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One of the hallmarks of molecular dynamics in deeply supercooled liquids is the non-exponential character of the relaxation functions. It has been a long standing issue if 'universal' features govern the lineshape of glassy dynamics…

We investigate the influence of dynamic heterogeneity on the spectral shape of structural relaxation in van der Waals liquids above the melting point by means of depolarized dynamic light scattering. To this end, we study optically…

Soft Condensed Matter · Physics 2026-02-17 Rolf Zeißler , Niklas Pfeiffer , Thomas Blochowicz

Structural relaxation in deeply supercooled liquids is non-exponential. In susceptibility representation, $\chi^{\prime\prime}(\nu)$, the spectral shape of the structural relaxation is observed as an asymmetrically broadened peak with a…

Soft Condensed Matter · Physics 2025-04-01 Till Böhmer , Florian Pabst , Jan Gabriel , Rolf Zeißler , Thomas Blochowicz

The non-exponential character of the structural relaxation is considered one of the hallmarks of the glassy dynamics and in this context, the singular shape observed by dielectric techniques has attracted the attention of the community for…

Soft Condensed Matter · Physics 2023-05-17 Silvia Arrese-Igor , Angel Alegria , Juan Colmenero

The relaxation dynamics and the vibrational spectra of amorphous solids, such as metal alloys, have been intensely investigated as well separated topics in the past. The aim of this review is to summarize recent results in both these areas…

Materials Science · Physics 2020-03-17 Alessio Zaccone

Understanding surface mechanics of soft solids, such as soft polymeric gels, is crucial in many engineering processes, such as dynamic wetting and adhesive failure. In these situations, a combination of capillary and elastic forces drives…

Soft Condensed Matter · Physics 2020-12-02 Qin Xu , Lawrence A. Wilen , Katharine E. Jensen , Robert W. Style , Eric R. Dufresne

Liquids in equilibrium exhibit two types of disorder, simple and complex. Typical simple disorder liquid are liquid nitrogen, or weakly polar liquids. Complex liquids concern those who can form long lived local assemblies, and cover a large…

Chemical Physics · Physics 2023-06-02 Bernarda Lovrinčević , Martina Požar , Ivo Jukić , David Perera , Aurélien Perera

The spectral representation is an effecient tool to explore electrical properties of material mixtures. It separates the contributions of geometrical topology and intrinsic properties of the constituents in the system. The aim of this paper…

Materials Science · Physics 2007-05-23 Enis Tuncer

Soft particulate gels include materials we can eat, squeeze, or 3D print. From foods to bio-inks to cement hydrates, these gels are composed of a small amount of particulate matter (proteins, polymers, colloidal particles, or agglomerates…

Strong correlation between equilibrium fluctuations of the potential energy, U, and the virial, W, is a characteristic of a liquid that implies the presence of certain dynamic properties, such as density scaling of the relaxation times and…

Soft Condensed Matter · Physics 2015-06-11 D. Fragiadakis , C. M. Roland

The frequency dependent specific heat has been measured under pressure for the molecular glass forming liquid 5-polyphenyl-4-ether in the viscous regime close to the glass transition. The temperature and pressure dependence of the…

Soft Condensed Matter · Physics 2015-12-15 Lisa Anita Roed , Kristine Niss , Bo Jakobsen

We have measured depolarized light scattering in liquid benzene over the whole accessible temperature range and over four decades in frequency. Between 40 and 180 GHz we find a susceptibility peak due to structural relaxation. This peak…

Soft Condensed Matter · Physics 2011-04-05 Sabine Wiebel , Joachim Wuttke

Dielectric measurements on molecular liquids just above the glass transition indicate that alpha relaxation is characterized by a generic high-frequency loss varying as $\omega^{-1/2}$, whereas deviations from this come from one or more…

Soft Condensed Matter · Physics 2009-11-11 Jeppe C. Dyre

We introduce a class of continuum mechanical models aimed at describing the behaviour of viscoelastic fluids by incorporating concepts originated in the theory of solid plasticity. Within this class, even a simple model with constant…

Soft Condensed Matter · Physics 2024-09-04 Muhanna A. H Alrashdi , Giulio G. Giusteri

Wetting behaviour of surfaces is believed to be affected by van der Waals (vdW) forces, however, there is no clear demonstration of this. With the isolation of two-dimensional vdW layered materials it is possible to test this hypothesis. In…

Mesoscale and Nanoscale Physics · Physics 2022-01-26 Meenakshi Annamalai , Kalon Gopinadhan , Sang A Han , Surajit Saha , Hye Jeong Park , Eun Bi Cho , Brijesh Kumar , Sang-Woo Kim , T Venkatesan

The coupling behavior of time scales of structural relaxation is investigated on the basis of five different response functions for 1,2,6-hexanetriol, a hydrogen-bonded liquid with a minor secondary contribution, and…

Soft Condensed Matter · Physics 2022-04-15 Lisa A. Roed , Jeppe C. Dyre , Kristine Niss , Tina Hecksher , Birte Riechers

Viscosities and their temperature, T, and volume, V, dependences are reported for 7 molecular liquids and polymers. In combination with literature viscosity data for 5 other liquids, we show that the superpositioning of relaxation times for…

Soft Condensed Matter · Physics 2009-11-11 CM Roland , S Bair , R Casalini

The relaxation dynamics in two van der Waals bonded and one hydrogen-bonding molecular liquids is studied as a function of pressure and temperature by incoherent neutron scattering using simultaneous dielectric spectroscopy. The dynamics is…

Soft Condensed Matter · Physics 2018-09-10 Henriette Wase Hansen , Bernhard Frick , Simone Capaccioli , Alejandro Sanz , Kristine Niss

In this work, we present a high-throughput first-principles study of elastic properties of bulk and monolayer materials mainly using the vdW-DF-optB88 functional. We discuss the trends on the elastic response with respect to changes in…

Materials Science · Physics 2018-07-18 Kamal Choudhary , Gowoon Cheon , Evan Reed , Francesca Tavazza

We propose a novel method for measuring linear and non-linear viscoelastic properties of a liquid by the oscillatory motion of an immersed rotating body in a vessel. The shape of a rotating object is general and we tested four different…

Fluid Dynamics · Physics 2025-05-19 Hye Jin Ahn , Wook Ryol Hwang
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