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We theoretically investigate the thermoelectric properties of semiconducting (gapped) materials by varying the degrees of polynomials in their energy dispersion relations, in which either the valence or conduction energy dispersion depends…

Thermoelectric devices that utilize the Seebeck effect convert heat flow into electrical energy and are highly desirable for the development of portable, solid state, passively-powered electronic systems. The conversion efficiencies of such…

Materials Science · Physics 2015-01-06 Ruixiang Fei , Alireza Faghaninia , Ryan Soklaski , Jia-An Yan , Cynthia Lo , Li Yang

Lead chalcogenides are the promising thermoelectric (TE) materials having narrow band gap. The present work investigates the TE behaviour of PbSe in the temperature range 300-500 K. The transport properties of the sample have been studied…

The electronic, phonon, and thermoelectric properties of a two-dimensional HfS2 monolayer are investigated by using the first-principles calculations combined with the Boltzmann transport theory. The band valleys of the HfS2 monolayer can…

Mesoscale and Nanoscale Physics · Physics 2016-08-22 H. Y. Lv , W. J. Lu , X. Luo , H. Y. Lu , X. B. Zhu , Y. P. Sun

The electronic and phonon transport properties of quaternary tetradymite BiSbSeTe2 are investigated using first-principles approach and Boltzmann transport theory. Unlike the binary counterpart Bi2Te3, we obtain a pair of Rashba splitting…

Materials Science · Physics 2018-08-01 Z. Z. Zhou , H. J. Liu , D. D. Fan , B. Y. Zhao , C. Y. Sheng , G. H. Cao , S. Huang

In 2016, bulk tellurium was experimentally observed as a remarkable thermoelectric material. Recently, two-dimensional (2D) tellurium, called tellurene, has been synthesized and has exhibited unexpected electronic properties compared with…

Computational Physics · Physics 2019-06-05 Zhibin Gao , Gang Liu , Jie Ren

In this study, we calculate the $T$=300 K scattering and thermoelectric transport properties of rhombohedral GeTe using first-principles modeling. The room-temperature phase of GeTe has a layered structure, with cross-plane and in-plane…

Materials Science · Physics 2019-08-07 Vahid Askarpour , Jesse Maassen

Unlike in many other semiconductors, the band gap of PbTe increases considerably with temperature. We compute the thermoelectric transport properties of n-type PbTe from first principles including the temperature variation of the electronic…

Materials Science · Physics 2019-12-19 Jiang Cao , José D. Querales-Flores , Stephen Fahy , Ivana Savić

Low-dimensional layered materials have attracted tremendous attentions due to their wide range of physical and chemical properties and potential applications in electronic devices. Using first-principles method taking into account the…

Materials Science · Physics 2018-08-16 Z. Z. Zhou , H. J. Liu , D. D. Fan , C. Y. Sheng , G. H. Cao

The unique structure of Zintl phase makes it an ideal system to realize the concept of phonon-glass and electron-crystal in the thermoelectric community. In this work, by combining first-principles calculations and Boltzmann transport…

Materials Science · Physics 2017-08-01 S. Huang , H. J. Liu , D. D. Fan , P. H. Jiang , J. H. Liang , G. H. Cao , J. Shi

Recently, $\mathrm{BaSn_2}$ is predicted to be a strong topological insulator by the first-principle calculations. It is well known that topological insulator has a close connection to thermoelectric material, such as $\mathrm{Bi_2Te_3}$…

Materials Science · Physics 2016-12-21 San-Dong Guo , Liang Qiu

Improving the figure of merit $zT$ of thermoelectric materials requires simultaneously a high power factor and low thermal conductivity. An effective approach for increasing the power factor is to align the band extremum and achieve high…

Materials Science · Physics 2019-03-06 Jiangang He , Yi Xia , S. Shahab Naghavi , Vidvuds Ozoliņš , Chris Wolverton

Two-dimensional transition metal dichalcogenides (TMDCs) are finding promising electronic and optical applications due to their unique properties. In this letter, we systematically study the phonon transport and thermal conductivity of…

Materials Science · Physics 2014-09-30 Xiaokun Gu , Ronggui Yang

The thermoelectric transport properties of CaMg2Bi2, EuMg2Bi2, and YbMg2Bi2 were characterized between 2 and 650K. As synthesized, the polycrystalline samples are found to have lower p-type carrier concentrations than single-crystalline…

Materials Science · Physics 2012-01-13 A. F. May , M. A. McGuire , J. Ma , O. Delaire , A. Huq , D. J. Singh , W. Cai , H. Wang

We investigate the thermoelectric properties of CaAl$_2$Si$_2$-type Zintl phase compounds $AB_2X_2$ ($A$ = Mg, Ca, Sr, Ba, $B$ = Mg, Zn, Cd, and $X$ = P, As, Sb) using first principles band calculations within the Boltzmann transport theory…

Materials Science · Physics 2020-11-16 Hidetomo Usui , Kazuhiko Kuroki

We have investigated the electrical resistivity, Seebeck coefficient and thermal conductivity of PdTe2 and 4% Cu intercalated PdTe2 compounds. Electrical resistivity for the compounds shows Bloch-Gruneisen type linear temperature (T)…

Strongly Correlated Electrons · Physics 2024-01-08 M. K. Hooda , C. S. Yadav

We present an analysis of the thermoelectric properties of of $n$-type GeTe and SnTe in relation to the lead chalcogenides PbTe and PbSe. We find that the singly degenerate conduction bands of semiconducting GeTe and SnTe are highly…

Materials Science · Physics 2013-10-22 Xin Chen , David Parker , David J. Singh

The increase of a thermoelectric material's figure of merit (ZT value) is limited by the interplay of the transport coefficients. Here we report the greatly enhanced thermoelectric performance of a ZrS2 monolayer by the biaxial tensile…

Mesoscale and Nanoscale Physics · Physics 2016-07-14 H. Y. Lv , W. J. Lu , D. F. Shao , H. Y. Lu , Y. P. Sun

The alloys with 8/18/24 valence electron count (VEC) are promising candidates for efficient energy conversion and refrigeration applications at low as well as high temperatures. The full potential linearized augmented plane wave method as…

Materials Science · Physics 2022-05-17 Mukesh K. Choudhary , H. Fjellvåg , P. Ravindran

Both electron and phonon transport properties of single layer MoS2 (SLMoS2) are studied. Based on first-principles calculations, the electrical conductivity of SLMoS2 is calculated by Boltzmann equations. The thermal conductivity of SLMoS2…

Mesoscale and Nanoscale Physics · Physics 2015-12-07 Zelin Jin , Quanwen Liao , Haisheng Fang , Zhichun Liu , Wei Liu , Zhidong Ding , Tengfei Luo , Nuo Yang