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In this work we study the intercalation of monolayer phosphorene with nitrogen, lithium and calcium for exploring prospects of spintronic applications. The electronic and the magnetic properties of the intercalated structure are…

Materials Science · Physics 2021-02-03 S. Koley , S. Basu

Two-dimensional (2D) materials, such as graphene and transition metal dichalcogenides have attracted great attention because of the rich physics and potential applications in next-generation nano-sized electronic devices. Recently,…

Materials Science · Physics 2015-05-25 Xiaolong Chen , Yingying Wu , Zefei Wu , Shuigang Xu , Lin Wang , Yu Han , Weiguang Ye , Tianyi Han , Yuheng He , Yuan Cai , Ning Wang

We investigate the electronic properties of $N$-layer black phosphorus by means of an analytical method based on a recently proposed tight-binding Hamiltonian involving $14$ hopping parameters. The method provides simple and accurate…

Mesoscale and Nanoscale Physics · Physics 2017-10-18 D. J. P. de Souza , L. V. de Castro , D. R. da Costa , J. Milton Pereira , Tony Low

We study the environmental instability of mechanically exfoliated few-layer black phosphorus (BP). From continuous measurements of flake topography over several days, we observe an increase of over 200% in volume due to the condensation of…

The environmental stability of the layered semiconductor black phosphorus (bP) remains a challenge. Passivation of the bP surface with phosphorus oxide, POx, grown by a reactive ion etch with oxygen plasma is known to improve…

Mesoscale and Nanoscale Physics · Physics 2018-04-30 W. Dickerson , V. Tayari , I. Fakih , A. Korinek , M. Caporali , M. Serrano-Ruiz , M. Peruzzini , S. Heun , G. A. Botton , T. Szkopek

Black phosphorus (bP) is the second known elemental allotrope with a layered crystal structure that can be mechanically exfoliated down to atomic layer thickness. We have fabricated bP naked quantum wells in a back-gated field effect…

Mesoscale and Nanoscale Physics · Physics 2015-09-04 V. Tayari , N. Hemsworth , I. Fakih , A. Favron , E. Gaufrès , G. Gervais , R. Martel , T. Szkopek

We present a monolayer black phosphorus (BP)-based metamaterial structure for tunable anisotropic absorption in the mid-infrared. Based on the critical coupling mechanism of guided resonance, the structure realizes the high absorption…

We theoretically explore Floquet engineering in few-layer black phosphorus (fBP) under time-periodic driving. Motivated by the ability of circularly polarized light to induce nontrivial topological states at Dirac nodes, we investigate the…

Mesoscale and Nanoscale Physics · Physics 2025-08-28 Taehun Kim , Hansol Kim , Dongeun Kim , Hongki Min

Nominally-pure black phosphorus (BP) is commonly found to be a p-type semiconductor, suggesting the ubiquitious presence of impurity species or intrinsic, charged defects. Moreover, scanning tunnelling microscopy (STM) images of black…

As an emerging single elemental layered material with a low symmetry in-plane crystal lattice, black phosphorus (BP) has attracted significant research interest owing to its unique electronic and optoelectronic properties, including its…

The electronic structure of few-layer(FL) black phosphorus(BP) sensitively depends on the sample thickness, strain and doping. In this paper, we show that it is also vulnerable to air-exposure. The oxidation of BP caused by air-exposure…

Mesoscale and Nanoscale Physics · Physics 2019-03-27 Fanjie Wang , Guowei Zhang , Shenyang Huang , Chaoyu Song , Chong Wang , Qiaoxia Xing , Yuchen Lei , Hugen Yan

The objective of this work is to study the effects of charge redistribution, applied layer-normal electric fields, applied strain, and layer engineering on the band alignment of Black Phosphorus (BP)/Molybdenum disulphide (MoS2)…

Materials Science · Physics 2022-12-28 Nupur Navlakha , Priyamvada Jadaun , Leonard F. Register , Sanjay K. Banerjee

In this work, we reported uniform layer-by-layer sublimation of black phosphorus under heating below 600 K. The uniformity and crystallinity of BP samples after thermal thinning were confirmed by Raman spectra and 2D Raman imaging. A…

Materials Science · Physics 2017-08-02 Weijun Luo , Rui Yang , Jialun Liu , Yunlong Zhao , Wenjuan Zhu , Guangrui , Xia

We investigate a previously unknown phase of phosphorus that shares its layered structure and high stability with the black phosphorus allotrope. We find the in-plane hexagonal structure and bulk layer stacking of this structure, which we…

Materials Science · Physics 2015-06-19 Zhen Zhu , David Tomanek

Few-layer black phosphorus (FLBP), a recently discovered two-dimensional semiconductor, has attracted substantial attention in the scientific and technical communities due to its great potential in electronic and optoelectronic…

We propose and evaluate the heterostructure based on the graphene-layer (GL) with the lateral electron injection from the side contacts and the hole vertical injection via the black phosphorus layer (PL) (p$^+$PL-PL-GL heterostructure). Due…

Mesoscale and Nanoscale Physics · Physics 2019-10-02 V. Ryzhii , T. Otsuji , M. Ryzhii , A. A. Dubinov , V. Ya. Aleshkin , V. E. Karasik , M. S. Shur

We explore the possibility of using van dar Waals bonded heterostructures of stacked together 2D bilayer black phosphorus (BP) for nanoscale device applications. The electronic property of BP in AA stacking and 90{\deg} twisted is studied…

Applied Physics · Physics 2018-11-09 Vivekanand Shukla , Anton Grigoriev , Rajeev Ahuja

Black phosphorus (BP) has recently emerged as a promising narrow band gap layered semiconductor with optoelectronic properties that bridge the gap between semi-metallic graphene and wide band gap transition metal dichalcogenides such as…

We report on the mechanical properties of few-layer black phosphorus (BP) nanosheets, in high vacuum and as a function of time of exposure to atmospheric conditions [1]. BP flakes with thicknesses ranging from 4 to 30 nm suspended over…

Artificial semiconductor heterostructures played a pivotal role in modern electronic and photonic technologies, providing a highly effective mean for the manipulation and control of carriers, from the visible to the far-infrared. Despite…

Mesoscale and Nanoscale Physics · Physics 2018-05-01 Leonardo Viti , Miriam S. Vitiello
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