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Nanoporous gold can be exploited as plasmonic material for enhanced spectroscopy both in the visible and in the near infrared spectral regions. In particular, with respect to bulk metal it presents interesting optical properties in the…

Applied Physics · Physics 2019-10-02 Eugenio Calandrini , Giorgia Giovannini , Denis Garoli

A robust and reproducible preparation of self-standing nanoporous gold leaves (NPGL) is presented, with optical characterization and plasmonic behaviour analysis. Nanoporous gold (NPG) layers are tipically prepared as thin films on a bulk…

The plasmonic properties of vacuum evaporated nanostructured gold thin films having different types of nanoparticles are presented. The films with more than 6 nm thickness show presence of nanorods having non cylindrical shape with…

Materials Science · Physics 2014-06-19 V. N. Rai , A. K. Srivastava , C. Mukherjee , S. K. Deb

Current optical detection schemes for single molecules require light absorption, either to produce fluorescence or direct absorption signals. This severely limits the range of molecules that can be detected, because most molecules are…

Chemical Physics · Physics 2012-07-06 Peter Zijlstra , Pedro M. R. Paulo , Michel Orrit

The applications of plasmonics to energy transfer from free-space radiation to molecules are currently limited to the visible region of the electromagnetic spectrum due to the intrinsic optical properties of bulk noble metals that support…

Applied Physics · Physics 2018-04-03 D. Garoli , E. Calandrini , A. Bozzola , M. Ortolani , S. Cattarin , S. Barison , A. Toma , F. De Angelis

Field-enhanced infrared molecular spectroscopy has been widely applied in chemical analysis, environment monitoring, and food and drug safety. The sensitivity of molecular spectroscopy critically depends on the electromagnetic field…

Metallic nanostructures can support so-called plasma oscillations (plasmons). Plasmons allow for the concentration of the energy from light, down to sizes well below the conventional diffraction limit known from optics. Plasmonics thus…

Mesoscale and Nanoscale Physics · Physics 2019-06-05 Christian Frydendahl

We developed a nanoplasmonic sensor platform employing the extraordinary optical properties of one-dimensional nanogratings patterned on 30nm-thick ultrathin Ag films. Excitation of Fano resonances in the ultrathin Ag nanogratings results…

Optics · Physics 2014-10-15 Beibei Zeng , Yongkang Gao , Filbert J. Bartoli

Plasmonic nanoparticles resonantly couple to and confine light below the diffraction limit. This mechanism has enabled a modern renaissance in optical materials, with potential applications ranging from sensing and circuitry to renewable…

We report the investigation of the generation and detection of GHz coherent acoustic phonons in plasmonic gold nanoparticles superlattices (NPS). The experiments have been performed from an optical femtosecond pump-probe scheme across the…

Materials Science · Physics 2015-12-09 P. Ruello , A. Ayouch , G. Vaudel , T. Pezeril , N. Delorme , S. Sato , K. Kimura , V. Gusev

Regular arrays of metal nanoparticles on metal films have tuneable optical resonances that can be applied for surface enhanced Raman scattering or biosensing. With the aim of developing more surface selective geometries we investigate…

Mesoscale and Nanoscale Physics · Physics 2012-09-13 Andreas Hohenau , Joachim R. Krenn

Nanoporous gold (npAu) has emerged as a potential candidate for many optical applications exploiting its large surface to volume ratio and high broadband absorption. However, the physical origin of its enhanced visible and near infrared…

Noble metal nanoparticles show specific optical properties due to the excitation of localized surface plasmons that make them attractive candidates for highly sensitive bionanosensors. The underlying physical principle is either an…

The present work addressed in this thesis introduces, for the first time, the use of tilted fiber Bragg grating (TFBG) sensors for accurate, real-time, and in-situ characterization of CVD and ALD processes for noble metals, but with a…

Chemical Physics · Physics 2017-11-29 David J. Mandia

There is a crucial need for effective and easily dispersible colloidal microsensors able to detect local pH changes before irreversible damages caused by demineralization, corrosion, or biofilms occur. One class of such microsensors is…

Applied Physics · Physics 2024-09-05 C. A. S. Burel , A. Teolis , A. Alsayed , C. B. Murray , B. Donnio , R. Dreyfus

Accessing fluid infiltration in nanogranular coatings is an outstanding challenge, of relevance for applications ranging from nanomedicine to catalysis. A sensing platform, allowing to quantify the amount of fluid infiltrated in a…

Porous nanosponges, percolated with a three-dimensional network of 10-nm sized ligaments, recently emerged as promising substrates for plasmon-enhanced spectroscopy and (photo-)catalysis. Experimental and theoretical work suggests surface…

Mesoscale and Nanoscale Physics · Physics 2018-09-19 Jinhui Zhong , Abbas Chimeh , Anke Korte , Felix Schwarz , Juemin Yi , Dong Wang , Jinxin Zhan , Peter Schaaf , Erich Runge , Christoph Lienau

Here we demonstrate the gas sensing ability of cavity-coupled metallic nanoparticle systems, comprising gold nanoparticles separated from a gold mirror with a polymer spacer. An increase in relative humidity (RH) causes the spacer to…

Optics · Physics 2017-03-27 Jian Qin , Yu-Hui Chen , Boyang Ding , Richard J. Blaikie , Min Qiu

The field of plasmonics is capable of enabling interesting applications in the different wavelength ranges, spanning from the ultraviolet up to the infrared. The choice of plasmonic material and how the material is nanostructured have…

Anisotropic nanostructured porous Pd films are fabricated using oblique angle deposition in vacuum on a glass substrate. They display a dichroic response, due to localised surface plasmon resonances (LSPR) within the nanoparticles forming…

Chemical Physics · Physics 2018-07-20 William L. Watkins , Yves Borensztein
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