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The structural properties of EuCo2As2 have been studied up to 35 GPa, through the use of x-ray diffraction in a diamond anvil cell at a synchrotron source. At ambient conditions, EuCo2As2 (I4/mmm) has a tetragonal lattice structure with a…

Materials Science · Physics 2011-04-19 Matthew Bishop , Walter Uhoya , Georgiy Tsoi , Yogesh K. Vohra , Athena S. Sefat , Brian C. Sales

The interplay between structural phase and electronic correlations has been an intriguing topic of research. An prominent example is the pressure-induced uncollapsed to collapsed tetragonal phase transition observed in CaFe$_2$As$_2$, which…

Strongly Correlated Electrons · Physics 2021-03-17 Jianzhou Zhao , Yilin Wang , Xiaolong Feng , Shengyuan A. Yang

A new hight Tc Fe-based compound system, AFe2As2 with A = K, Cs, K/Sr and Cs/Sr has been found. Through electron-doping, Tc of the A = K and Cs compounds rises to ~37 K, and finally enter a spin-density-wave state (SDW) through further…

Superconductivity · Physics 2008-09-09 K. Sasmal , B. Lv , B. Lorenz , A. Guloy , F. Chen , Y. Xue , C. W. Chu

We report the synthesis and basic physical properties of single crystals of CaFe2As2, an isostructural compound to BaFe2As2 which has been recently doped to produce superconductivity. CaFe2As2 crystalizes in the ThCr2Si2 structure with…

Strongly Correlated Electrons · Physics 2008-07-10 F. Ronning , T. Klimczuk , E. D. Bauer , H. Volz , J. D. Thompson

CaFe$_2$As$_2$ has been found to be exceptionally sensitive to the application of hydrostatic pressure and superconductivity has been found to exist in a narrow pressure region that appears to be at the interface between two different phase…

Superconductivity · Physics 2009-11-13 Milton S. Torikachvili , Sergey L. Bud'ko , Ni Ni , Paul C. Canfield

To clarify superconductivity in EuFe2As2 hidden by antiferromagnetism of Eu2+, we investigated a Ca-substituted sample, Eu0.5Ca0.5Fe2As2, under high pressure. For ambient pressure, the sample exhibits a spin-density-wave (SDW) transition at…

Superconductivity · Physics 2010-07-13 Akihiro Mitsuda , Tomohiro Matoba , Hirofumi Wada , Fumihiro Ishikawa , Yuh Yamada

Compounds of Sr1-xLaxFe2As2 were synthesized by solid state reaction at 1273 K, under pressures of 2 or 3 GPa. The Sr1-xLaxFe2As2 phase was dominant up to x = 0.5, and superconductivity was observed at $x \ge 0.2$. A maximum critical…

Superconductivity · Physics 2015-05-18 Yoshinori Muraba , Satoru Matsuishi , Sung-Wng Kim , Toshiyuki Atou , Osamu Fukunaga , Hideo Hosono

By substituting the Fe with the 5d-transition metal Ir in SrFe2As2, we have successfully synthesized the superconductor SrFe2-xIrxAs2 with Tc = 22.3 K at x = 0.5. X-ray diffraction indicates that the material has formed the ThCr2Si2-type…

Superconductivity · Physics 2016-06-28 Fei Han , Xiyu Zhu , Ying Jia , Lei Fang , Peng Cheng , Huiqian Luo , Bing Shen , Hai-Hu Wen

We present detailed electronic structure calculations for CaFe2As2. We investigate in particular the `collapsed' tetragonal and orthorhombic regions of the temperature-pressure phase diagram and find properties that distinguish CaFe2As2…

Strongly Correlated Electrons · Physics 2009-03-27 D. A. Tompsett , G. G. Lonzarich

We report here synthesis, structural, DC magnetization, and transport studies of new BiS2 based layered LaO0.5F0.5BiS2 superconductor [1]. The sample was synthesized by conventional solid state route via vacuum encapsulation technique at…

Superconductivity · Physics 2015-06-05 V. P. S. Awana , Anuj Kumar , Rajveer Jha , Shiva Kumar , Anand Pal , Shruti , J. Saha , S. Patnaik

The surprising discovery of tripling the superconducting critical temperature of KFe$_2$As$_2$ at high pressures issued an intriguing question of how the superconductivity in the collapsed tetragonal phase differs from that in the…

Strongly Correlated Electrons · Physics 2017-11-29 J. Srpcic , P. Jeglic , I. Felner , Bing Lv , C. W. Chu , D. Arcon

We report superconductivity in the novel 112-type iron-based compound Ca1-xLaxFeAs2. Single-crystal X-ray diffraction analysis revealed that the compound crystallizes in a monoclinic structure (space group P21), in which Fe2As2 layers…

We report resistivity measurement under pressure in single crystals of SrFe_2As_2, which is one of the parent materials of Fe-based superconductors. The structural and antiferromagnetic (AFM) transition of T_0 = 198 K at ambient pressure is…

Superconductivity · Physics 2009-11-13 H. Kotegawa , H. Sugawara , H. Tou

We report a systematic and ab-initio electronic structure calculation of Ca0.75 M0.25 Fe2 As2 with M = Ca, Sr, Eu, La, Ce, Pr, Nd, Pm, Sm, Na, K, Rb. The recently reported experimentally observed structural trends in rare earths-doped CaFe2…

Superconductivity · Physics 2014-06-26 A. Sanna , G. Profeta , S. Massidda , E. K. U. Gross

We use angle-resolved photoemission spectroscopy (ARPES) and density functional theory (DFT) calculations to study the electronic structure of CaFe$_2$As$_2$ in previously unexplored collapsed tetragonal (CT) phase. This unusual phase of…

We report a high-pressure study of simultaneous low-temperature electrical resistivity and Hall effect measurements on high quality single-crystalline KFe2As2 using designer diamond anvil cell techniques with applied pressures up to 33 GPa.…

Single crystalline CaFe2As2 and (Ca1-xNax)Fe2As2 polycrystals (0 < x < 0.66) are synthesized and characterized using structural, magnetic, electronic transport, and heat capacity measurements. These measurements show that the…

Superconductivity · Physics 2011-12-02 K. Zhao , Q. Q. Liu , X. C. Wang , Z. Deng , Y. X. Lv , J. L. Zhu , F. Y. Li , C. Q. Jin

Here we report the synthesis and superconductivity of a novel ternary compound LaPd2Bi2. Shiny plate-like single crystals of LaPd2Bi2 were first synthesized by high-temperature solution method with PdBi flux. X-ray diffraction analysis…

Superconductivity · Physics 2018-09-14 Qing-Ge Mu , Bo-Jin Pan , Bin-Bin Ruan , Tong Liu , Kang Zhao , Lei Shan , Gen-Fu Chen , Zhi-An Ren

In order to clarify the origin of anomalous superconductivity in (Ca,RE)Fe2As2 system, Pr doped and Pr,Co co-doped CaFe2As2 single crystals were grown by the FeAs flux method. These samples showed two-step superconducting transition with…

Superconductivity under pressure in FeSe ($T_{\rm c}$$\sim$7.5 K) has been investigated using single-crystal specimens through the measurements of DC magnetization and electrical resistivity. A characteristic three-step increase in $T_{\rm…