Related papers: Waste forms for actinides: borosilicate glasses
Controlling nanostructure from molecular, crystal lattice to the electrode level remains as arts in practice, where nucleation and growth of the crystals still require more fundamental understanding and precise control to shape the…
Long-term solutions for the disposal of toxic wastes usually involve isolation of the wastes in a deep subsurface geologic environment. In the case of spent nuclear fuel, if radionuclide leakage occurs from the engineered barrier, the…
Gaining control over the motion of active particles is crucial for applications ranging from targeted cargo delivery to nanomedicine. While much progress has been made recently to control active motion based on external forces, flows or…
Charged colloids can form ordered structures like Wigner crystals or glasses at very low concentrations due to long-range electrostatic repulsions. Here, we combine small-angle x-ray scattering (SAXS) and optical experiments with…
December 1991 legislation in France has spurred research on enhanced separation and conditioning or transmutation of long-lived radionuclides from high level radioactive wastes (HLW). In this field, we have studied zirconolite-based…
Actinide-based compounds exhibit unique physics due to the presence of 5f electrons, and serve in many cases as important technological materials. Targeted thin film synthesis of actinide materials has been successful in generating…
Unlike crystals, glasses age or devitrify over time, reflecting their non-equilibrium nature. This lack of stability is a serious issue in many industrial applications. Here, we show by numerical simulations that the devitrification of…
Future decades will experience tons of silicon waste from various sources, with no reliable recycling route. The transformation of bulk silicon into SiO2 nanoparticles is environmentally significant because it provides a way to recycle…
Atomic cells made by anodically bonding silicon and borosilicate glasses are widely used in atomic devices. One inherent problem in these cells is that the silicon material blocks beams with wavelengths shorter than 1000 nm, which limits…
Alkali and alkaline earth aluminoborate glasses feature high resistance to cracking under sharp contact loading compared to other oxide glasses. However, due to the high content of hygroscopic B2O3, it is expected that applications of these…
Vitrification in colloidal systems typically occurs at high densities driven by sharply varying, short-ranged interactions. The possibility of glassy behavior arising from smoothly varying, long-ranged particle interactions has received…
An environmental survey was carried out in order to provide an adequate and updated assessment of the radiological impact that the decommissioning operations of the Garigliano NNP may have procured to the environment of the surrounding…
Core optics components for high precision measurements are made of stable materials, having small optical and mechanical dissipation. The natural choice in many cases is glass, in particular fused silica. Glass is a solid amorphous state of…
The idea of a novel labeling method is suggested for a new way of long-term security identification, inventory tracking, prevention of falsification and theft of waste casks, copper canisters, spent fuel containers, mercury containers,…
Lithium disilicate glasses and glass-ceramics are good potential candidates for biomedical applications and solid-state batteries, and serve as models of nucleation and crystal growth. Moreover, these glasses exhibit a phase separation that…
In enzymatic recycling or biodegradation of semi-crystalline plastic waste, crystalline spherulites embedded into an amorphous matrix hinder and slow down depolymerisation. When the enzymatic depolymerisation temperature exceeds the glass…
Phase selection in deeply undercooled liquids and devitrified glasses during heating involves complex interplay between the barriers to nucleation and the ability for these nuclei to grow. During the devitrification of glassy alloys,…
Mineral dissolution in porous media coupled with single- or multi-phase flows is pervasive in natural and engineering systems including carbon capture and sequestration (CCS) and acid stimulation in reservoir engineering. Dissolution of…
Our goal is the mathematical analysis of a two phase (liquid and gas) two components (water and hydrogen) system modeling the hydrogen displacement in a storage site for radioactive waste. We suppose that the water is only in the liquid…
Although the multimessenger detection of the neutron star merger event GW170817 confirmed that mergers are promising sites producing the majority of nature's heavy elements via the rapid neutron-capture process ($r$-process), a number of…