Related papers: Isocyanogen formation in the cold interstellar med…
The line intensities of the fundamental rotational transitions of H13CN and HC15N were observed towards two prestellar cores, L183 and L1544, and lead to molecular isotopic ratios 140 6 14N/15N 6 250 and 140 6 14N/15N 6 360, respectively.…
We have obtained deep HI observations in the direction of 22 continuum sources without previously detected cold neutral medium (CNM). 18 CNM clouds were detected with the typical HI column density of $3\times10^{18}$ cm$^{-2}$. Our…
From millimeter and optical observations of the Jupiter-family comet 17P/Holmes performed soon after its huge outburst of October 24, 2007, we derive 14 N/15N = 139 +/- 26 in HCN, and 14N/15N = 165 +/- 40 in CN, establishing that HCN has…
Fragments of small solar system bodies entering Earth's atmosphere have possibly been important contributors of organic compounds to the early Earth. The cyano radical (CN) emission from meteors is considered as potentially one of the most…
To date, two isomers of H$_2$C$_3$O have been detected, namely, propynal (HCCCHO) and cylclopropenone (c-H$_2$C$_3$O). A third, propadienone (CH$_2$CCO), has thus far eluded observers despite the fact that it is the lowest in energy of the…
We present a study of the isocyano isomers of the cyanopolyynes HC3N, HC5N, and HC7N in TMC-1 and IRC+10216 carried out with the Yebes 40m radio telescope. This study has enabled us to report the detection, for the first time in space, of…
Hydrogen cyanide (HCN) and hydrogen isocyanide (HNC) are isomers with similar chemical properties. However, HNC can be converted into other molecules by reactions with atomic hydrogen (H) and atomic oxygen (O), resulting in a variation of…
We have carried out interferometric observations of cyanopolyynes, HC$_{3}$N, HC$_{5}$N, and HC$_{7}$N, in the 36 GHz band toward the G28.28$-$0.36 high-mass star-forming region using the Karl G. Jansky Very Large Array (VLA) Ka-band…
The interstellar medium contains dust and gas, in which at high densities and cold conditions molecules can proliferate. Interstellar Complex Organic Molecules (iCOMs) are C-bearing species that contain at least six atoms. As they are…
The low temperature reaction between CN and benzene (C$_6$H$_6$) is of significant interest in the astrochemical community due to the recent detection of benzonitrile, the first aromatic molecule identified in the interstellar medium (ISM)…
We present an IRAM 30m line survey of the dense core L483 in the 3 mm band. We detected 71 molecules (140 including different isotopologs), most of which are present in the cold and quiescent ambient cloud. Of particular interest among the…
The variations of elemental abundance and their ratios along the Galactocentric radius result from the chemical evolution of the Milky Way disks. The $\rm ^{12}C/^{13}C$ ratio in particular is often used as a proxy to determine other…
The observation of oxygen (O)- and nitrogen (N)-bearing molecules gives an idea about the complex prebiotic chemistry in the interstellar medium (ISM). In this article, we present the identification of the rotational emission lines of…
We report on the detection of hydromagnesium isocyanide, HMgNC, in the laboratory and in the carbon rich evolved star IRC+10216. The J=1-0 and J=2-1 lines were observed in our microwave laboratory equipment in Valladolid with a spectral…
Stars form out of the densest parts of molecular clouds. Far-IR emission can be used to estimate the Star Formation Rate (SFR) and high dipole moment molecules, typically HCN, trace the dense gas. A strong correlation exists between HCN and…
The interstellar delivery of carbon atoms locked into molecules might be one of the key ingredients for the emergence of life. Cyanopolyynes are carbon chains delimited at their two extremities by an atom of hydrogen and a cyano group, so…
(Abridged) Complex organic molecules (COMs) are commonly detected in and near star-forming regions. However, the dominant process in the release of these COMs from the icy grains - where they predominately form - to the gas phase is still…
The interstellar medium (ISM) consists of highly ionized and neutral atomic, as well as molecular, components. Knowledge of their distribution is important for tracing the structure and lifecycle of the ISM. Here we determine the properties…
C-cyanomethanimine (HNCHCN), existing in the two $Z$ and $E$ isomeric forms, is a key prebiotic molecule, but, so far, only the $E$ isomer has been detected toward the massive star-forming region. Sagittarius B2(N) using transitions in the…
Motivated by the value of CN-bearing molecules as tracers of interstellar physical conditions, we investigate the reactions of adsorbed CN radicals with acetylene and ethylene (C2H2 and C2H4) on interstellar dust-grain analogues using…