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Phase diagrams of binary mixtures of oppositely charged colloids are calculated theoretically. The proposed mean-field-like formalism interpolates between the limits of a hard-sphere system at high temperatures and the colloidal crystals…

Soft Condensed Matter · Physics 2011-09-14 Markus Bier , Rene van Roij , Marjolein Dijkstra

Phase separation of multicomponent liquid mixtures plays an integral part in many processes ranging from industry to cellular biology. In many cases the morphology of coexisting phases is crucially linked to the function of the separated…

Soft Condensed Matter · Physics 2020-11-25 Sheng Mao , Milena S. Chakraverti-Wuerthwein , Hunter Gaudio , Andrej Kosmrlj

Phase diagrams are integral to the application and interpretation of materials thermodynamics, and none is more ubiquitous than the common Temperature-Pressure diagram of water and its many icy phases. Inspired by recent advances in…

Materials Science · Physics 2022-05-27 Matthew J. Powell-Palm

An understanding of the hydrodynamics of multiphase processes is essential for their design and operation. Multiphase computational fluid dynamics (CFD) simulations enable researchers to gain insight which is inaccessible experimentally.…

Numerical Analysis · Mathematics 2021-01-18 Tanyakarn Treeratanaphitak , Nasser Mohieddin Abukhdeir

Accurate phase diagram calculation from molecular dynamics requires systematic treatment and convergence of statistical averages. In this work we propose a Gaussian process regression based framework for reconstructing the free energy…

Computational Physics · Physics 2021-11-02 V. Ladygin , I. Beniya , E. Makarov , A. Shapeev

We derive a phase diagram for amorphous solids and liquid supercooled water and explain why the amorphous solids of water exist in several different forms. Application of large-deviation theory allows us to prepare such phases in computer…

Statistical Mechanics · Physics 2015-06-16 David T Limmer , David Chandler

Using Monte Carlo simulation techniques, we calculate the phase diagram for a square shoulder-square well potential in two dimensions that has been previously shown to exhibit liquid anomalies consistent with a metastable liquid-liquid…

Soft Condensed Matter · Physics 2015-06-04 Ahmad M. Almudallal , Sergey V. Buldyrev , Ivan Saika-Voivod

We map the mean-field Ising model equation of state onto the QCD phase diagram, and reconstruct the full coexistence region in the case of a first order phase transition. Beyond the coexistence line, we maintain access to the spinodal…

Nuclear Theory · Physics 2024-09-24 Jamie M. Karthein , Volker Koch , Claudia Ratti

Under many circumstances many soft and hard materials are present in a puzzling wealth of non-equilibrium amorphous states, whose properties are not stationary and depend on preparation. They are often summarized in unconventional "phase…

Soft Condensed Matter · Physics 2021-04-20 Jesús Benigno Zepeda-López , Magdaleno Medina-Noyola

We present a physical formulation, and a numerical algorithm, based on a class of general order parameters for simulating the motion of a mixture of $N$ ($N\geqslant 2$) immiscible incompressible fluids with given densities, dynamic…

Fluid Dynamics · Physics 2014-12-17 Suchuan Dong

The phase diagram of water has been calculated for the TIP4PQ/2005 model, an empirical rigid non-polarisable model. The path integral Monte Carlo technique was used, permitting the incorporation of nuclear quantum effects. The coexistence…

Statistical Mechanics · Physics 2017-04-05 Carl McBride , Eva G. Noya , Juan L. Aragones , Maria M. Conde , Carlos Vega

At present, many laboratories are performing experiments to simulate theoretical models of strongly correlated systems using cold atoms in optical lattices, a program referred to as "Quantum Simulation". It is hoped that these experiments…

Superconductivity · Physics 2016-11-07 Tin-Lun Ho , Qi Zhou

One method for computationally determining phase boundaries is to explicitly simulate a direct coexistence between the two phases of interest. Although this approach works very well for fluid-fluid coexistences, it is often considered to be…

Soft Condensed Matter · Physics 2025-04-24 Frank Smallenburg , Giovanni Del Monte , Marjolein de Jager , Laura Filion

A methodology to sample the isothermal-isobaric ensemble using Langevin dynamics is proposed, which combines novel features of geometric integrators for the equations of motion. By employing the Trotter expansion, the methodology generates…

Statistical Mechanics · Physics 2018-08-29 Samuel Cajahuaringa , Alex Antonelli

We present the phase diagram and critical properties of a coupled $XY$-Ising model on a triangular lattice using the mean-field approximation, the Migdal-Kadanoff scheme of renormalization group and Monte-Carlo simulations. The topology of…

Condensed Matter · Physics 2009-10-28 M. Hébert , M. L. Plumer

We consider the liquid-vapor type phase transition for fluids confined within spatially periodic external fields. For a fluid in d=3 dimensions, the periodic field induces an additional phase, characterized by large density modulations…

Statistical Mechanics · Physics 2015-03-19 Richard L. C. Vink , A. J. Archer

Water's phase diagram remains one of the most intricate and challenging benchmarks in molecular modeling. In this study, we compute the phase diagram of water using an Atomic Cluster Expansion (ACE) potential trained on density-functional…

Materials Science · Physics 2026-01-21 Eslam Ibrahim , Yury Lysogorskiy , Ralf Drautz , Pablo Piaggi

The pressure-temperature phase diagram of a one-component system, with particles interacting through a spherically symmetric pair potential is studied. It is shown that if the pair potential allows for a discontinuous reduction of the…

Statistical Mechanics · Physics 2008-02-03 E. A. Jagla

We calculate the phase behavior of hard spheres with size polydispersity, using accurate free energy expressions for the fluid and solid phases. Cloud and shadow curves, which determine the onset of phase coexistence, are found exactly by…

Condensed Matter · Physics 2007-05-23 M. Fasolo , P. Sollich

In this study, we incorporate configuration mapping between simulation ensembles into the successive interpolation of multistate reweighting (SIMR) method in order to increase phase space overlap between neighboring simulation ensembles.…

Statistical Mechanics · Physics 2019-05-06 Natalie P. Schieber , Michael R. Shirts