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Density Functional Tight-Binding (DFTB), an approximative approach derived from Density Functional Theory (DFT), has the potential to pave the way for simulations of large periodic or non-periodic systems. We have specifically tailored DFTB…

We have predicted a new phase of nitrogen with octagon structure in our previous study, which we referred to as octa-nitrogene (ON). In this work, we make further investigation on its electronic structure. The phonon band structure has no…

Materials Science · Physics 2018-01-29 Wanxing Lin , Jiesen Li , Weiliang Wang , Shi-Dong Liang , Dao-Xin Yao

The large bandgap and strong covalent bonds of hexagonal boron nitride (hBN) had long been thought to be chemically inert. Due to its inertness with saturated robust covalent bonds, the pristine 2D monolayer hBN cannot be functionalized for…

Materials Science · Physics 2024-04-22 Lokesh Yadav , Srimanta Pakhira

The recent experimental synthesis of 2D graphitic C3N5 has attracted lot of interests in its electronic and optical properties and its comparison with other graphitic C3N4 and C3N3. To this end, we performed DFT calculations using more…

Materials Science · Physics 2022-07-19 Shakti Singh , P. Anees , Sharat Chandra , Tapan Ghanty

Two-dimensional (2D) carbon-based materials have attracted considerable interest due to their diverse structural and electronic properties, making them ideal for next-generation flat electronics. Among these materials, metallic-like porous…

In our previous study, we have predicted the novel two-dimensional honeycomb monolayers of pnictogen. In particular, the structure and properties of the honeycomb monolayer of nitrogen, which we call nitrogene, are very unusual. In this…

Materials Science · Physics 2016-10-04 Jie-Sen Li , Wei-Liang Wang , Dao-Xin Yao

In this study we present a theoretical investigation of structural, electronic and mechanical properties of pentagonal monolayers of carbon (p-graphene), boron nitride (p-B$_{2}$N$_{4}$ and p-B$_{4}$N$_{2}$) and silver azide (p-AgN$_{3}$)…

Materials Science · Physics 2015-10-06 M. Yagmurcukardes , H. Sahin , J. Kang , E. Torun , F. M. Peeters , R. T. Senger

BaZn2As2 is expected for a good p-type semiconductor and has two crystalline phases of an orthorhombic alpha phase and a higher-symmetry tetragonal beta phase. Here, we report high-quality epitaxial films of the tetragonal beta-BaZn2As2…

Materials Science · Physics 2013-12-03 Zewen Xiao , Fan-Yong Ran , Hidenori Hiramatsu , Satoru Matsuishi , Hideo Hosono , Toshio Kamiya

Successful synthesis of the nitrogenated holey two-dimensional structures C2N (Nat. Commun. 2015, 6, 1-7) using simply wet-chemical reaction offer a cost-effective way to generate other 2D materials with novel optical and electronic…

Materials Science · Physics 2015-05-12 Ruiqi Zhang , Bin Li , Jinlong Yang

The light-like dispersion of graphene monolayer results in many novel electronic properties in it1, however, this gapless feature also limits the applications of graphene monolayer in digital electronics2. A rare working solution to…

Mesoscale and Nanoscale Physics · Physics 2016-09-02 Si-Yu Li , Mei Zhou , Jia-Bin Qiao , Wenhui Duan , Lin He

The existence of a new two dimensional CN2 structure was predicted using ab-initio molecular dynamics (AIMD) and density-functional theory calculations. It consists tetragonal and hexagonal rings with C-N and N-N bonds arranged in a…

Materials Science · Physics 2021-01-29 Qun Wei , Ying Yang , Alexander Gavrilov , Xihong Peng

By performing density functional theory-based calculations, we investigate how hydrogen atom interacts with the surfaces of monolayer PbI2 and how one and two side hydrogenation modify its structural, electronic, and magnetic properties.…

Mesoscale and Nanoscale Physics · Physics 2016-07-22 C. Bacaksiz , H. Sahin

The theoretical discovery of new and stable 2D penta materials has stimulated the technological advancement due to the anticipated exotic properties of such structure, including the recent $\alpha$ phase and $\beta$ phase of penta-NiPS…

Two-dimensional (2D) lattices composed exclusively of pentagons represent an exceptional structure of materials correlated to the famous pentagonal tiling problem in mathematics, but their $\pi$-conjugation and the related electronic…

Materials Science · Physics 2018-09-12 Xiaofei Shao , Xiaobiao Liu , Xinrui Zhao , Junru Wang , Xiaoming Zhang , Mingwen Zhao

Tetra-Penta-Deca-Hexa-graphene (TPDH) is a new 2D carbon allotrope with attractive electronic and mechanical properties. It is composed of tetragonal, pentagonal, and hexagonal carbon rings. When TPDH-graphene is sliced into…

Materials Science · Physics 2024-07-01 Juan Gomez Quispe , Douglas Soares Galvao , Pedro Alves da Silva Autreto

Searching for materials with single atom-thin as well as planar structure, like graphene and borophene, is one of the most attractive themes in two dimensional materials. Herein, using density functional theory calculations, we have…

Materials Science · Physics 2024-09-17 Jun-Hui Yuan , Biao Zhang , Ya-Qian Song , Jia-Fu Wang , Kan-Hao Xue , Xiang-Shui Miao

A specific structure of doped graphene with substituted silicon impurity is introduced and ab. initio density-functional approach is applied for energy band structure calculation of proposed structure. Using the band structure calculation…

Mesoscale and Nanoscale Physics · Physics 2011-03-01 Mohammad S. Sharif Azadeh , Alireza Kokabi , Mehdi Hosseini , Mehdi Fardmanesh

We report a detailed theoretical study of the structural, vibrational, and optical properties of solid nitromethane using first principles density functional calculations. The ground state properties were calculated using a plane wave…

Materials Science · Physics 2015-06-17 S. Appalakondaiah , G. Vaitheeswaran , S. Lebegue

Two-dimensional (2D) metallic systems with intrinsically low lattice thermal conductivity are rare, yet they are of great interest for next-generation energy and electronic technologies. Here, we present a comprehensive first-principles…

The structural profiles and electronic properties of pentacene (C$_{22}$H$_{14}$) multilayers on Ag(111) surface has been studied within the density functional theory (DFT) framework. We have performed first-principle total energy…

Materials Science · Physics 2011-01-06 Ersen Mete , Ilker Demiroglu , M. Fatih Danisman , Sinasi Ellialtioglu