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Polaritons are an emerging platform for exploration of synthetic materials [1] and quantum information processing [2] that draw properties from two disparate particles: a photon and an atom. Cavity polaritons are particularly promising, as…

Strong coupling typically occurs between two separate objects or between an object and its environment (such as an atom and a cavity). However, it can also occur between two different excitations within the same object, a situation that has…

Phonons play a central role in fundamental solid-state phenomena, including superconductivity, Raman scattering, and symmetry-breaking phases. Harnessing phonons to control these effects and enable quantum technologies is therefore of great…

Time-varying optical media, whose dielectric properties are actively modulated in time, introduce a host of novel effects in the classical propagation of light, and are of intense current interest. In the quantum domain, time-dependent…

The optical properties of molecules close to plasmonic nanostructures greatly differ from their isolated molecule counterparts. To theoretically investigate such systems in a Quantum Chemistry perspective, one has to take into account that…

Mesoscale and Nanoscale Physics · Physics 2016-12-26 Silvio Pipolo , Stefano Corni

Photonic resonances are a powerful tool for controlling light-matter interactions. However, unlocking many of the most scientifically intriguing and technologically promising phenomena requires entering the strong coupling regime, where…

The interaction within a hybrid system consisting of a spherical metal nanoparticle and a nearby organic dye molecule is formulated in a combined quantum-classical approach. Whereas the nanoparticle's polarization field is treated in…

Chemical Physics · Physics 2019-09-04 Xiaomeng Liu , Lennart Seiffert , Thomas Fennel , Oliver Kühn

The field of 2D materials-based nanophotonics has been growing at a rapid pace, triggered by the ability to design nanophotonic systems with in situ control, unprecedented degrees of freedom, and to build material heterostructures from…

Polaritons are unique hybrid light-matter states that offer an alternative way to manipulate chemical processes and change material properties. In this work we theoretically demonstrate that singlet fission dynamics can be accelerated under…

Chemical Physics · Physics 2021-10-06 Clàudia Climent , David Casanova , Johannes Feist , Francisco J. García-Vidal

We consider a hybrid plasmon-exciton system comprised of a resonant molecular subsystem and three Au wires supporting a dipole mode which can be coupled to a dark mode in controllable fashion by variation of a symmetry parameter. The…

Optics · Physics 2015-03-25 Maxim Sukharev , Paul N. Day , Ruth Pachter

In the last decade, much theoretical research has focused on studying the strong coupling between organic molecules (or quantum emitters, in general) and light modes. The description and prediction of polaritonic phenomena emerging in this…

Understanding the quantum dynamics of strongly coupled molecule-cavity systems remains a significant challenge in molecular polaritonics. This work develops a comprehensive self-consistent model simulating electromagnetic interactions of…

Chemical Physics · Physics 2025-01-29 Maxim Sukharev , Joseph E. Subotnik , Abraham Nitzan

We reveal new aspects of the interaction between plasmons and phonons in 2D materials that go beyond a mere shift and increase in plasmon width due to coupling to either intrinsic vibrational modes of the material or phonons in a supporting…

We theoretically investigate plasmon polaritons in cubic lattices of spherical metallic nanoparticles. The nanoparticles, each supporting triply-degenerate localized surface plasmons, couple through the Coulomb dipole-dipole interaction,…

Mesoscale and Nanoscale Physics · Physics 2018-03-12 Simon Lamowski , Charlie-Ray Mann , Felicitas Hellbach , Eros Mariani , Guillaume Weick , Fabian Pauly

Plasmon resonances at the surface of plasmonic antennas allow for extremely strong enhancement of Raman scattering. Intrinsic to plasmonics, however, is that extreme field confinement lacks precise spectral control, which would hold great…

Realizing strong coupling between a single quantum emitter (QE) and an optical cavity is of crucial importance in the context of various quantum optical applications. While Rabi splitting of single quantum emitters coupled to high-Q…

We consider parametric interactions of laser pulses in a coherent macroscopic ensemble of resonant atoms, which are possible in the strong coupling regime of light-matter interaction. The spectrum condensation (lasing at collective vacuum…

Quantum Physics · Physics 2007-05-23 I. B. Mekhov , V. S. Egorov , V. N. Lebedev , P. V. Moroshkin , I. A. Chekhonin , S. N. Bagayev

Plasmon-polaritons are among the most promising candidates for next generation optical sensors due to their ability to support extremely confined electromagnetic fields and empower strong coupling of light and matter. Here we propose…

Polaritonic states arise when a bright optical transition of a molecular ensemble is resonantly matched to an optical cavity mode frequency. Here, we lay the groundwork to study the behavior of polaritons in clean, isolated systems by…

Chemical Physics · Physics 2023-10-20 Adam D. Wright , Jane C. Nelson , Marissa L. Weichman

In the past decade, advances in nanotechnology have led to the development of plasmonic nanocavities which facilitate light-matter strong coupling in ambient conditions. The most robust example is the nanoparticle-on-mirror (NPoM) structure…