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If a system is at thermodynamic equilibrium, an observer cannot tell whether a film of it is being played forward or in reverse: any transition will occur with the same frequency in the forward as in the reverse direction. However, if…

Statistical Mechanics · Physics 2020-07-01 John W. Biddle , Jeremy Gunawardena

Nonequilibrium interfacial thermodynamics is formulated in the presence of surface reactions for the study of diffusiophoresis in isothermal systems. As a consequence of microreversibility and Onsager-Casimir reciprocal relations,…

Chemical Physics · Physics 2018-12-24 Pierre Gaspard , Raymond Kapral

When a small dynamical system that is initially in contact with a heat bath is detached from this heat bath and then caused to undergo a quasi-static adiabatic processes, the statistical distribution of the system's energy differs from that…

Statistical Mechanics · Physics 2007-05-23 K. Sato , K. Sekimoto , T. Hondou , F. Takagi

We report on numerical simulations of the dynamics of a test particle coupled to competing Boltzmann heat baths of finite size. After discussing some features of the single bath case, we show that the presence of two heat baths further…

Quantum Physics · Physics 2015-05-18 Qun Wei , S. Taylor Smith , Roberto Onofrio

We consider thermal relaxation process of a quantum system attached to a single or multiple reservoirs. Quantifying the degree of irreversibility by entropy production, we prove that the irreversibility of the thermal relaxation is…

Statistical Mechanics · Physics 2021-11-08 Tan Van Vu , Yoshihiko Hasegawa

A fundamental challenge is to understand nonequilibrium statistical mechanics starting from microscopic chaos in the equations of motion of a many-particle system. In this review we summarize recent theoretical advances along these lines.…

Chaotic Dynamics · Physics 2010-01-04 R. Klages

The thermodynamic uncertainty relation gives a lower bound on the amount of dissipation in a mesoscopic system. By considering the fluctuations in the hysteresis of the current -- the sum of the currents in the time-forward and…

Statistical Mechanics · Physics 2019-09-04 Karel Proesmans , Jordan M. Horowitz

Time reversal invariance (TRI) of particles systems has many consequences, among~which the celebrated Onsager reciprocal relations, a milestone in Statistical Mechanics dating back to 1931. Because for a long time it was believed that (TRI)…

Statistical Mechanics · Physics 2020-08-13 Davide Carbone , Lamberto Rondoni

The relationships between reversible Carnot cycles, the absence of perpetual motion machines and the existence of a non-decreasing, globally unique entropy function forms the starting point of many textbook presentations of the foundations…

Statistical Mechanics · Physics 2015-05-14 O. J. E. Maroney

We consider a quantum particle coupled (with strength $\la$) to a spatial array of independent non-interacting reservoirs in thermal states (heat baths). Under the assumption that the reservoir correlations decay exponentially in time, we…

Mathematical Physics · Physics 2015-05-13 W. De Roeck , J. Frohlich , A. Pizzo

The first Kelvin relation that states the Peltier coefficient should be equal to the product of temperature and Seebeck coefficient is a fundamental principle in thermoelectricity. It has been regarded as an important application and direct…

Statistical Mechanics · Physics 2021-01-20 Yu-Chao Hua , Ti-Wei Xue , Zeng-Yuan Guo

We proved when random-variable fluctuations obey the central limit theorem the equality of the uncertainty relation corresponds to the thermodynamic equilibrium state. The inequality corresponds to the thermodynamic non-equilibrium state.…

Quantum Physics · Physics 2007-05-23 You-gang Feng

The second law of thermodynamics dictates that heat flows spontaneously from a high-temperature entity to a lower-temperature one. Yet, recent advances have demonstrated that quantum correlations between a system and its thermal environment…

One considers the motion of a test particle in an homogeneous fluid in equilibrium at temperature $T$, undergoing dissipative collisions with the fluid particles. It is shown that the corresponding linear Boltzmann equation still posseses a…

Statistical Mechanics · Physics 2007-05-23 Ph. A. Martin , J. Piasecki

We present the stochastic thermodynamics analysis of an open quantum system weakly coupled to multiple reservoirs and driven by a rapidly oscillating external field. The analysis is built on a modified stochastic master equation in the…

Statistical Mechanics · Physics 2015-05-12 Gregory Bulnes Cuetara , Andreas Engel , Massimiliano Esposito

It is shown that the phenomenon of irreversibility in many-body and few-body systems can be explained and described within the framework of the concept of direct (not instantaneous) interaction of particles without using probabilistic…

Statistical Mechanics · Physics 2019-06-26 A. Yu. Zakharov

On the basis of new, concise foundations, this paper establishes the four laws of thermodynamics, the Maxwell relations, and the stability requirements for response functions, in a form applicable to global (homogeneous), local…

Statistical Mechanics · Physics 2007-05-28 Arnold Neumaier

Stochastic thermodynamics extends the notions and relations of classical thermodynamics to small systems that experience strong fluctuations. The definitions of work and heat and the microscopically reversible condition are two key concepts…

Statistical Mechanics · Physics 2019-07-23 Geng Li , Z. C. Tu

Assuming time-scale separation, a simple and unified theory of thermodynamics and stochastic thermodynamics is constructed for small classical systems strongly interacting with its environment in a controllable fashion. The total…

Statistical Mechanics · Physics 2022-08-16 Mingnan Ding , Zhanchun Tu , Xiangjun Xing

Universal properties of the statistics of stochastic efficiency for mesoscopic time-reversal symmetry broken energy transducers are revealed in the Gaussian approximation. We also discuss how the second law of thermodynamics restricts the…

Statistical Mechanics · Physics 2015-07-23 Jian-Hua Jiang , Bijay Kumar Agarwalla , Dvira Segal