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The calculation time for the energy of atoms and molecules scales exponentially with system size on a classical computer but polynomially using quantum algorithms. We demonstrate that such algorithms can be applied to problems of chemical…

Quantum Physics · Physics 2007-05-23 Alán Aspuru-Guzik , Anthony D. Dutoi , Peter J. Love , Martin Head-Gordon

A modified ideal Bose gas model is proposed as an approach for liquid helium at the lambda point. The decisive modification of the ideal Bose gas model is the use of phase ordered single particle functions. The entropy due to this phase…

Condensed Matter · Physics 2007-05-23 Torsten Fliessbach

Using singlet S states of the helium atom as an example, I describe precise calculation of energy levels in few-electron atoms. In particular, a complete set of effective operators is derived which generates O(m*alpha^6) relativistic and…

High Energy Physics - Phenomenology · Physics 2009-11-07 Alexander Yelkhovsky

Starting from an independent-particle model with a finite and arbitrary set of single-particle energies, we develop an analytical approximation to the many-body level density $\rho_A(E)$ and to particle-hole densities. We use exact…

Nuclear Theory · Physics 2013-09-30 Adriana Pálffy , Hans A. Weidenmüller

It is shown that, in the self-consistent quantum statistical Hartree-Fock approximation, the number of electronic states localized on one nucleus is finite. This result is obtained on the basis of the general electron-nuclear model of…

Statistical Mechanics · Physics 2010-06-14 V. B. Bobrov , S. A. Trigger

Calculational results are presented for the fine-structure splitting of the 2^3P state of helium and helium-like ions with the nuclear charge Z up to 10. Theoretical predictions are in agreement with the latest experimental results for the…

Atomic Physics · Physics 2015-05-20 Krzysztof Pachucki , Vladimir A. Yerokhin

High precision variational calculations in Hylleraas coordinates are presented for all singlet and triplet $P$-states of helium up to principal quantum number $n = 35$ with a uniform accuracy of 1 part in $10^{22}$ for the nonrelativistic…

Atomic Physics · Physics 2025-10-27 G. W. F. Drake , Aaron T. Bondy , Oliver P. Hallett , Benjamin C. Najem

This article presents a study of the grand canonical Bose-Einstein (BE) statistics for a finite number of particles in an arbitrary quantum system. The thermodynamical quantities that identify BE condensation -- namely, the fraction of…

Quantum Gases · Physics 2021-10-27 Pedro Pessoa

Helium atom is the simplest many-body electronic system provided by nature. The exact solution to the Schr\"odinger equation is known for helium ground and excited states, and represents a workbench for any many-body methodology. Here, we…

Atomic Physics · Physics 2017-04-26 Jing Li , Markus Holzmann , Ivan Duchemin , Xavier Blase , Valerio Olevano

The $m \alpha^6$ correction to energy is expressed in terms of an effective Hamiltonian $H^{(6)}$ for an arbitrary state of helium. Numerical calculations are performed for $n=2$ levels, and the previous result for the $2^3P$ centroid is…

Atomic Physics · Physics 2009-11-13 Krzysztof Pachucki

We investigate the finite nuclear mass corrections in the helium atom in order to resolve a significant disagreement between the $2^3S - 2^3P$ and $2^3S - 2^1S$ transition isotope shifts. These two transitions lead to discrepant results for…

Atomic Physics · Physics 2017-01-31 V. Patkos , V. A. Yerokhin , K. Pachucki

Theoretical predictions for the Lamb shift in helium are limited by unknown quantum electrodynamic effects of the order $\alpha^7m$, where $\alpha$ is the fine-structure constant and $m$ is the electron mass. We make an important step…

High Energy Physics - Phenomenology · Physics 2021-02-16 Vojtěch Patkóš , Vladimir A. Yerokhin , Krzysztof Pachucki

A harmonic oscillator model in four dimensions is presented for the helium atom to estimate the distance to the inner and outer electron from the nucleus, the angle between electrons and the energy levels. The method is algebraic and is not…

Quantum Physics · Physics 2015-12-02 Martin Carlsen

Hyperfine intervals in light hydrogenic atoms and ions are among the most accurately measured quantities in physics. The theory of QED corrections has recently advanced to the point that uncalculated terms for hydrogenic atoms and ions are…

Nuclear Theory · Physics 2014-11-18 J. L. Friar , G. L. Payne

We report a detailed study of high-order harmonic generation (HHG) in helium. When comparing predictions from a single-active-electron model with those from all-electron simulations, such as ATTOMESA and R-matrix with time-dependence, which…

Atomic Physics · Physics 2024-03-06 A. T. Bondy , S. Saha , J. C. del Valle , A. Harth , N. Douguet , K. R. Hamilton , K. Bartschat

Highly precise variational calculations of non-relativistic energies of the (2p^2)^3P^e state of Helium atom are presented.We get an upper bound energy E=-0.71050015565678 a.u.,the lowest yet obtained.

Atomic Physics · Physics 2009-11-10 Tapan K. Mukherjee , Prasanta K. Mukherjee

Extremely low metallicity HII regions have been observed with the goal of determining the primordial helium abundance ($Y_{\rm p}$). $Y_{\rm p}$, combined with standard big bang nucleosynthesis and the half-life of the neutron, provides a…

Accurate results for nonrelativistic energy, relativistic, QED, and finite nuclear mass corrections are obtained for $2^1S_{1/2}$, $3^1S_{1/2}$ and $2^1P_{1/2}$ states of the Li atom and Be$^+$ ion. Our computational approach uses the…

Atomic Physics · Physics 2009-11-13 Mariusz Puchalski , Krzysztof Pachucki

The solubility of helium in liquid metals is a knowledge of fundamental importance in the design of the future nuclear fusion reactors, since the formation of helium bubbles inside the breeding blankets of the reactors can be a threat to…

Materials Science · Physics 2024-12-19 Edgar Alvarez-Galera , Daniel Laria , Ferran Mazzanti , Lluis Batet , Jordi Marti

We propose a method to determine the quantum numbers, which we call the rigged configurations, for the solutions to the Bethe ansatz equations for the spin-1/2 isotropic Heisenberg model under the periodic boundary condition. Our method is…

Mathematical Physics · Physics 2016-03-17 Anatol N. Kirillov , Reiho Sakamoto