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A new, more comprehensive model of gas-grain chemistry in hot molecular cores is presented, in which nondiffusive reaction processes on dust-grain surfaces and in ice mantles are implemented alongside traditional diffusive surface/bulk-ice…

Astrophysics of Galaxies · Physics 2022-02-23 Robin T. Garrod , Mihwa Jin , Kayla A. Matis , Dylan Jones , Eric R. Willis , Eric Herbst

In recent years, a significant number of oxygen-bearing complex organic molecules (COMs) have been detected in the gas phase of cold dark clouds such as TMC-1. The formation of these COMs cannot be explained by diffusive mechanisms on…

Astrophysics of Galaxies · Physics 2024-12-10 Yang Lu , Donghui Quan , Qiang Chang , Long-Fei Chen , Di Li

We present a publicly available, open source version of the time dependent gas-grain chemical code UCLCHEM. UCLCHEM propagates the abundances of chemical species through a large network of chemical reactions in a variety of physical…

Astrophysics of Galaxies · Physics 2017-07-25 Jonathan Holdship , Serena Viti , Izaskun Jiménez-Serra , Antonios Makrymallis , Felix Priestley

Complex organic molecules (COMs) have been detected in a variety of interstellar sources. The abundances of these COMs in warming sources can be explained by syntheses linked to increasing temperatures and densities, allowing quasi-thermal…

Astrophysics of Galaxies · Physics 2020-11-18 Alec Paulive , Christopher N. Shingledecker , Eric Herbst

Complex organic molecules (COMs) have been identified in different environments in star- forming regions. Laboratory studies show that COMs form in the solid state, on icy grains, typically following a non-energetic (atom-addition) or…

Astrophysics of Galaxies · Physics 2017-05-23 K. -J. Chuang , G. Fedoseev , D. Qasim , S. Ioppolo , E. F. van Dishoeck , H. Linnartz

Recent observations have revealed the existence of Complex Organic Molecules (COMs) in cold dense cores and prestellar cores. The presence of these molecules in such cold conditions is not well understood and remains a matter of debate…

Solar and Stellar Astrophysics · Physics 2015-06-23 M. Ruaud , J. C. Loison , K. M. Hickson , P. Gratier , F. Hersant , V. Wakelam

A prevailing theory for the interstellar production of complex organic molecules (COMs) involves formation on warm dust-grain surfaces, via the diffusion and reaction of radicals produced through grain-surface photodissociation of stable…

Astrophysics of Galaxies · Physics 2020-08-19 Mihwa Jin , Robin T. Garrod

Gas-phase processes were long thought to be the key formation mechanisms for complex organic molecules in star-forming regions. However, recent experimental and theoretical evidence has cast doubt on the efficiency of such processes.…

Astrophysics · Physics 2009-11-13 Robin T. Garrod , Susanna L. Widicus Weaver , Eric Herbst

Cold dense cores are unique among the structures found in the interstellar medium (ISM), as they harbor a rich chemical inventory, including complex organic molecules (COMs), which will be inherited by future evolutionary stages. These…

Astrophysics of Galaxies · Physics 2025-04-28 S. Maitrey , Liton Majumdar , Varun Manilal , Baibhav Srivastava , Prathap Rayalacheruvu , Karen Willacy , Eric Herbst

We investigate the roles of stochastic grain heating in the formation of complex organic molecules (COMs) in cold cores, where COMs have been detected. Two different types of grain-size distributions are used in the chemical models. The…

Astrophysics of Galaxies · Physics 2022-09-21 Long-Fei Chen , Qiang Chang , Yao Wang , Di Li

We present the results of astrochemical modeling of complex organic molecules (COMs) in the ice and gas of the prestellar core L1544 with the recently updated MONACO rate equations-based model. The model includes, in particular,…

Observations of gaseous complex organic molecules (COMs) in cold starless and prestellar cloud cores require efficient desorption of the COMs and their parent species from icy mantles on interstellar grains. With a simple astrochemical…

Astrophysics of Galaxies · Physics 2022-07-04 Juris Kalvāns , Kedron Silsbee

Chemical models and experiments indicate that interstellar dust grains and their ice mantles play an important role in the production of complex organic molecules (COMs). To date, the most complex solid-phase molecule detected with…

Complex organic molecules (COMs), the building blocks of life, have been extensively detected under various physical conditions, from quiescent clouds to star-forming regions. They therefore serve as excellent tracers for the local physical…

The recent discovery of methyl formate and dimethyl ether in the gas phase of cold cores with temperatures as cold as 10 K challenges our previous astrochemical models concerning the formation of complex organic molecules. The strong…

Solar and Stellar Astrophysics · Physics 2016-03-23 Qiang Chang , Eric Herbst

Recent astrochemical models and experiments have explained that complex organic molecules (COMs; molecules composed of six or more atoms) are produced on the dust grain mantles in cold and dense gas in prestellar cores. However, the…

Astrophysics of Galaxies · Physics 2022-11-16 Giseon Baek , Jeong-Eun Lee , Tomoya Hirota , Kee-Tae Kim , Mi Kyoung Kim

Complex organic molecules (COMs) have been detected abundantly at various stages of star formation, particularly in the warm protostellar phase. The progress in gas-phase measurements has been accelerated by the advent of the Atacama Large…

Astrophysics of Galaxies · Physics 2025-10-20 P. Nazari

A magnetohydrodynamic model of a steady, transverse C-type shock in a dense molecular cloud is presented. A complete gas-grain chemical network is taken into account: the gas-phase chemistry, the adsorption of gas species on dust grains,…

Astrophysics of Galaxies · Physics 2018-06-12 A. V. Nesterenok

Molecular complexity builds up at each step of the Sun-like star formation process, starting from simple molecules and ending up in large polyatomic species. Complex organic molecules (COMs; such as methyl formate, HCOOCH$_3$, dymethyl…

In this paper, we present preliminary results illustrating the effect of cosmic rays on solid-phase chemistry in models of both TMC-1 and several sources with physical conditions identical to TMC-1 except for hypothetically enhanced…

Astrophysics of Galaxies · Physics 2018-07-11 Christopher N. Shingledecker , Jessica D. Tennis , Romane Le Gal , Eric Herbst
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