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The existence of a new two dimensional CN2 structure was predicted using ab-initio molecular dynamics (AIMD) and density-functional theory calculations. It consists tetragonal and hexagonal rings with C-N and N-N bonds arranged in a…

Materials Science · Physics 2021-01-29 Qun Wei , Ying Yang , Alexander Gavrilov , Xihong Peng

Tin sulfides SnxSy are important class of materials that are actively investigated as novel photovoltaic and water splitting materials. First-principles evolutionary crystal structure search is performed with the goal of constructing the…

Materials Science · Physics 2017-10-11 Joseph M. Gonzalez , Kien Nguyen-Cong , Brad A. Steele , Ivan I. Oleynik

We have studied by means of high-pressure x-ray diffraction the structural stability of Ni2Mo3N, Co3Mo3N, and Fe3Mo3N. We also report ab initio computing modeling of the high-pressure properties of these compounds, Pd2Mo3N, and Pt2Mo3N. We…

A number of diverse bulk properties of the zincblende and wurtzite III-V nitrides AlN, GaN, and InN, are predicted from first principles within density functional theory using the plane-wave ultrasoft pseudopotential method, within both the…

Materials Science · Physics 2009-10-31 A. Zoroddu , F. Bernardini , P. Ruggerone , V. Fiorentini

Nitriding introduces nitrides into the surface of steels, significantly enhancing the surface me-chanical properties. By combining the variable composition evolutionary algorithm and first-principles calculations based on density functional…

Materials Science · Physics 2024-11-27 Ergen Bao , Jinbin Zhao , Qiang Gao , Ijaz Shahid , Hui Ma , Yixiu Luo , Peitao Liu , Yan Sun , Xing-Qiu Chen

Using density functional theory (DFT), the structural, mechanical, electronic, thermal, and optical properties of Hf2AB (A = Pb, Bi) borides were studied, considering the pressure effect up to 50 GPa. The lattice constants were found to be…

Materials Science · Physics 2022-12-20 M. S. Hossain , N. Jahan , M. M. Hossain , M. M. Uddin , M. A. Ali

First-principles crystal structure search is performed to predict novel rubidium poly-nitrogen materials at high pressure by varying the stoichiometry, i. e. relative quantities of the constituent rubidium and nitrogen atoms. Three…

Materials Science · Physics 2017-11-29 Ashley S. Williams , Brad A. Steele , van I. Oleynik

Density functional theory based study of the pressure dependent physical properties of binary SnS compound has been carried out. The computed elastic constants reveal that SnS is mechanically stable and brittle under ambient conditions.…

Materials Science · Physics 2022-10-31 Ayesha Tasnim , Md. Mahamudujjaman , Md. Asif Afzal , R. S. Islam , S. H. Naqib

Understanding the complexities of electronic and magnetic ground states in solids is one of the main goals of solid-state physics. Materials with the canonical ThCr$_2$Si$_2$-type structure have proved particularly fruitful in this regards,…

Strongly Correlated Electrons · Physics 2015-06-12 James R. Neilson , Anna Llobet , Jiajia Wen , Matthew R. Suchomel , Tyrel M. McQueen

NaSn2P2 is a recently discovered superconducting system belonging to a particular class of materials with van der Waals structure. There is enormous interest in such compounds because of their intriguing electrical, optical, chemical,…

Materials Science · Physics 2020-11-24 F. Parvin , S. H. Naqib

Low-dimensional Si-based semiconductors are unique materials that can both match well with the Si-based electronics and satisfy the demand of miniaturization in modern industry. Owing to the lack of such materials, many researchers put…

Materials Science · Physics 2018-07-06 Yan Qian , Zhengwei Du , Renzhu Zhu , Haiping Wu , Erjun Kan , Kaiming Deng

Two dimensional allotropes of group IV substrates including silicene, germanene and stanene have recently attracted considerable attention in nanodevice fabrication industry. These materials involving the buckled structure have been…

Materials Science · Physics 2017-04-17 B Mortazavi , O Rahaman , M Makaremi , A Dianat , G Cuniberti , T Rabczuk

The polymeric phase of nitrogen connected by the lower (than three) order N-N bonds has been long sought after for the potential application as high energy density materials. Here we report a hitherto unknown polymeric N$_2$H phase…

Materials Science · Physics 2015-03-16 Ketao Yin , Yanchao Wang , Hanyu Liu , Feng Peng , Lijun Zhang

The high-pressure behavior of two Mn-based honeycomb-structured magnetoelectric materials, Mn4Nb2O9 (MNO) and Mn4Ta2O9 (MTO), was investigated using Raman spectroscopy, synchrotron x-ray diffraction, and density functional theory (DFT)…

A report of progress in spintronics-related works involving group III nitrides is given emphasizing contradictory opinions concerning basics characteristics of these materials. The actual position of magnetic impurities in the GaN lattice…

Materials Science · Physics 2015-06-24 Tomasz Dietl

Recent advances in theoretical structure prediction methods and high-throughput computational techniques are revolutionizing experimental discovery of the thermodynamically stable inorganic materials. Metastable materials represent a new…

Layered SnAs-based Zintl compounds exhibit a distinctive electronic structure, igniting extensive research efforts in areas of superconductivity, topological insulators and quantum magnetism. In this paper, we systematically investigate the…

First principles calculations of the vibrational, thermodynamic and mechanical properties of the Ni-Ti-Sn Heusler and half-Heusler compounds have been performed. First, we have calculated the Raman and infrared spectra of NiTiSn, providing…

Materials Science · Physics 2013-09-30 P. Hermet , K. Niedziolka , P. Jund

The structural, electronic, and elastic properties of three mixed transition metal carbonitrides TiNxC1-x, ZrNxC1-x, and HfNxC1-x (0<x<1) with the rock-salt structure were calculated at ambient and elevated up to 50 GPa hydrostatic…

Materials Science · Physics 2014-03-11 V. Krasnenko , M. G. Brik

We have performed first principles total energy calculations to investigate the structural and reactivity parameters of novel N12X12H12 (X=B, Al, Ga, In, TI) nitrides, in their coronene-like (C24H12) structure to simulate these sheets. The…

Materials Science · Physics 2009-07-31 E. Chigo Anota , M. Salazar Villanueva , H. Hernandez Cocoletzi