the dynamic heterogeneity has a…

Soft Condensed Matter · Physics 2015-06-11 Wen-Sheng Xu , Zhao-Yan Sun , Li-Jia An

We show that the replica approach to glassy dynamics provides, in spite of its static nature, a characterization of critical dynamics in the $\beta$-regime of super-cooled liquids that is equivalent to the one of Mode-Coupling-Theory, both…

Disordered Systems and Neural Networks · Physics 2013-02-25 Tommaso Rizzo

In this Perspective, I describe recent work on systems in which the traditional distinctions between (i) unentangled vs. well-entangled systems and (ii) melts vs. glasses seem least useful, and argue for the broader use in glassy polymer…

Soft Condensed Matter · Physics 2015-05-27 Robert S. Hoy

The rotational dynamics of a supercooled molecular liquid is investigated by a molecular-dynamics numerical study. We detect rotational jumps with a waiting-time distribution which is well fitted by a truncated power law. At lower…

Statistical Mechanics · Physics 2007-05-23 Cristiano De Michele , Dino Leporini

The fragility, that controls the temperature-dependent viscous properties of liquids as the glass transition is approached, in various glass-forming liquids with different atomic interactions and densities is investigated by molecular…

Soft Condensed Matter · Physics 2016-08-03 Lijin Wang , Pengfei Guan , W. H. Wang

We investigate the heterogeneous dynamics in a model, where chemical gelation and glass transition interplay, focusing on the dynamical susceptibility. Two independent mechanisms give raise to the correlations, which are manifested in the…

Soft Condensed Matter · Physics 2017-05-09 Antonio de Candia , Annalisa Fierro , Raffaele Pastore , Massimo Pica Ciamarra , Antonio Coniglio

A theory which uses data of the static pair-correlation function is developed to calculate quantities associated with the viscous slowing down of supercooled liquids. We calculate value of the energy fluctuations that determine the number…

Statistical Mechanics · Physics 2019-09-09 Ankit Singh , Yashwant Singh