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We study macroscopic observables defined as the total value of a physical quantity over a collection of quantum systems. We show that previous results obtained for infinite ensemble of identically prepared systems lead to incorrect…

Quantum Physics · Physics 2009-11-10 David Poulin

The concept of entropy has been pivotal in the formulation of thermodynamics. For systems driven away from thermal equilibrium, a comparable role is played by entropy production and dissipation. Here we provide a comprehensive picture how…

Soft Condensed Matter · Physics 2025-05-15 Robin Bebon , Joshua F. Robinson , Thomas Speck

We analyze a gas of noninteracting fermions confined to a one-dimensional harmonic oscillator potential, with the aim of distinguishing between two proposed definitions of the thermodynamic entropy in the microcanonical ensemble, namely the…

Statistical Mechanics · Physics 2017-03-13 Kenneth J. Higginbotham , Daniel E. Sheehy

The postulates of thermodynamics were originally formulated for macroscopic systems. They lead to the definition of the entropy, which, for a homogeneous system, is a homogeneous function of order one in the extensive variables and is…

Statistical Mechanics · Physics 2018-11-14 Dragos-Victor Anghel , Alexandru S. Parvan

New methods are presented which enables one to analyze the thermodynamics of systems with long-range interactions. Generically, such systems have entropies which are non-extensive, (do not scale with the size of the system). We show how to…

General Relativity and Quantum Cosmology · Physics 2009-11-07 Jonathan Oppenheim

The precision of nonequilibrium thermodynamic systems is fundamentally limited, yet how quantum coherence shapes these limits remains largely unexplored. A general theoretical framework is introduced that explicitly links quantum coherence…

Quantum Physics · Physics 2025-10-27 Shanhe Su , Cong Fu , Ousi Pan , Shihao Xia , Fei Liu , Jincan Chen

On the basis of information theory, a new formalism of classical non-relativistic mechanics of a mass point is proposed. The particle trajectories of a general dynamical system defined on an (1+n)-dimensional smooth manifold are treated…

Quantum Physics · Physics 2014-07-30 Yoshimasa Kurihara , Khiem Hong Phan , Nhi My Uyen Quach

Universality of classical thermodynamics rests on the central limit theorem, due to which, measurements of thermal fluctuations are unable to reveal detailed information regarding the microscopic structure of a macroscopic body. When small…

Quantum Physics · Physics 2024-02-28 Lucas Chibebe Céleri , Łukasz Rudnicki

The aim of this work is to analyze the entropy, entropy flux and entropy supply rate of granular fluids within the frameworks of the Boltzmann equation and continuum thermodynamics. It is shown that the entropy inequality for a granular gas…

Statistical Mechanics · Physics 2010-11-17 Gilberto M. Kremer

Understanding stochastic thermodynamics of active Brownian particles (ABPs) system has been an important topic in very recent years. In this article we study a general model of active Brownian particle systems by introducing a…

Statistical Mechanics · Physics 2022-05-11 Zhiyu Cao , Jie Su , Huijun Jiang , Zhonghuai Hou

To the student of thermodynamics the most difficult subject is entropy. In this paper we examine the actual, practical application of entropy to two simple systems, the homogeneous slab with fixed boundary values of the temperature, and an…

Statistical Mechanics · Physics 2015-05-28 Christian Frønsdal , Abhishek Pathak

In this paper, we discuss information-theoretic tools for obtaining optimized coarse-grained molecular models for both equilibrium and non-equilibrium molecular dynamics. The latter are ubiquitous in physicochemical and biological…

Numerical Analysis · Mathematics 2016-04-20 Vagelis Harmandaris , Evangelia Kalligiannaki , Markos A. Katsoulakis , Petr Plecháč

We show that the naive application of the maximum entropy principle can yield answers which depend on the level of description, i.e. the result is not invariant under coarse-graining. We demonstrate that the correct approach, even for…

Statistical Mechanics · Physics 2007-05-23 Jayanth Banavar , Amos Maritan

It is known that the variance and entropy of quantum observables decompose into intrinsically quantum and classical contributions. Here a general method of constructing quantum-classical decompositions of resources such as uncertainty is…

Quantum Physics · Physics 2023-07-07 Michael J. W. Hall

In this work we study the evolution of Boltzmann's entropy in the context of free expansion of a one dimensional interacting gas inside a box. Boltzmann's entropy is defined for single microstates and is given by the phase-space volume…

Statistical Mechanics · Physics 2023-03-29 Subhadip Chakraborti , Abhishek Dhar , Anupam Kundu

We set up a framework for quantum stochastic thermodynamics based solely on experimentally controllable, but otherwise arbitrary interventions at discrete times. Using standard assumptions about the system-bath dynamics and insights from…

Quantum Physics · Physics 2019-08-22 Philipp Strasberg

A pedagogical derivation of statistical mechanics from quantum mechanics is provided, by means of open quantum systems. Besides, a new definition of Boltzmann entropy for a quantum closed system is also given to count microstates in a way…

High Energy Physics - Theory · Physics 2015-04-08 Yu-Lei Feng , Yi-Xin Chen

Gravity is a macroscopic manifestation of a microscopic quantum theory of space-time, just as the theories of elasticity and hydrodynamics are the macroscopic manifestation of the underlying quantum theory of atoms. The connection of…

High Energy Physics - Theory · Physics 2011-01-31 George F. Smoot

We numerically analyze the dynamical generation of quantum entanglement in a system of 2 interacting particles, started in a coherent separable state, for decreasing values of $\hbar$. As $\hbar\to 0$ the entanglement entropy, computed at…

Quantum Physics · Physics 2015-05-30 Giulio Casati , Italo Guarneri , Jose Reslen

Thermodynamics can be formulated in either of two approaches, the phenomenological approach, which refers to the macroscopic properties of systems, and the statistical approach, which describes systems in terms of their microscopic…

Quantum Physics · Physics 2019-05-01 Mirjam Weilenmann , Lea Krämer Gabriel , Philippe Faist , Renato Renner
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