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Monolayer group-III monochalcogenides (MX, M = Ga, In; X = S, Se, Te), an emerging category of two-dimensional (2D) semiconductors, hold great promise for electronics, optoelectronics and catalysts. By first-principles calculations, we show…

Materials Science · Physics 2018-05-11 Si Zhou , Cheng-Cheng Liu , Jijun Zhao , Yugui Yao

In transition metal dichalcogenides (TMDCs), charge carriers have spin, pseudospin, and valley degrees of freedom associated with magnetic moments. The monolayers and bilayers of the TMDCs, in particular, MoS$_2$, lead strong couplings…

Materials Science · Physics 2021-11-29 Yeon Lee , Dasol Kim , Dong Eon Kim , Alexis Chacón

The controlled assembly of twisted 2D structures requires precise determination of the crystal orientation of their component layers. In the established procedure, the second-harmonic generation (SHG) intensity of a noncentrosymmetric layer…

Transition metal dichalcogenides (TMDCs) have demonstrated significant potential as versatile quantum materials for light absorption and emission. Their unique properties are primarily governed by exciton-photon interactions, which can be…

We present optical spectroscopy (photoluminescence and reflectance) studies of thin layers of the transition metal dichalcogenide WSe2, with thickness ranging from mono- to tetra-layer and in the bulk limit. The investigated spectra show…

Mesoscale and Nanoscale Physics · Physics 2015-03-06 Ashish Arora , Maciej Koperski , Karol Nogajewski , Jacques Marcus , Clement Faugeras , Marek Potemski

The weakly screened electron-hole interactions in an atomically thin semiconductor not only downshift its excitation spectrum from a quasiparticle one, but also redistribute excitation energies and wavefunction characters with profound…

Mesoscale and Nanoscale Physics · Physics 2018-10-24 Yuanxi Wang , Bruno R. Carvalho , Vincent H. Crespi

Single-crystal X-ray diffraction and nonlinear optical measurements, especially second- and third-harmonic generation (SHG/THG) are comprehensively investigated for the van der Waals layered material AgScP2S6 with a non-centrosymmetric P31c…

We measure the second-harmonic (SH) response of MoS$_2$ in a broad fundamental photon energy range between 0.85 and 1.7 eV, and present a continuous SH spectrum capturing signatures of both the fundamental A and B excitons in addition to…

Mesoscale and Nanoscale Physics · Physics 2015-10-28 Mads L. Trolle , Yao-Chung Tsao , Kjeld Pedersen , Thomas G. Pedersen

We calculate high-harmonic generation (HHG) by intense infrared lasers in atoms and molecules with the inclusion of macroscopic propagation of the harmonics in the gas medium. We show that the observed experimental spectra can be accurately…

Since de discovery of graphene, the family of 2-dimensional materials has attracted much recent attention. In this work, the nonlinear optical properties of few-layer MoS2 two-dimensional crystals are studied using femtosecond laser pulses.…

Mesoscale and Nanoscale Physics · Physics 2013-06-20 Leandro M. Malard , Thonimar V. Alencar , Ana Paula M. Barboza , Kin Fai Mak , Ana M. de Paula

This Letter brings together two topics that, until now, have been the focus of intense but non-overlapping research efforts. The first concerns high harmonic generation in solids, which occurs when intense light field excites highly…

Strongly Correlated Electrons · Physics 2022-04-06 R. E. F. Silva , Igor V. Blinov , Alexey N. Rubtsov , O. Smirnova , M. Ivanov

Ion specific outcomes at aqueous interfaces remain among the most enigmatic phenomena in interfacial chemistry. Here, charged fused silica/water interfaces have been probed by homodyne- and heterodyne-detected (HD) second harmonic…

Chemical Physics · Physics 2019-05-13 Mavis D. Boamah , Paul E. Ohno , Emilie Lozier , Jacqueline Van Ardenne , Franz M. Geiger

The surface sensitivity and probe depth in the x-ray regime of diamond for second harmonic generation (SHG) was investigated both analytically and computationally with velocity gauge real-time time-dependent density functional theory…

Materials Science · Physics 2026-04-22 Daniel Schacher , Tod A. Pascal , Keith V. Lawler , Craig P. Schwartz

An analytical theory of the nonlinear electromagnetic response of a two-dimensional (2D) electron system in the second order in the electric field amplitude is developed. The second-order polarizability and the intensity of the second…

Mesoscale and Nanoscale Physics · Physics 2015-05-27 S. A. Mikhailov

Optical nonlinearity, especially the second harmonic generation (SHG), is generally weak in materials but has the potential to be applied in high-speed optical computers and energy-efficient artificial intelligence systems. In order to…

Strongly Correlated Electrons · Physics 2024-12-05 Junyi Shan

The lack of available table-top extreme ultraviolet (XUV) sources with high enough fluxes and coherence properties have limited the availability of nonlinear XUV and x-ray spectroscopies to free electron lasers (FEL). Here, we demonstrate…

High-harmonic generation (HHG) in solids has been touted as a way to probe ultrafast dynamics and crystal symmetries in condensed matter systems. Here, we investigate the polarization properties of high-order harmonics generated in…

We predict enormous piezoelectric effects in intrinsic monolayer group IV monochalcogenides (MX, M=Sn or Ge, X=Se or S), including SnSe, SnS, GeSe and GeS. Using first-principle simulations based on the modern theory of polarization, we…

Materials Science · Physics 2015-11-05 Ruixiang Fei , Wenbin Li , Ju Li , Li Yang

Monolayer transition metal dichalcogenides are a suitable platform for studying excitonic coherence in the light-matter coupling regime. We present an ab initio time-dependent GW-Bethe-Salpeter equation (GW-BSE) investigation of coherent…

A newly synthesized layered material C2N was investigated based on many- body perturbation theory using GW plus Bethe-Salpeter equation approach. The electronic band gap was determined to be ranging from 3.75 to 1.89 eV from monolayer to…

Materials Science · Physics 2016-11-03 Jiuyu Sun , Ruiqi Zhang , Xingxing Li , Jinlong Yang