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Spinel oxides are well-known functional materials but rarely show superconductivity. Recently, emergent superconductivity was discovered in MgTi$_2$O$_4$, which is attributed to the increase of electron doping and the suppression of orbital…

Superconductivity · Physics 2023-03-23 Qizhi Li , Abhishek Nag , Xiquan Zheng , Fucong Chen , Jie Yuan , Kui Jin , Yi Lu , Ke-Jin Zhou , Yingying Peng

Superconductivity in the family of spinel oxides is very rare owing to their robust Mott-insulating nature. About half a century ago, LiTi$_2$O$_4$ became the first reported spinel compound to show superconductivity with a 12K transition…

Superconductivity · Physics 2023-05-16 Dibyendu Dey , T. Maitra , A. Taraphder

Around fifty years ago, LiTi$_2$O$_4$ was reported to be first spinel oxide to exhibit a superconducting transition with highest T$_c$ $\approx$ 13.7 K. Recently, MgTi$_2$O$_4$ has been found to be the only other spinel oxide to reveal a…

Superconductivity · Physics 2023-06-27 A. Rahaman , T. Paramanik , B. Pal , R. Pal , P. Maji , K. Bera , S. Mallik , D. K. Goswami , A. N. Pal , D. Choudhury

LiTi2O4 is a unique material in that it is the only known oxide spinel superconductor. Although bulk studies have demonstrated that superconductivity can be generally described by the Bardeen-Cooper-Schreiffer theory, the microscopic…

Superconductivity · Physics 2010-05-27 Rajesh V. Chopdekar , Elke Arenholz , Yuri Suzuki

The charge frustration with the mixed-valence state inherent to LiTi$_2$O$_4$, which is found to be a unique spinel oxide superconductor, is the impetus for paying special attention to reveal the existence of intriguing superconducting…

Superconductivity · Physics 2023-01-18 Huanyi Xue , Lijie Wang , Zhongjie Wang , Guanqun Zhang , Wei Peng , Shiwei Wu , Chunlei Gao , Zhenghua An , Yan Chen , Wei Li

Recent renewal of the highest transition temperature in a conventional superconductor of the sulfer hydride attracts much attention to exploring simple compounds with the lighter elements, situated in unconventional conditions. We report…

Materials Science · Physics 2022-05-11 K. Yoshimatsu , O. Sakata , A. Ohtomo

Transition-metal oxides offer an opportunity to explore unconventional superconductors, where the superconductivity (SC) is often interrelated with novel phenomena such as spin/charge order, fluctuations, and Fermi surface instability…

Unique superconductivity at surfaces/interfaces, as exemplified by LaAlO3/SrTiO3 interfaces, and the high transition temperature in ultrathin FeSe films, have triggered intense debates on how superconductivity is affected in atomic and…

We report pressure-induced superconductivity in the spinel CuIr$_{2}$S$_{4}$ with a transition temperature ($T_{\text{c}}$) reaching \textbf{18.2 K}, establishing a new record for this class of materials and surpassing the decades-old limit…

High-field electrical transport and point-contact tunneling spectroscopy were used to investigate superconducting properties of the unique spinel oxide, LiTi$_2$O$_{4-\delta}$ films with various oxygen content. We find that the upper…

We performed resistivity measurements in CuRh$_{2}$S$_{4}$ under quasi-hydrostatic pressure of up to 8.0 GPa, and found a pressure induced superconductor-insulator (SI) transition. Initially, with increasing pressure, the superconducting…

Superconductivity · Physics 2009-11-07 M. Ito , J. Hori , H. Kurisaki , H. Okada , A. J. Perez Kuroki , N. Ogita , M. Udagawa , H. Fujii , F. Nakamura , T. Fujita , T. Suzuki

The family of titanium oxide superconductors exhibits many intriguing phenomena comparable to cuprates and iron pnictides/chalcogenides, and thus provides an ideal platform to contrastively study the unconventional pairing mechanism of…

This review discusses the multifaceted electronic properties of spinel oxides with a particular focus on Lithium Vanadate (LiV2O4), Lithium Titanate (LiTi2O4), and Magnesium Titanate (MgTi2O4). We selected LiTi2O4, LiV2O4, and MgTi2O4…

Materials Science · Physics 2025-12-03 Jagadis Prasad Nayak , Raju Saini , Sourav Dash , Gopi Nath Daptary

High-temperature cuprate superconductors have naturally a superlattice structure. Infinite-layer CaCuO2 is the common ingredient of cuprates with superconducting transition temperatures above 100 K. However, infinite-layer CaCuO2 by itself…

Superconductivity · Physics 2021-09-10 Ai Ikeda , Yoshiharu Krockenberger , Yoshitaka Taniyasu , Hideki Yamamoto

Superconductivity has been found in RuN films obtained by reactive magnetron sputtering. This is a novel member of the metal nitride superconductors family. The critical temperature of the superconducting transition varies depending on the…

The recently discovered spin-triplet superconductor candidate UTe2 with Tc = 2 K has attracted enormous attention because it possesses many interesting properties, such as the extremely high upper critical field Hc2(0), chiral…

Superconductivity · Physics 2026-05-12 Qing Li , Zhe-Ning Xiang , Bin-Bin Zhang , Ying-Jie Zhang , Chaofan Zhang , Hai-Hu Wen

A systematic study is performed on the spinel oxide, i.e. LiTi2O4 thin films oriented along [111]-, [110]-, and [001]-directions, to reveal the crystallographic dependence of transport properties. With decreasing temperature, the LiTi2O4…

Superconductivity · Physics 2016-08-25 Yanli Jia , Ge He , Heshan Yu , Wei Hu , Zhenzhong Yang , Jinan Shi , Zefeng Lin , Jie Yuan , Beiyi Zhu , Kai Liu , Lin Gu , Hong Li , Kui Jin

The evolution from superconducting LiTi2O4-delta to insulating Li4Ti5O12 thin films has been studied by precisely adjusting the oxygen pressure during the sample fabrication process. In the superconducting LiTi2O4-delta films, with the…

Superconductivity · Physics 2017-06-26 Yanli Jia , Ge He , Wei Hu , Hua Yang , Zhenzhong Yang , Heshan Yu , Qinghua Zhang , Jinan Shi , Zefeng Lin , Jie Yuan , Beiyi Zhu , Lin Gu , Hong Li , Kui Jin

The associations between emergent physical phenomena (e.g., superconductivity) and orbital, charge, and spin degrees of freedom of $3d$ electrons are intriguing in transition metal compounds. Here, we successfully manipulate the…

The exploration of superconductors in metastable phases by manipulating crystal structures through high-pressure techniques has attracted significant interest in materials science to achieve a high critical temperature ($T_c$). In this…

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