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The small cross section of Raman scattering poses a great challenge for its direct study at the single-molecule level. By exploiting the high Franck-Condon factor of a common-mode resonance, choosing a large vibrational frequency difference…

Vibronic spectra of molecules are typically described within the Franck-Condon model. Here, we show that highly resolved vibronic spectra of large organic molecules on a single layer of MoS$_{2}$ on Au(111) show spatial variations in their…

Mesoscale and Nanoscale Physics · Physics 2020-03-24 Gaël Reecht , Nils Krane , Christian Lotze , Lei Zhang , Alejandro L. Briseno , Katharina J. Franke

This article is an attempt to provide a self consistent picture, including existence analysis and numerical solution algorithms, of the mathematical problems arising from modeling photocurrent transients in Organic-polymer Solar Cells…

Numerical Analysis · Mathematics 2012-06-29 Carlo de Falco , Riccardo Sacco , Maurizio Verri

Optical cycling refers to repeated excitation and spontaneous emission on an electronic transition in an atom or molecule. Optical cycling in molecules can enable a wide range of quantum control and readout techniques, but unfortunately it…

Out-of-time-order correlators (OTOCs) can be used to probe how quickly a quantum system scrambles information when the initial conditions of the dynamics are changed. In sufficiently large quantum systems, one can extract from the OTOC the…

Chemical Physics · Physics 2022-03-31 Chenghao Zhang , Peter G. Wolynes , Martin Gruebele

We identify an intriguing feature of the electron-vibrational dynamics of molecular systems via a computational examination of \emph{trans}-polyacetylene oligomers. Here, via the vibronic interactions, the decay of an electron in the…

Quantum Physics · Physics 2013-04-09 Ignacio Franco , Angel Rubio , Paul Brumer

This thesis is mainly devoted to the study of the quantum properties of optical parametric oscillators (OPOs), which are nowadays the sources of the highest-quality quantum-correlated light, apart from fundamental tools in the…

Quantum Physics · Physics 2015-04-23 Carlos Navarrete-Benlloch

Quantum statistics and symmetrization dictate that identical fermions do not interact via s-wave collisions. However, in the presence of spin-orbit coupling (SOC), fermions prepared in identical internal states with distinct momenta become…

Atomic Physics · Physics 2018-05-09 S. L. Bromley , S. Kolkowitz , T. Bothwell , D. Kedar , A. Safavi-Naini , M. L. Wall , C. Salomon , A. M. Rey , J. Ye

A survey is presented of the dynamic features of non-itinerant off-center defects in crystals, such as rotation-like reorientation of isolated species by either impurity or host ions. The occurrence of off-center displacements in…

Chemical Physics · Physics 2008-12-12 Mladen Georgiev

We study the coupling of internal electronic excitations to vibrational modes of the external motion of ultracold atoms in an optical lattice. For different ground and excited state potentials the on-site coupling of excitations and…

Quantum Physics · Physics 2009-08-11 Hashem Zoubi , Helmut Ritsch

Studying optical properties of organic materials is important due to the rapid development of organic light-emitting diodes, solar cells, and photon detectors. Here for the first time we have performed tight-binding calculations for singlet…

Mesoscale and Nanoscale Physics · Physics 2023-04-06 Q. Chen , J. Chang , L. Ma , C. Li , L. Duan , X. Ji , J. Zhang , W. Wu , H. Wang

Color centers in silicon are emerging as promising platforms for quantum technologies. Among them, the G center has attracted considerable interest owing to its bright telecom O-band single-photon emission and its optically addressable…

Spin-orbit coupling (SOC) describes the relativistic interaction between the spin and momentum degrees of freedom of electrons, and is central to the rich phenomena observed in condensed matter systems. In recent years, new phases of matter…

Mesoscale and Nanoscale Physics · Physics 2016-11-30 Anjan Soumyanarayanan , Nicolas Reyren , Albert Fert , Christos Panagopoulos

Spin-orbit coupling (SOC) in solids normally originates from the electron motion in the electric field of the crystal. It is key to understanding a variety of spin-transport and topological phenomena, such as Majorana fermions and recently…

Quantum Gases · Physics 2014-11-18 Sergey V. Syzranov , Michael L. Wall , Victor Gurarie , Ana Maria Rey

Resonant vibrational-excitation cross sections and rate constants for electron scattering by molecular oxygen are presented. Transitions between all 42 vibrational levels of O$_2(\textrm{X}\ ^3\Sigma_g^- $) are considered. Molecular…

Plasma Physics · Physics 2016-04-21 V Laporta , R Celiberto , J Tennyson

Time-dependent coupled-cluster method with time-varying orbital functions, called time-dependent optimized coupled- cluster (TD-OCC) method, is formulated for multielectron dynamics in an intense laser field. We have successfully derived…

Chemical Physics · Physics 2018-03-14 Takeshi Sato , Himadri Pathak , Yuki Orimo , Kenichi L. Ishikawa

In the few-photon regime, we theoretically propose a feasible scheme to realize strong coupling optomechanical cycle in a three-mode optomechanical circulatory system (OMCS) comprising of cross-Kerr (CK) type and linear coupling between the…

Quantum Physics · Physics 2022-11-22 Cheng Shang , H. Z. Shen , X. X. Yi

Motivated by recent experimental development, we investigate spin-orbit coupled repulsive Fermi atoms in a one-dimensional optical lattice. Using the density-matrix renormalization group method, we calculate momentum distribution function,…

Quantum Gases · Physics 2015-10-09 Xiaofan Zhou , Kuang Zhang , Junjun Liang , Gang Chen , Suotang Jia

Two-photon coherent states are one of the main building pillars of non-linear and quantum optics. It is the basis for the generation of minimum-uncertainty quantum states and entangled photon pairs, applications not obtainable from standard…

Mesoscale and Nanoscale Physics · Physics 2022-05-30 A. A. Reynoso , G. Usaj , D. L. Chafatinos , F. Mangussi , A. E. Bruchhausen , A. S. Kuznetsov , K. Biermann , P. V. Santos , A. Fainstein

Multi-molecular excited states accompanied by an intra- and inter-molecular geometric relaxation are commonly encountered in optical and electrooptical studies and applications of organic semiconductors as, for example excimers or charge…

Materials Science · Physics 2022-11-14 Sebastian Hammer , Theresa Linderl , Kristofer Tvingstedt , Wolfgang Brütting , Jens Pflaum