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In the endeavour of developing quantum memories, Er$^{3+}$:CaWO$_4$ has emerged as a promising rare-earth ion-doped (REID) crystal platform due to its long optical coherence times and compatibility with the 1550 nm telecommunications band.…

A potential energy curve (PEC) accurate to a fraction of 1 ppm ($1:10^6$) is computed for the $^3\Sigma_\mathrm{u}^+$ state of He$_2$ endowed with relativistic and QED corrections. The nuclear Schr\"odinger equation is solved on this PEC…

Chemical Physics · Physics 2026-02-25 Ádám Margócsy , Balázs Rácsai , Péter Jeszenszki , Edit Mátyus

Tayal and Zatsarinny [Astrophys. J. 850 (2017) 147] have reported results for energy levels, radiative rates (A-values), lifetimes, and effective collision strengths ($\Upsilon$) for transitions among 202 levels of C-like O~III. For the…

Atomic Physics · Physics 2021-03-04 K M Aggarwal

An absorption spectrum of H$_2$$^{16}$O at 1950 K is recorded in a premixed methane/air flat flame using a cavity-enhanced optical frequency comb-based Fourier transform spectrometer. 2417 absorption lines are identified in the 6250 -- 6670…

Published high-resolution rotation-vibration transitions of \spec{h212c16o}, the principal isotopologue of methanal, are analyzed using the MARVEL (Measured Active Rotation-Vibration Energy Levels) procedure. The literature results are…

We present the first framework for fully quantum calculation of the third dielectric virial coefficient $C_\varepsilon(T)$ of noble gases, including exchange effects. The quantum effects are taken into account with the path-integral Monte…

Statistical Mechanics · Physics 2021-12-16 Giovanni Garberoglio , Allan H. Harvey , Bogumił Jeziorski

The intensities of all rovibrational electric quadrupole absorption lines in $^{16}$O$_2$($X^{3}\Sigma^{-}_{g}$), for which the vibrational quantum number is $v \leq 35$ and the total angular momentum quantum number is $J \leq 40$, are…

Atomic Physics · Physics 2025-02-14 Maciej Gancewski , Hubert Jóźwiak , Hubert Cybulski , Piotr Wcisło

We present the first high-resolution measurements and rotational analysis of the fundamental asymmetric stretching vibrational band ${\nu_3}(F_2)$ of radiocarbon methane. A spectrometer consisting of a mid-infrared continuous-wave optical…

The first excited torsional state of the chiral molecule propylene oxide, $\mathrm{CH_{3}C_{2}H_{3}O}$, is investigated from millimeter up to sub-millimeter wavelengths (75-950 GHz). The first excited vibrational mode of propylene oxide,…

Full quantum statistical $NVT$ simulation of the five-particle system H$_3^+$ has been carried out using the path integral Monte Carlo method. Structure and energetics is evaluated as a function of temperature up to the thermal dissociation…

Quantum Physics · Physics 2015-05-18 Ilkka Kylänpää , Tapio T. Rantala

We present a lattice QCD based determination of the chiral phase transition temperature in QCD with two massless (up and down) and one strange quark having its physical mass. We propose and calculate two novel estimators for the chiral…

High Energy Physics - Lattice · Physics 2020-09-07 Olaf Kaczmarek , Frithjof Karsch , Anirban Lahiri , Lukas Mazur , Christian Schmidt

The inelastic cross sections and rate coefficients for the rotational excitation of methanimine (CH$_2$NH) by cold H$_2$ have been determined quantum mechanically based on a new highly correlated five-dimensional potential energy surface.…

Astrophysics of Galaxies · Physics 2018-06-06 Alexandre Faure , François Lique , Anthony J. Remijan

The term values of all rotational levels of the $^4$He${_2}^+\,X^+\,^2\Sigma_u^+\,(\nu^+=0)$ ground vibronic state with rotational quantum number $N^+\le 19$ have been determined with an accuracy of 8 x 10$^{-4}$ cm$^{-1}$ ($\sim{25}$ MHz)…

Chemical Physics · Physics 2017-05-03 Luca Semeria , Paul Jansen , Frédéric Merkt

In this work, trions in two-dimensional (2D) space are studied by variational method with trial wavefunctions being constructed by linear combinations of 2D slater-type orbitals (STOs). Via this method, trion energy levels and wavefunctions…

Mesoscale and Nanoscale Physics · Physics 2021-07-28 Yao-Wen Chang , Yia-Chung Chang

For understanding carbon erosion and redeposition in nuclear fusion devices, it is important to understand the transport and chemical break-up of hydrocarbon molecules in edge plasmas, often diagnosed by emission of the CH A^2\Delta -…

High precision measurements of the Hall effect have been carried out for archetypal heavy fermion compound - CeAl3 in a wide range of temperatures 1.8-300K. For the first time a complex activated behavior of the Hall coefficient in CeAl3…

Strongly Correlated Electrons · Physics 2007-05-23 N. E. Sluchanko , V. V. Glushkov , S. V. Demishev , N. A. Samarin , G. S. Burhanov , O. D. Chistiakov , D. N. Sluchanko

A variational approach is developed for bound state calculations in three- and four-electron atomic systems. This approach can be applied to determine, in principle, an arbitrary bound state in three- and four-electron ions and atoms. Our…

Atomic Physics · Physics 2015-05-19 Alexei M Frolov , David M. Wardlaw

We report the structural, elastic and vibrational properties of five ionic-molecular solid oxidizers MNO$_3$ (M = Li, Na, K) and MClO$_3$ (M = Na, K). By treating long range electron-correlation effects, dispersion corrected method leads to…

Materials Science · Physics 2016-09-05 N. Yedukondalu , G. Vaitheeswaran

Rates and line strengths are calculated for the 2s22p53l3l' - 2s22p63l'' and 2s2p63l3l' - 2s22p63l'' electric-dipole (E1) transitions in Na-like ions with nuclear charges ranging from Z = 14 to 100. Relativistic many-body perturbation…

Atomic Physics · Physics 2009-11-07 U. I. Safronova , W. R. Johnson , M. S. Safronova , J. R. Albritton

Ammonia inversion lines are often used as probes of the physical conditions in the dense ISM. The excitation temperature between the first two para metastable (rotational) levels is an excellent probe of the gas kinetic temperature.…

Astrophysics of Galaxies · Physics 2015-05-13 Sebastien Maret , Alexandre Faure , Emanuele Scifoni , Laurent Wiesenfeld
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