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Related papers: Laser induced persistent orientation of chiral mol…

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Abstract We report the experimental observation of molecular unidirectional rotation (UDR) echoes, and analyze their origin and behavior both classically and quantum mechanically. The molecules are excited by two time-delayed…

We investigate the persistent orientation of asymmetric-top molecules induced by time-delayed THz pulses that are either collinearly or cross polarized. Our theoretical and numerical results demonstrate that the orthogonal configuration…

Chemical Physics · Physics 2023-12-05 Long Xu , Ilia Tutunnikov , Yehiam Prior , Ilya Sh. Averbukh

Photoelectron angular distributions (PADs) of oriented polar molecules in response to different polarized lasers are systematically investigated. It is found that the PADs of polar CO molecules show three distinct styles excited by…

Chemical Physics · Physics 2013-03-05 Xiaosong Zhu , Qingbin Zhang , Weiyi Hong , Peixiang Lu , Zhizhan Xu

The mixed-field orientation of an asymmetric-rotor molecule with its permanent dipole moment non-parallel to the principal axes of polarizability is investigated experimentally and theoretically. We find that for the typical case of a…

Recently developed circularly polarized X-ray light sources can probe ultrafast chiral electronic and nuclear dynamics through spatially localized resonant core transitions. We present simulations of time-resolved circular dichroism (TRCD)…

Chemical Physics · Physics 2017-02-08 Jérémy R. Rouxel , Markus Kowalewski , Shaul Mukamel

We present a new technique for detecting chirality in the gas phase: Chiral molecules are spatially aligned in three-dimensions by a moderately strong elliptically-polarized laser field. The momentum distributions of the charged fragments,…

Chemical Physics · Physics 2021-02-18 Cem Saribal , Alec Owens , Andrey Yachmenev , Jochen Küpper

Ultrashort laser pulses are widely used for transient field-free molecular orientation -- a phenomenon important in chemical reaction dynamics, ultrafast molecular imaging, high harmonics generation, and attosecond science. However,…

Chemical Physics · Physics 2022-12-21 Ilia Tutunnikov , Long Xu , Yehiam Prior , Ilya Sh. Averbukh

We explore the role of laser induced anti-alignment in enhancing molecular orientation. A field-free enhanced orientation via anti-alignment scheme is presented, which combines a linearly polarized femtosecond laser pulse with a half-cycle…

Optics · Physics 2009-11-11 E. Gershnabel , I. Sh. Averbukh , Robert J. Gordon

We present an analysis of two experimental approaches to controlling the directionality of molecular rotation with ultrashort laser pulses. The two methods are based on the molecular interaction with either a pair of pulses (a "double kick"…

Optics · Physics 2015-06-11 C. Bloomquist , S. Zhdanovich , A. A. Milner , V. Milner

Chirality causes symmetry breaks in a large variety of natural phenomena ranging from particle physics to biochemistry. We investigate one of the simplest conceivable chiral systems, a laser-excited, oriented, effective one-electron Li…

We review on the theoretical status of intense laser orientation and alignment. The evolution of the rotational wave packet and its dynamics leading to orientation and alignment is the topic of the present discussion. The major part of the…

Atomic Physics · Physics 2021-04-14 Vijit V. Nautiyal , Sumana Devi , Ashish Tyagi , Bhawna Vidhani , Anjali Maan , Vinod Prasad

Two mechanisms of two-color (\omega + 2\omega) laser-induced field-free molecular orientation, based on the hyperpolarizability and ionization depletion, are explored and compared. The CO molecule is used as a computational example. While…

Atomic Physics · Physics 2012-09-14 Michael Spanner , Serguei Patchkovskii , Eugene Frumker , Paul Corkum

We introduce a new scheme for controlling the sense of molecular rotation. By varying the polarization and the delay between two ultrashort laser pulses, we induce unidirectional molecular rotation, thereby forcing the molecules to rotate…

Quantum Physics · Physics 2015-05-13 Sharly Fleischer , Yuri Khodorkovsky , Yehiam Prior , Ilya Sh. Averbukh

Distinguishing between the left- and right-handed versions of a chiral molecule (enantiomers) is vital, but also inherently difficult. Traditional optical methods using elliptically or circularly polarized light rely on weak linear effects…

Optics · Physics 2022-06-08 Laura Rego , David Ayuso

Measuring and controlling the ionization dynamics by intense laser fields has recently led to important breakthroughs, from the investigation of tunneling time delays to attosecond molecular imaging by electron holography. In these…

Ionization and excitation of water molecules in intense laser pulses is studied theoretically by solving the three-dimensional time-dependent electronic Schr\"odinger equation within the single-active-electron approximation. The possibility…

Atomic Physics · Physics 2011-12-13 Simon Petretti , Alejandro Saenz , Alberto Castro , Piero Decleva

Chirality is a fundamental concept in physics that underpins various phenomena in nonlinear optics, quantum physics, and topological photonics. Although the spin of a photon naturally brings chirality, orbital angular momentum can also…

Molecular chirality is a key design property for many technologies including bioresponsive imaging, circularly polarized light detection and emission, molecular motors and switches. Imaging and manipulating the primary steps of transient…

The discovery of the chiral induced spin selectivity effect has provided a novel tool to study how active physical and chemical mechanism may differ in chiral enantiomers, however, the origin of the effect itself is yet an open question. In…

Mesoscale and Nanoscale Physics · Physics 2026-04-17 J. Fransson

We provide a detailed theoretical analysis of molecular rotational excitation by a chiral pulse train -- a sequence of linearly polarised pulses with the polarisation direction rotating from pulse to pulse by a controllable angle. Molecular…

Quantum Physics · Physics 2013-05-30 Johannes Floß , Ilya Sh. Averbukh