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Nonequilibrium interfacial thermodynamics is formulated in the presence of surface reactions for the study of diffusiophoresis in isothermal systems. As a consequence of microreversibility and Onsager-Casimir reciprocal relations,…

Chemical Physics · Physics 2018-12-24 Pierre Gaspard , Raymond Kapral

This article presents a multi-physics methodology for the numerical simulation of physical systems that involve the non-linear interaction of multi-phase reactive fluids and elastoplastic solids, inducing high strain-rates and high…

Computational Physics · Physics 2021-06-04 Tim Wallis , Philip T. Barton , Nikolaos Nikiforakis

We revisit the sharp-interface continuum thermodynamics of two-phase multicomponent fluid systems with interfacial mass. Since the published work is not fully consistent, we provide a rigorous derivation of the local balance equations and…

Fluid Dynamics · Physics 2022-08-15 Dieter Bothe

Numerical heat and mass transfer analysis of a configuration where a cool liquid hydrocarbon is suddenly introduced to a hotter gas at supercritical pressure shows that a well-defined phase equilibrium can be established before substantial…

Fluid Dynamics · Physics 2022-04-25 Jordi Poblador-Ibanez , William A. Sirignano

The paper is devoted to the thermodynamics of normal surface electromagnetic fields within a nonuniform dispersive and absorptive system. This system is formed by vacuum and lossy medium separated by a plane interface. As a medium, we used…

Other Condensed Matter · Physics 2012-12-04 Illarion Dorofeyev

In this paper, we consider a diffuse-interface gas-liquid two-phase flow model with inhomogeneous temperatures, in which we employ the Peng-Robinson equation of state and the temperature-dependent influence parameter instead of the van der…

Numerical Analysis · Mathematics 2018-08-01 Jisheng Kou , Shuyu Sun

Four results associated with the diffuse-interface model (DIM) for contact lines are reported in this paper. First, a boundary condition is derived, which states that the fluid near a solid wall must have a certain density $\rho_{0}$…

Fluid Dynamics · Physics 2021-09-27 E. S. Benilov

There are various methods for modeling phase transformations in materials science, including general classes of phase-field methods and reactive diffusion methodologies, which most importantly differ in their treatment of interface energy.…

In this paper, a thermal-dynamical consistent model for mass transfer across permeable moving interfaces is proposed by using the energy variation method. We consider a restricted diffusion problem where the flux across the interface…

Numerical Analysis · Mathematics 2022-06-15 Yuzhe Qin , Huaxiong Huang , Yi Zhu , Chun Liu , Shixin Xu

Several aspects of the theory of the coexistence of phases and equilibrium forms are discussed. In section 1, the problem is studied from the point of view of thermodynamics. In section 2, the statistical mechanical theory is introduced. We…

Statistical Mechanics · Physics 2012-06-20 Salvador Miracle-Sole

Boundary conditions for the solid-liquid interface of the solidifying pure melt have been derived. In the derivation the model of Gibbs interface is used. The boundary conditions include both the state quantities of bulk phases are taken at…

Materials Science · Physics 2016-11-02 Gennady Buchbinder , Peter Galenko

We study the interface between a fractional topological insulator and an ordinary insulator, both described using holography. By turning on a chemical potential we induce a finite density of matter localized at the interface. These are…

High Energy Physics - Theory · Physics 2013-05-30 Moshe Rozali

Interactions between an evolving solid and inviscid flow can result in substantial computational complexity, particularly in circumstances involving varied boundary conditions between the solid and fluid phases. Examples of such…

Fluid Dynamics · Physics 2022-09-30 Emma M. Schmidt , J. Matt Quinlan , Brandon Runnels

Solids facing a plasma are a common situation in many astrophysical systems and laboratory setups. Moreover, many plasma technology applications rely on the control of the plasma-surface interaction. However, presently often a fundamental…

Plasma Physics · Physics 2019-12-20 M Bonitz , A Filinov , J W Abraham , K Balzer , H Kählert , E Pehlke , FX Bronold , M Pamperin , M M Becker , D Loffhagen , H Fehske

A new diffuse interface model for a two-phase flow of two incompressible fluids with different densities is introduced using methods from rational continuum mechanics. The model fulfills local and global dissipation inequalities and is…

Fluid Dynamics · Physics 2011-04-08 H. Abels , H. Garcke , G. Grün

The application of a temperature gradient along a fluid-solid interface generates stresses in the fluid causing "thermo-osmotic" flow. Much of the understanding of this phenomenon is based on Derjaguin's work relating thermo-osmotic flows…

Soft Condensed Matter · Physics 2019-10-24 Oded Farago

We analyze the surface tension exerted at the interface between an active fluid and a solid boundary in terms of tangential forces. Focusing on active systems known to possess an equation of state for the pressure, we show that interfacial…

In this work, a thermodynamically consistent and conservative diffuse-interface model for gas-liquid-solid multiphase flows is proposed. In this model, a novel free energy for the gas-liquid-solid multiphase flows is established according…

Fluid Dynamics · Physics 2025-04-09 Chengjie Zhan , Xi Liu , Zhenhua Chai , Baochang Shi

A diffuse-interface model for microstructure with an arbitrary number of components and phases was developed from basic thermodynamic and kinetic principles and formalized within a variational framework. The model includes a composition…

Materials Science · Physics 2011-07-28 Daniel A. Cogswell , W. Craig Carter

The effect of thermal fluctuations near a contact line of a liquid interface partially wetting an impenetrable substrate is studied analytically and numerically. Promoting both the interface profile and the contact line position to random…

Soft Condensed Matter · Physics 2016-11-15 D. Belardinelli , M. Sbragaglia , M. Gross , B. Andreotti