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It is strong Coulomb effects in carbon nanotubes that lead to formation of the so-called "bright" and "dark" (forbidden one-photon optical transition) exciton states, and dramatically decrease the efficiency of one-photon light emission via…

Quantum Physics · Physics 2009-02-09 Nikolai G. Kalugin , Yuri V. Rostovtsev

We show that strong light-matter coupling can be used to overcome a long standing problem that has prevented efficient optical emission from carbon nanotubes. The luminescence from the nominally bright exciton states of carbon nanotubes is…

Mesoscale and Nanoscale Physics · Physics 2019-04-30 Vanik A. Shahnazaryan , Vasil A. Saroka , Ivan A. Shelykh , William L. Barnes , Mikhail E. Portnoi

Luminescence properties of carbon nanotubes are strongly affected by exciton diffusion, which plays an important role in various nonradiative decay processes. Here we perform photoluminescence microscopy on hundreds of individual…

Mesoscale and Nanoscale Physics · Physics 2015-03-23 A. Ishii , M. Yoshida , Y. K. Kato

The efficiencies of photonic devices are primarily governed by radiative quantum efficiency, which is a property given by the light emitting material. Quantitative characterization for carbon nanotubes, however, has been difficult despite…

Mesoscale and Nanoscale Physics · Physics 2022-04-19 H. Machiya , D. Yamashita , A. Ishii , Y. K. Kato

The bright exciton emission of semiconducting carbon nanotubes is appealing for optoelectronic and quantum photonic devices as well as fundamental studies of light-matter interaction in one-dimensional nanostructures. The photophysics of…

Mesoscale and Nanoscale Physics · Physics 2017-05-09 Ibrahim Sarpkaya , Zhengyi Zhang , William Walden-Newman , Xuesi Wang , James Hone , Chee Wei Wong , Stefan Strauf

We report the direct observation of the spin-singlet dark excitonic state in individual single-walled carbon nanotubes through low-temperature micro-photoluminescence spectroscopy in magnetic fields. A magnetic field up to 5 T, applied…

Mesoscale and Nanoscale Physics · Physics 2008-08-22 A. Srivastava , H. Htoon , V. I. Klimov , J. Kono

Light emission from carbon nanotubes is expected to be dominated by excitonic recombination. Here we calculate the properties of excitons in nanotubes embedded in a dielectric, for a wide range of tube radii and dielectric environments. We…

Materials Science · Physics 2009-11-10 Vasili Perebeinos , J. Tersoff , Phaedon Avouris

We investigate the lowest many-body excited states in carbon nanotubes by means of ab initio calculations. On the basis of these calculations and an additional theoretical analysis of the excitons, we demonstrate that the splitting between…

Materials Science · Physics 2007-05-23 Eric Chang , Deborah Prezzi , Alice Ruini , Elisa Molinari

We present theoretical analysis and first-principles calculation of the radiative lifetime of excitons in semiconducting carbon nanotubes. An intrinsic lifetime of the order of 10 ps is computed for the lowest optically active bright…

Materials Science · Physics 2009-11-11 Catalin D. Spataru , Sohrab Ismail-Beigi , Rodrigo B. Capaz , Steven G. Louie

Direct measurements of the diffusion length of excitons in air-suspended single-walled carbon nanotubes are reported. Photoluminescence microscopy is used to identify individual nanotubes and to determine their lengths and chiral indices.…

Mesoscale and Nanoscale Physics · Physics 2010-06-17 S. Moritsubo , T. Murai , T. Shimada , Y. Murakami , S. Chiashi , S. Maruyama , Y. K. Kato

Energy dissipation and decoherence are at first glance harmful to acquiring long exciton lifetime desired for efficient photovoltaics. In the presence of both optically forbidden (namely, dark) and allowed (bright) excitons, however, they…

Mesoscale and Nanoscale Physics · Physics 2015-11-11 Yasuhiro Yamada , Youhei Yamaji , Masatoshi Imada

We report optical studies of quantum dot excitons in individual suspended carbon nanotubes at cryogenic temperatures. Narrow optical linewidths, strongly suppressed spectral wandering, and photoluminescence lifetimes in the range of…

Mesoscale and Nanoscale Physics · Physics 2014-10-03 Matthias S. Hofmann , Jan T. Glückert , Alexander Högele

Photoluminescence is commonly used to identify the electronic structure of individual nanotubes. But, nanotubes naturally occur in bundles. Thus, we investigate photoluminescence of nanotube bundles. We show that their complex spectra are…

Materials Science · Physics 2015-05-13 P. H. Tan , A. G. Rozhin , T. Hasan , P. Hu , V. Scardaci , W. I. Milne , A. C. Ferrari

Dark ground state exciton in semiconductor nanocrystals has been a subject of much interest due to its long lifetime attractive for applications requiring long-lived electronic or spin states. Significant effort has been made recently to…

Strong coupling of excitonic resonances with a cavity gives rise to exciton-polaritons which possess a modified energy landscape compared to the uncoupled emitter. However, due to the femtosecond lifetime of the so-called bright polariton…

Mesoscale and Nanoscale Physics · Physics 2022-05-19 Jan M. Lüttgens , Zhuoran Kuang , Nicolas F. Zorn , Tiago Buckup , Jana Zaumseil

We have studied emission properties of high-density excitons in single-walled carbon nanotubes through nonlinear photoluminescence excitation spectroscopy. As the excitation intensity was increased, all emission peaks arising from different…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Y. Murakami , J. Kono

Polymeric carbon nitrides (PCNs) exhibit intriguing optical properties and exceptional performance in (photo)catalysis, optoelectronics, and energy storage. Nevertheless, the intricate phenomena involving light absorption extending to the…

Materials Science · Physics 2024-07-17 Changbin Im , Radim Beranek , Timo Jacob

Nanomaterials exhibit unique optical phenomena, in particular excitonic quantum processes occurring at room temperature. The low dimensionality, however, imposes strict requirements for conventional optical excitation, and an approach for…

Mesoscale and Nanoscale Physics · Physics 2023-12-15 N. Fang , D. Yamashita , S. Fujii , M. Maruyama , Y. Gao , Y. R. Chang , C. F. Fong , K. Otsuka , K. Nagashio , S. Okada , Y. K. Kato

Highly efficient exciton-exciton annihilation process unique to one-dimensional systems is utilized for super-resolution imaging of air-suspended carbon nanotubes. Through the comparison of fluorescence signals in linear and sublinear…

Mesoscale and Nanoscale Physics · Physics 2019-06-12 K. Otsuka , A. Ishii , Y. K. Kato

We study the excitonic recombination dynamics in an ensemble of (9,4) semiconducting single-wall carbon nanotubes by high sensitivity time-resolved photo-luminescence experiments. Measurements from cryogenic to room temperature allow us to…

Other Condensed Matter · Physics 2015-06-25 S. Berger , C. Voisin , G. Cassabois , C. Delalande , Philippe Roussignol , X. Marie
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