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Weakly attractive interactions between the tips of rod-like colloidal particles affect their liquid-crystal phase behaviour due to a subtle interplay between enthalpy and entropy. Here, we employ molecular dynamics simulations on…

Soft Condensed Matter · Physics 2019-10-16 Mariana Oshima Menegon , Guido L. A. Kusters , Paul van der Schoot

Curved particles have been shown to stabilize a range of states with unique order in dense suspensions of colloidal bent core liquid crystals. The shape of the colloidal rods encourages the formation of curved director fields. However,…

Soft Condensed Matter · Physics 2026-01-08 Nicholas W. Hackney , Joel T. Clemmer , Gary S. Grest

The geometric shape, symmetry, and topology of colloidal particles often allow for controlling colloidal phase behavior and physical properties of these soft matter systems. In liquid crystalline dispersions, colloidal particles with low…

Soft Condensed Matter · Physics 2024-10-14 Ye Yuan , Ivan I. Smalyukh

Self-assembly of colloidal particles due to elastic interactions in nematic liquid crystals promises tunable composite materials and can be guided by exploiting surface functionalization, geometric shape and topology, though these means of…

Soft Condensed Matter · Physics 2017-12-29 Bohdan Senyuk , Qingkun Liu , Philip D. Nystrom , Ivan I. Smalyukh

We report on a comprehensive computer simulation study of the liquid-crystal phase behaviour of purely repulsive, semi-flexible rod-like particles. For the four aspect ratios we consider, the particles form five distinct phases depending on…

Soft Condensed Matter · Physics 2018-01-17 Bart de Braaf , Mariana Oshima Menegon , Stefan Paquay , Paul van der Schoot

Rod-shaped colloids with attractive tips can form linear aggregates that may subsequently undergo hierarchical self-assembly into nematic fluids. Inspired by recent modelling efforts on chromonic liquid crystals, composed of discotic…

Soft Condensed Matter · Physics 2020-07-01 H. H. Wensink

By employing Molecular Dynamics computer simulations, the phase behavior of systems of rodlike particles with varying degree of internal flexibility has been traced from the perfectly rigid rod limit till very flexible particles, and from…

Soft Condensed Matter · Physics 2009-11-13 Giorgio Cinacchi , Luca De Gaetani

Colloids self-assemble into various organized superstructures determined by particle interactions. There is a tremendous progress in both the scientific understanding and applications of self-assemblies of single-type identical particles.…

Soft Condensed Matter · Physics 2016-09-23 Chenhui Peng , Taras Turiv , Yubing Guo , Sergij V. Shiyanovskii , Qi-Huo Wei , Oleg D. Lavrentovich

Anisotropic rod-like particles form liquid crystalline phases with varying degrees of orientational and translational order. When confined geometrically, these phases can give rise to topological defects, which can be selected and…

Soft Condensed Matter · Physics 2026-05-29 Gerardo Campos-Villalobos , André F. V. Matias , Ethan I. L. Jull , Lisa Tran , Marjolein Dijkstra

One of the central experimental efforts in nematic colloids research aims to explore how the interplay between the geometry of particles along with the accompanying nematic director deformations and defects around them can provide a means…

Soft Condensed Matter · Physics 2016-12-28 Bohdan Senyuk , Manoj B. Pandey , Qingkun Liu , Mykola Tasinkevych , Ivan I. Smalyukh

Orientational and positional ordering properties of liquid crystal monolayers are examined by means of Fundamental-Measure Density Functional Theory. Particles forming the monolayer are modeled as hard parallelepipeds of square section of…

Soft Condensed Matter · Physics 2015-06-19 Yuri Martinez-Raton , Szabolcs Varga y Enrique Velasco

Self-assembly of nanoparticles can enable composites with pre-designed properties but remains challenged by reproducing structural diversity of atomic and molecular crystals. We combine anisotropic elastic and weakly screened electrostatic…

Soft Condensed Matter · Physics 2016-12-09 Haridas Mundoor , Bohdan Senyuk , Ivan I. Smalyukh

Nematic colloids exhibit a large diversity of topological defects and structures induced by colloidal particles in the orientationally ordered liquid crystal host fluids. These defects and field configurations define elastic interactions…

Soft Condensed Matter · Physics 2016-12-30 Bohdan Senyuk , Qingkun Liu , Ye Yuan , Ivan I. Smalyukh

Control of physical behaviors of nematic colloids and colloidal crystals has been demonstrated by tuning particle shape, topology, chirality and surface charging. However, the capability of altering physical behaviors of such soft matter…

Soft Condensed Matter · Physics 2021-01-12 Ye Yuan , Patrick Keller , Ivan I. Smalyukh

The assembly of nanometer-sized building blocks into complex morphologies is not only of fundamental interest but also plays a key role in material science and nanotechnology. We show that the shape of self-assembled superstructures formed…

Soft Condensed Matter · Physics 2020-05-08 Baeckkyoung Sung , Rik Wensink , Eric Grelet

Monodisperse rod-like colloidal particles are known for spontaneously forming both nematic and smectic liquid crystal phases, but their self-assembly was typically exploited from the fundamental soft condensed matter physics perspective.…

Soft Condensed Matter · Physics 2017-12-29 Yong Xie , Yuanyuan Li , Guoqing Wei , Qingkun Liu , Haridas Mundoor , Ziyu Chen , Ivan I. Smalyukh

By means of computer simulations we study how droplets of hard, rod-like particles optimize their shape and internal structure under the influence of the osmotic compression caused by the presence of spherical particles that act as…

Soft Condensed Matter · Physics 2015-05-13 Y. Trukhina , S. Jungblut , P. van der Schoot , T. Schilling

The ordering of rod-like particles in soft, deformable containers emerges from the interplay of anisotropic interactions, geometric confinement, and boundary compliance. This competition couples internal particle organization to container…

Soft Condensed Matter · Physics 2026-05-22 Stijn van der Ham , André F. V. Matias , Marjolein Dijkstra , Hanumantha Rao Vutukuri

We study by simulation the physics of two colloidal particles in a cholesteric liquid crystal with tangential order parameter alignment at the particle surface. The effective force between the pair is attractive at short range and favors…

Soft Condensed Matter · Physics 2015-03-19 J. S. Lintuvuori , K. Stratford , M. E. Cates , D. Marenduzzo

The ability to dictate colloid motion is an important challenge in fields ranging from materials science to living systems. Here, by embedding energy landscapes in confined nematic liquid crystals, we design a versatile platform to define…

Soft Condensed Matter · Physics 2018-11-07 Yimin Luo , Daniel A. Beller , Giuseppe Boniello , Francesca Serra , Kathleen J. Stebe
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