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Related papers: Molecular Electronics: From Single-Molecule to Lar…

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Devices made of few molecules constitute the miniaturization limit that both inorganic and organic-based electronics aspire to reach. However, integration of millions of molecular junctions with less than 100 molecules each has been a long…

Mesoscale and Nanoscale Physics · Physics 2013-02-11 Kacem Smaali , Nicolas Clement , Gilles Patriarche , Dominique Vuillaume

We present an original method to estimate the conductivity of a single molecule anchored to nanometric-sized metallic electrodes, using a Mechanically Controlled Break Junction (MCBJ) operated at room temperature in liquid. We record the…

Mesoscale and Nanoscale Physics · Physics 2018-03-16 M. Gil , T. Malinowski , M. Iazykov , H. Klein

The simplicity of single-molecule junctions based on direct bonding of a small molecule between two metallic electrodes make them an ideal system for the study of fundamental questions related to molecular electronics. Here we study the…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 O. Tal , M. Kiguchi , W. H. A. Thijssen , D. Djukic , C. Untiedt , R. H. M. Smit , J. M. van Ruitenbeek

We report on inelastic electron tunneling spectroscopy measurements carried out on single molecules incorporated into a mechanically controllable break-junction of Au and Pt electrodes at low temperature. Here we establish a correlation…

Mesoscale and Nanoscale Physics · Physics 2010-11-16 Youngsang Kim , Hyunwook Song , Florian Strigl , Hans-Fridtjof Pernau , Takhee Lee , Elke Scheer

Molecular electronics originally proposed that small molecules sandwiched between electrodes would accomplish electronic functions and enable to reach ultimate scaling. However, so far, functional molecular devices have been only…

Mesoscale and Nanoscale Physics · Physics 2016-10-10 Jorge Trasobares , Dominiqe Vuillaume , Didier Théron , Nicolas Clement

Molecular electronics break-junction experiments are widely used to investigate fundamental physics and chemistry at the nanoscale. Reproducibility in these experiments relies on measuring conductance on thousands of freshly formed…

Chemical Physics · Physics 2024-01-29 Leopoldo Mejía , Pilar Cossio , Ignacio Franco

Recent years have shown steady progress in research towards molecular electronics [1,2], where molecules have been investigated as switches [3-5], diodes [6], and electronic mixers [7]. In much of the previous work a Scanning Tunnelling…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 R. H. M. Smit , Y. Noat , C. Untiedt , N. D. Lang , M. van Hemert , J. M. van Ruitenbeek

Since the first measurement of electron tunneling through an organic monolayer in 1971,(Mann and Kuhn, 1971) and the gedanken experiment of a molecular current rectifying diode in 1974,(Aviram and Ratner, 1974) molecular-scale electronics…

Mesoscale and Nanoscale Physics · Physics 2010-05-17 D. Vuillaume

This review presents recent results on the physics of electron transport in molecular devices. The review is organized as follows. A brief description of molecular junction (MJ) technology is first given followed by an introduction to the…

Mesoscale and Nanoscale Physics · Physics 2021-11-23 Dominique Vuillaume

Molecular electronics targets tiny devices exploiting the electronic properties of the molecular orbitals, which can be tailored and controlled by the chemical structure/conformation of the molecules. Many functional devices have been…

Molecular electronics is a fascinating area of research with the ability to tune device properties by a chemical tailoring of organic molecules. However, molecular electronics devices often suffer from dispersion and lack of reproducibility…

Mesoscale and Nanoscale Physics · Physics 2013-02-11 Nicolas Clement , David Guerin , Stephane Pleutin , Sylvie Godey , Dominique Vuillaume

We propose an objective and robust method to extract the electrical conductance of single molecules connected to metal electrodes from a set of measured conductance data. Our method roots in the physics of tunneling and is tested on…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 M. Teresa González , Songmei Wu , Roman Huber , Sense J. van der Molen , Christian Schönenberger , Michel Calame

Molecular junctions comprise small molecules on the order of one or a few nanometers in length, chemically attached to two electrodes of metal or semiconductors. They have recently been identified as promising candidates for…

Mesoscale and Nanoscale Physics · Physics 2021-11-12 Andrea Gemma , Bernd Gotsmann

In the field of molecular electronics, particularly in quantum transport studies, the orientation of molecules plays a crucial role. This orientation, with respect to the electrodes, can be defined through the cavity of ring-shaped…

Materials Science · Physics 2023-02-17 A. Martinez-Garcia , T. de Ara , L. Pastor-Amat , C. Untiedt , E. B. Lombardi , W. Dednam , C. Sabater

Commercially successful magnetic tunnel junction can harness the unmatched capabilities of molecular device elements by solving decade-old fabrication issues. Utilization of magnetic tunnel junction as a testbed for molecules also enables…

Materials Science · Physics 2020-08-10 Pawan Tyagi , Christopher Riso

The appealing feature of molecular electronics is the possibility of exploiting functionality built within a single molecule. This functionality can be employed, for example, for sensing or switching purposes. Thus, ideally, the associated…

We review charge transport across molecular monolayers, which is central to molecular electronics (MoE) using large-area junctions (NmJ). We strive to provide a wide conceptual overview of three main sub-topics. First, a broad introduction…

Materials Science · Physics 2017-03-17 Ayelet Vilan , Dinesh Aswal , David Cahen

Transport properties of metal-molecule-metal junctions containing monolayer of conjugated and saturated molecules with characteristic dimensions in the range of 30-300 nm are correlated with microscopic topography, stress and chemical…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Nikolai B. Zhitenev , Weirong Jiang , Artur Erbe , Zhenan Bao , Eric Garfunkel , Donald M. Tennant , Raymond A. Cirelli

Electrically connected and plasmonically enhanced molecular junctions combine the optical functionalities of high field confinement and enhancement (cavity function), and of high radiative efficiency (antenna function) with the electrical…

As the dimensions of a conductor approach the nano-scale, quantum effects will begin to dominate its behavior. This entails the exciting possibility of controlling the conductance of a device by direct manipulation of the electron wave…

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