English
Related papers

Related papers: Diffusion and Chemical Potential in Polymer Soluti…

200 papers

Pseudopotential theory has greatly driven first-principles calculations in materials, replacing the explicit treatment of the chemically inert core electrons with an effective potential acting only on the valence states. This is inherently…

Materials Science · Physics 2026-05-07 Matteo Quinzi , Tommaso Chiarotti , Nicola Marzari

Various origins of linear and nonlinear Schrodinger equations are discussed in connection with diffusion, hydrodynamics, and fractal structure. The treatment is mainly expository, emphasizing the quantum potential, with a few new…

Quantum Physics · Physics 2007-05-23 Robert Carroll

The research is important for a molecular theory of liquid and has a wide interest as an example solving the problem when dynamic parameters of systems can be indirectly connected with their equilibrium properties. In frameworks of the…

Disordered Systems and Neural Networks · Physics 2007-05-23 Andrei N. Yakunin

Nonequilibrium thermodynamics has shown its applicability in a wide variety of different situations pertaining to fields such as physics, chemistry, biology, and engineering. As successful as it is, however, its current formulation…

Condensed Matter · Physics 2009-11-07 J. M. G. Vilar , J. M. Rubi

A narrow Gaussian excluded volume potential, which tends to a delta-function repulsive potential in the limit of a width parameter d* going to zero, has been used to examine the universal consequences of excluded volume interactions on the…

Soft Condensed Matter · Physics 2020-07-03 K. Satheesh Kumar , J. Ravi Prakash

The morphometric approach is a powerful ansatz for decomposing the chemical potential for a complex solute into purely geometrical terms. This method has proven accuracy in hard spheres, presenting an alternative to comparatively expensive…

Statistical Mechanics · Physics 2019-10-28 Joshua F. Robinson , Roland Roth , C. Patrick Royall

We study the quantum dynamics of a suddenly released beam of particles using a background independent (polymer) quantization scheme. We show that, in the first order of approximation, the low-energy polymer distribution converges to the…

Quantum Physics · Physics 2015-06-22 A. Martín-Ruiz

Recent progress on molecular theories of hydration of nonpolar solutes in aqueous solution has led to new ways of thinking about the old issue of free, or "available," volume in liquids. This article surveys the principal new results with…

Chemical Physics · Physics 2007-05-23 Lawrence R. Pratt , Shekhar Garde , Gerhard Hummer

Tracer-diffusion of small molecules through dense systems of chain polymers is studied within an athermal lattice model, where hard core interactions are taken into account by means of the site exclusion principle. An approximate mapping of…

Soft Condensed Matter · Physics 2009-11-07 O. Durr , T. Volz , W. Dieterich , A. Nitzan

An extension of the H-theorem for dissipative particle dynamics (DPD) to the case of a multi-component fluid is made. Detailed balance and an additional H-theorem are proved for an energy-conserving version of the DPD algorithm. The…

Statistical Mechanics · Physics 2009-10-31 C. A. Marsh , P. V. Coveney

We review the literature on scaled particle theory (SPT) and its extensions and discuss results applied to describe the thermodynamics of hard particle mixtures. After explaining the basic concepts of scaled particle theory to compute the…

Soft Condensed Matter · Physics 2025-07-01 Volodymyr Shmotolokha , Jonas Maier-Borst , Mark Vis , Anja Kuhnhold , Remco Tuinier

In this paper, we use the theory of symmetric Dirichlet forms to give a probabilistic interpretation of Calder\'{o}n's inverse conductivity problem in terms of reflecting diffusion processes and their corresponding boundary trace processes.

Analysis of PDEs · Mathematics 2015-03-27 Petteri Piiroinen , Martin Simon

In this paper, a diffusion-aggregation equation with delta potential is introduced. Based on the global existence and uniform estimates of solutions to the diffusion-aggregation equation, we also provide the rigorous derivation from a…

Analysis of PDEs · Mathematics 2019-12-13 Li Chen , Simone Göttlich , Stephan Knapp

Discrete element method simulations of confined bidisperse granular shear flows elucidate the balance between diffusion and segregation that can lead to either mixed or segregated states, depending on confining pressure. Results indicate…

Soft Condensed Matter · Physics 2018-09-24 Alexander M. Fry , Paul B. Umbanhowar , Julio M. Ottino , Richard M. Lueptow

We present the full thermodynamics of a fluid confined by an arbitrary external potential based on the virial expansion of the grand potential. The fluid may be classical or quantum and it is assumed that interatomic interactions are…

Statistical Mechanics · Physics 2008-08-13 Nadia Sandoval-Figueroa , Víctor Romero-Rochín

In a thermal field theory, the cumulants of the momentum distribution can be extracted from the dependence of the Euclidean path integral on a shift in the fields built into the temporal boundary condition. When combined with the Ward…

High Energy Physics - Lattice · Physics 2015-05-30 Leonardo Giusti , Harvey B. Meyer

We propose a thermodynamically consistent general-purpose model describing diffusion of a solute or a fluid in a solid undergoing possible phase transformations and damage, beside possible visco-inelastic processes. Also heat…

Mathematical Physics · Physics 2015-10-28 Tomas Roubicek , Giuseppe Tomassetti

We present a short overview of the recent results in the theory of diffusion and wave equations with generalised derivative operators. We give generic examples of such generalised diffusion and wave equations, which include time-fractional,…

Statistical Mechanics · Physics 2019-03-05 Trifce Sandev , Ralf Metzler , Aleksei Chechkin

The concept of the derivative-dependent functional separable solution, as a generalization to the functional separable solution, is proposed. As an application, it is used to discuss the generalized nonlinear diffusion equations based on…

Exactly Solvable and Integrable Systems · Physics 2009-11-07 Shun-li Zhang , Sen-yue Lou , Chang-zheng Qu

First steps towards developing a new perturbation theory for molecular liquids are taken. By choosing a new form of splitting the site-site potential functions between molecules, we will get a set of atomic fluids as the reference system…

Chemical Physics · Physics 2017-11-21 Mehrdad Khanpour