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The time-dependent restricted-active-space self-consistent-field (TD-RASSCF) method is formulated based on the TD variational principle. In analogy with the configuration-interaction singles (CIS), singles-and-doubles (CISD),…

Quantum Physics · Physics 2014-06-26 Haruhide Miyagi , Lars Bojer Madsen

We present a numerical implementation of the infinite-range exterior complex scaling (irECS) [Phys. Rev. A 81, 053845 (2010)] as an efficient absorbing boundary to the time-dependent complete-active-space self-consistent field (TD-CASSCF)…

Atomic Physics · Physics 2018-03-07 Yuki Orimo , Takeshi Sato , Armin Scrinzi , Kenichi L. Ishikawa

We apply a three-dimensional (3D) implementation of the time-dependent restricted-active-space self-consistent-field (TD-RASSCF) method to investigate effects of electron correlation in the ground state of Be as well as in its…

Atomic Physics · Physics 2017-06-07 Juan J. Omiste , Wenliang Li , Lars Bojer Madsen

We describe the time-dependent restricted-active-space self-consistent-field (TD-RASSCF) method for a system of interacting bosons. We provide the theory of the method and discuss its numerical implementation. The method provides a general…

Quantum Physics · Physics 2017-04-28 Camille Lévêque , Lars Bojer Madsen

Over the last three decades numerous numerical methods for solving the time-dependent Schr\"{o}dinger equation within the single-active electron approximation have been developed for studying ionization of atomic targets exposed to an…

Atomic Physics · Physics 2020-08-12 B. Fetić , W. Becker , D. B. Milošević

The time-dependent multiconfiguration self-consistent-field method based on the occupation-restricted multiple active space model is proposed (TD-ORMAS) for multielectron dynamics in intense laser fields. Extending the previously proposed…

Atomic Physics · Physics 2015-06-23 Takeshi Sato , Kenichi L. Ishikawa

Time-dependent coupled-cluster method with time-varying orbital functions, called time-dependent optimized coupled- cluster (TD-OCC) method, is formulated for multielectron dynamics in an intense laser field. We have successfully derived…

Chemical Physics · Physics 2018-03-14 Takeshi Sato , Himadri Pathak , Yuki Orimo , Kenichi L. Ishikawa

We report the implementation of a cost-effective approximation method within the framework of time-dependent optimized coupled-cluster (TD-OCC) method [J. Chem. Phys. 148, 051101 (2018)] for real-time simulations of intense laser-driven…

Chemical Physics · Physics 2020-04-22 Himadri Pathak , Takeshi Sato , Kenichi L. Ishikawa

We explore the merits of linear-response range-separated time-dependent density-functional theory (TDDFT) for the calculation of photoionization spectra. We consider two variants of range-separated TDDFT, namely the timedependent…

Chemical Physics · Physics 2022-06-22 Karno Schwinn , Felipe Zapata , Antoine Levitt , Eric Cancès , Eleonora Luppi , Julien Toulouse

We present a cost-effective treatment of the triple excitation amplitudes in the time-dependent optimized coupled-cluster (TD-OCC) framework called TD-OCCDT(4) for studying intense laser-driven multielectron dynamics. It considers triple…

Chemical Physics · Physics 2021-07-07 Himadri Pathak , Takeshi Sato , Kenichi L. Ishikawa

The calculation of accurate photoelectron spectra (PES) for strong-field laser-atom experiments is a demanding computational task, even in single-active-electron approximation. The QPROP code, published in 2006, has been extended in 2016 in…

Computational Physics · Physics 2020-04-22 Vasily Tulsky , Dieter Bauer

We report the formulation of a new, cost-effective approximation method in the time-dependent optimized coupled-cluster (TD-OCC) framework [T. Sato et al., J. Chem. Phys. 148, 051101 (2018)] for first-principles simulations of multielectron…

Chemical Physics · Physics 2022-08-11 Himadri Pathak , Takeshi Sato , Kenichi L. Ishikawa

We present a time-dependent density-functional method able to describe the photoelectron spectrum of atoms and molecules when excited by laser pulses. This computationally feasible scheme is based on a geometrical partitioning that…

Atomic Physics · Physics 2012-06-28 U. De Giovannini , D. Varsano , M. A. L. Marques , H. Appel , E. K. U. Gross , A. Rubio

We calculate the high-harmonic generation (HHG) spectra, strong-field ionization, and time-dependent dipole-moment of Ne using explicitly time-dependent optimized second-order many-body perturbation method (TD-OMP2) where both orbitals and…

Chemical Physics · Physics 2020-08-18 Himadri Pathak , Takeshi Sato , Kenichi L. Ishikawa

By simulating the real-time multielectron wavefunction with the multi-configurational time-dependent Hartree-Fock (MCTDHF) approach, we conduct an \textit{ab initio} study of the single-photon ionization process of a body-fixed water…

Atomic Physics · Physics 2026-01-14 Zhao-Han Zhang , Yang Li , Himadri Pathak , Takeshi Sato , Kenichi L. Ishikawa , Feng He

The accurate description of the non-linear response of many-electron systems to strong-laser fields remains a major challenge. Methods that bypass the unfavorable exponential scaling with particle number are required to address larger…

X-ray photoelectron spectra provide a wealth of information on the electronic structure. The extraction of molecular details requires adequate theoretical methods, which in case of transition metal complexes has to account for effects due…

In parallel with the evolution of femtosecond and attosecond laser as well as free-electron laser technology, a variety of theoretical methods have been developed to describe the behavior of atoms, molecules, clusters, and solids under the…

Atomic Physics · Physics 2015-11-12 Kenichi L. Ishikawa , Takeshi Sato

We present a comprehensive theoretical description for an irradiation of an ultrashort light pulse normally on thin materials based on first-principles time-dependent density functional theory. As the most elaborate scheme, we develop a…

Optics · Physics 2018-12-31 Shunsuke Yamada , Masashi Noda , Katsuyuki Nobusada , Kazuhiro Yabana

We present a wave-function based method to solve the time-dependent many-electron Schr\"odinger equation (TDSE) with special emphasis on strong-field ionization phenomena. The theory builds on the configuration-interaction (CI) approach…

Quantum Physics · Physics 2014-12-11 Sebastian Bauch , Lasse Kragh Sørensen , Lars Bojer Madsen