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Generalizations of the microcanonical and canonical ensembles for paths of Markov processes have been proposed recently to describe the statistical properties of nonequilibrium systems driven in steady states. Here we propose a theory of…

Statistical Mechanics · Physics 2013-09-18 Raphael Chetrite , Hugo Touchette

We present a statistical physics framework for description of nonlinear non-equilibrium stochastic processes, modeled via chemical master equation, in the weak-noise limit. Using the Poisson representation approach and applying the…

Chemical Physics · Physics 2014-05-15 K. G. Petrosyan , Chin-Kun Hu

We develop the stochastic approach to thermodynamics based on the stochastic dynamics, which can be discrete (master equation) continuous (Fokker-Planck equation), and on two assumptions concerning entropy. The first is the definition of…

Statistical Mechanics · Physics 2015-06-11 Tânia Tomé , Mário J. de Oliveira

The nonlinear Markov processes are the measure-valued dynamical systems which preserve positivity. They can be represented as the law of large numbers limits of general Markov models of interacting particles. In physics, the kinetic…

Chemical Physics · Physics 2015-09-28 A. N. Gorban , V. N. Kolokoltsov

We investigate the structure of non-equilibrium steady states (NESS) for a class of exactly solvable models in the setting of a chain with left and right reservoirs. Inspired by recent results on the harmonic model, we focus on models in…

Probability · Mathematics 2025-12-02 Frank Redig , Berend van Tol

The dynamics of free vibrations of a chain of atoms is investigated taking into account the retardation of interactions. It is shown that all oscillations of the circuit are damped. The dynamics of forced vibrations of this chain of atoms…

Statistical Mechanics · Physics 2021-04-13 A. Yu. Zakharov , M. A. Zakharov

The aim of the article is to develop the stochastic interpretation of quantum mechanics by E. Nelson on the basis of balancing the intra-systemic contradiction (i.e., antisymmetry) between "order" and "chaos". For the set task, it is…

General Physics · Physics 2024-07-02 Mikhail Batanov-Gaukhman

The selection of an equilibrium state by maximising the entropy of a system, subject to certain constraints, is often powerfully motivated as an exercise in logical inference, a procedure where conclusions are reached on the basis of…

Statistical Mechanics · Physics 2015-12-03 Ian J. Ford

The consistency across scales of a recently developed mathematical thermodynamic structure, between a continuous stochastic nonlinear dynamical system (diffusion process with Langevin or Fokker-Planck equations) and its emergent discrete,…

Statistical Mechanics · Physics 2015-10-28 Moises Santillan , Hong Qian

The extension of thermodynamic principles to active matter remains a challenge due to the non-equilibrium nature inherent to active systems. In this study, we introduce a framework to assess entropy in our minimal macroscopic experiment…

Soft Condensed Matter · Physics 2024-09-26 Francesco Romanò , Michael Riedl

A Hamiltonian-based model of many harmonically interacting massive particles that are subject to linear friction and coupled to heat baths at different temperatures is used to study the dynamic approach to equilibrium and non-equilibrium…

Statistical Mechanics · Physics 2020-09-17 Roland R. Netz

Local Shannon entropy lies at the heart of modern thermodynamics, with much discussion of trajectory-dependent entropy production. When taken at both boundaries of a process in phase space, it reproduces the second law of thermodynamics…

Statistical Mechanics · Physics 2015-01-20 Lee Jinwoo , Hajime Tanaka

We extend stochastic thermodynamics by relaxing the two assumptions that the Markovian dynamics must be linear and that the equilibrium distribution must be a Boltzmann distribution. We show that if we require the second law to hold when…

Statistical Mechanics · Physics 2021-05-26 Jan Korbel , David H. Wolpert

We develop non-equilibrium theory by using averages in time and space as a generalized way to upscale thermodynamics in non-ergodic systems. The approach offers a classical perspective on the energy dynamics in fluctuating systems. The rate…

Soft Condensed Matter · Physics 2021-09-29 James E. McClure , Steffen Berg , Ryan T. Armstrong

A new effective theory framework for fluctuating hydrodynamics in the relativistic regime is derived using standard thermodynamical principles and general properties of non-equilibrium stochastic dynamics. For the first time, we establish…

Nuclear Theory · Physics 2025-01-09 Nicki Mullins , Mauricio Hippert , Jorge Noronha

Organisms are nonequilibrium, stationary systems self-organized via spontaneous symmetry breaking and undergoing metabolic cycles with broken detailed balance in the environment. The thermodynamic free-energy principle describes an…

Neurons and Cognition · Quantitative Biology 2022-11-24 Chang Sub Kim

How is it that entropy derivatives almost in their own are characterizing the state of a system close to equilibrium, and what happens further away from it? We explain within the framework of Markov jump processes why fluctuation theory can…

Statistical Mechanics · Physics 2009-08-24 Christian Maes , Karel Netočný , Bram Wynants

Stochastic thermodynamics and the associated fluctuation relations provide the means to extend the fundamental laws of thermodynamics to small scales and systems out of equilibrium. The fluctuating thermodynamic variables are usually…

Statistical Mechanics · Physics 2015-05-29 Aki Kutvonen , Tapio Ala-Nissilä , Jukka P. Pekola

An estimator for the dynamical temperature in an arbitrary ensemble is derived in the framework of Bayesian statistical mechanics and the maximum entropy principle. We test this estimator numerically by a simulation of the two-dimensional…

Statistical Mechanics · Physics 2016-12-14 G. Palma , G. Gutiérrez , S. Davis

In this paper we propose a novel approach to construct macroscopic balance equations and constitutive equations describing various irreversible phenomena. It is based on the general principles of non-equilibrium thermodynamics and consists…

Statistical Mechanics · Physics 2014-11-27 Liu Hong , Zaibao Yang , Yi Zhu , Wen-An Yong
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