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We present a theoretical study of wetting phenomena and interactions between liquid-vapor interfaces based on the density functional theory. The focus is mostly on the impact of long-range van der Waals interactions both within the fluid…

Chemical Physics · Physics 2011-11-10 Arik Yochelis , Len M. Pismen

We study the wetting model, which considers a random walk constrained to remain above a hard wall, but with additional pinning potential for each contact with the wall. This model is known to exhibit a wetting phase transition, from a…

Probability · Mathematics 2023-09-19 Quentin Berger , Brune Massoulié

We present results of a microscopic density functional theory study of wedge filling transitions, at a right-angle wedge, in the presence of dispersion-like wall-fluid forces. Far from the corner the walls of the wedge show a first-order…

Statistical Mechanics · Physics 2013-04-19 Alexandr Malijevsky , Andrew O. Parry

Through Monte Carlo simulations and the Associating Lattice Gas Model, the phases of a two-dimensional fluid under hydrophilic confinement are evaluated. The model, in its unconfined version, reproduces the anomalous behavior of water…

In this two-part study we investigate the phase behaviour of a fluid spatially confined in a semi-infinite rectangular pore formed by three orthogonal walls and connected to a reservoir maintaining constant values of pressure and…

Soft Condensed Matter · Physics 2013-09-23 P. Yatsyshin , N. Savva , S. Kalliadasis

Although realizing wetting transitions of droplets spontaneously on solid rough surfaces is quite challenging, it is becoming a key research topic in many practical applications which require highly efficient removal of liquid. We report…

Soft Condensed Matter · Physics 2015-06-30 Cunjing Lv , Pengfei Hao , Xiwen Zhang , Feng He

The properties of the coexisting bulk gas and liquid phases of a polydisperse fluid depend not only on the prevailing temperature, but also on the overall parent density. As a result, a polydisperse fluid near a wall will exhibit…

Statistical Mechanics · Physics 2009-11-11 Matteo Buzzacchi , Nigel B. Wilding , Peter Sollich

The unbinding properties of an interface near structured wedges are investigated by discrete models with short range interactions. The calculations demonstrate that interface unbinding take place in two stages: $i$) a continuous…

Statistical Mechanics · Physics 2009-11-11 Gilberto Giugliarelli

Within Gross-Pitaevskii (GP) theory we derive the interface potential V (l) which describes the interaction between the interface separating two demixed Bose-condensed gases and an optical hard wall at a distance l. Previous work revealed…

Quantum Gases · Physics 2022-05-27 Bert Van Schaeybroeck , Patrick Navez , Joseph O. Indekeu

We have carried out extensive equilibrium molecular dynamics (MD) simulations to study the structure and the interfacial properties in the liquid-vapor (LV) phase coexistence of partially miscible binary Lennard-Jones (LJ) mixtures. By…

Soft Condensed Matter · Physics 2009-11-10 Enrique Díaz-Herrera , José A. Moreno-Razo , Guillermo Ramírez-Santiago

We report on the onset of fluid entrainment when a contact line is forced to advance over a dry solid of arbitrary wettability. We show that entrainment occurs at a critical advancing speed beyond which the balance between capillary,…

Soft Condensed Matter · Physics 2015-06-16 Rodrigo Ledesma-Aguilar , Aurora Hernández-Machado , Ignacio Pagonabarraga

We investigate the interaction between an infinite cylinder and a free fluid-fluid interface governed only by its surface tension. We study the deformation of an initially flat interface when it is deformed by the presence of a cylindrical…

Soft Condensed Matter · Physics 2012-08-15 Christophe Raufaste , Geoffroy Kirstetter , Franck Celestini , Simon Cox

The influence of the external pressure and surface energy on the wetting transition at nanotextured interfaces is studied using molecular dynamics and continuum simulations. The surface roughness of the composite interface is introduced via…

Soft Condensed Matter · Physics 2018-07-12 Bishal Bhattarai , Nikolai V. Priezjev

We report a theoretical and simulation study of the drying and wetting phase transitions of a truncated Lennard-Jones fluid at a flat structureless wall. Binding potential calculations predict that the nature of these transitions depends on…

Statistical Mechanics · Physics 2017-09-13 Robert Evans , Maria C. Stewart , Nigel B. Wilding

For one-component volatile fluids governed by dispersion forces an effective interface Hamiltonian, derived from a microscopic density functional theory, is used to study complete wetting of geometrically structured substrates. Also the…

Statistical Mechanics · Physics 2009-11-13 M. Tasinkevych , S. Dietrich

For one-component fluids, we predict a pre-dewetting phase transition between a thin and thick low-density layer in liquid on a wall repelling the fluid. This is the case of a hydrophobic wall for water. A pre-dewetting line starts from the…

Soft Condensed Matter · Physics 2015-05-30 Ryohei Teshigawara , Akira Onuki

We study the pinning transition in a (1+1)-dimensional lattice model of a fluctuating interface interacting with a corrugated impenetrable wall. The interface is modeled as an $N$-step directed one-dimensional random walk on the half-line…

Statistical Mechanics · Physics 2026-01-06 Ruijie Xu , Sergei Nechaev

We study adsorption at periodically corrugated substrates formed by scoring rectangular grooves into a planar solid wall which interacts with the fluid via long-range (dispersion) forces. The grooves are assumed to be macroscopically long…

Statistical Mechanics · Physics 2020-07-21 Alexandr Malijevský

We briefly discuss how the wetting properties of a fluid/solid interface can indirectly influence the diffusion properties of fluid confined between two solid walls. This influence is related to the variability of the hydrodynamic boundary…

Soft Condensed Matter · Physics 2007-05-23 Yannick Alméras , Jean-Louis Barrat , Lydéric Bocquet

This study has numerically investigated the effect of surface wettability on two-phase immiscible flow and dynamics of droplet pinch-off in a T-junction microchannel using finite element method. A conservative level set method (CLSM) has…

Fluid Dynamics · Physics 2022-12-01 Akepogu Venkateshwarlu , Ram Prakash Bharti