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Intercalation is an established technique for tailoring the electronic structure of epitaxial graphene. Moreover, it enables the synthesis of otherwise unstable two-dimensional (2D) layers of elements with unique physical properties…

Mesoscale and Nanoscale Physics · Physics 2022-06-29 Bharti Matta , Philipp Rosenzweig , Olaf Bolkenbaas , Kathrin Küster , Ulrich Starke

Atomistic simulation was performed to study the mechanical properties of few layer graphene (FLG) in conjunction with monlayer graphene (MLG) under uniaxial elongation by systematically increasing the layer number from one to six. We found…

Mesoscale and Nanoscale Physics · Physics 2012-03-02 Young In Jhon , Myung S. Jhon

The calculated results of FeCl3 graphite intercalation compounds show the detailed features. The stage-1 FeCl3-graphite intercalation compounds present diversified electronic properties due to the intercalant. The first-principles…

Materials Science · Physics 2021-01-01 Li Wei-Bang , Lin Shih-Yang , Tsai Ming-Shuei , Lin Ming-Fa , Lin Kuang-I

Molecular-crystalline duality of graphene ensures a tight alliance of its physical and chemical natures, each of which is unique in its own way. The paper examines the physical-chemical harmony and/or confrontation in terms of the molecular…

Mesoscale and Nanoscale Physics · Physics 2013-12-05 Elena F. Sheka

Using full-potential density functional calculations we have investigated the structural and electronic properties of graphene and some of its structural analogues, viz., monolayer (ML) of SiC, GeC, BN, AlN, GaN, ZnO, ZnS and ZnSe. While…

Mesoscale and Nanoscale Physics · Physics 2013-05-30 Gautam Mukhopadhyay , Harihar Behera

One popular approach to prepare graphene is to grow them on transition metal substrates via chemical vapor deposition. By using the density functional theory with dispersion correction, we systematically investigate for the first time the…

Materials Science · Physics 2015-06-03 Jiaxin Zheng , Yangyang Wang , Lu Wang , Ruge Quhe , Zeyuan Ni , Wai-Ning Mei , Zhengxiang Gao , Dapeng Yu , Junjie Shi , Jing Lu

A conversion of AA- to AB-stacking bilayer graphene (BLG) due to interlayer interaction is demonstrated. Two types of interlayer interactions, an attractive and a repulsive, between the Boron and Nitrogen dopant atoms in BLG are found. In…

Mesoscale and Nanoscale Physics · Physics 2022-04-05 Nzar Rauf Abdullah , Hunar Omar Rashid , Chi-Shung Tang , Andrei Manolescu , Vidar Gudmundsson

Among two-dimensional atomic crystals, hexagonal boron nitride (hBN) is one of the most remarkable materials to fabricate heterostructures revealing unusual properties. We perform first-principles calculations to determine whether…

Mesoscale and Nanoscale Physics · Physics 2014-04-09 Sohee Park , Changwon Park , Gunn Kim

We investigate the effects of lithium intercalation in twisted bilayers of graphene, using first-principles electronic structure calculations. To model this system we employ commensurate supercells that correspond to twist angles of…

Mesoscale and Nanoscale Physics · Physics 2020-02-11 Daniel T. Larson , Stephen Carr , Georgios A. Tritsaris , Efthimios Kaxiras

Work function-mediated charge transfer in graphene/$\alpha$-RuCl$_3$ heterostructures has been proposed as a strategy for generating highly-doped 2D interfaces. In this geometry, graphene should become sufficiently doped to host surface and…

We present microscopic investigations on the two-dimensional arrangement of cobalt phthalocyanine molecules on a graphite (HOPG) substrate in the low coverage regime. The initial growth and ordering of molecular layers is revealed in high…

Chemical Physics · Physics 2014-07-08 M. Scheffler , L. Smykalla , D. Baumann , R. Schlegel , T. Hänke , M. Toader , B. Büchner , M. Hietschold , C. Hess

We investigate the possibility of non-destructive electron diffraction imaging of a single molecule to determine its structure. The molecular specimen will be held on a free-standing sheet of graphene. Due to the high conductivity of…

Chemical Physics · Physics 2009-11-13 E. E. Fill , F. Krausz , M. Raizen

Twisted double bilayer graphene has recently emerged as an interesting moir\'e material that exhibits strong correlation phenomena that are tunable by an applied electric field. Here we study the atomic and electronic properties of three…

We study the effects of an attractive interaction between the boron (B) and the nitrogen (N) atoms doped in a bilayer graphene (BLG), BC$_{14}$N, on the electronic, the thermal and the optical properties for two different types of a doping…

Mesoscale and Nanoscale Physics · Physics 2021-08-03 Nzar Rauf Abdullah , Hunar Omar Rashid , Vidar Gudmundsson

The current state of the art in structural biology is led by NMR, X-ray crystallography and TEM investigations. These powerful tools however all rely on averaging over a large ensemble of molecules. Here, we present an alternative concept…

Atomic and Molecular Clusters · Physics 2015-12-15 Tatiana Latychevskaia , Jean-Nicolas Longchamp , Conrad Escher , Hans-Werner Fink

Many intercalation compounds possess layered structures or inter-penetrating lattices that enable phase separation into three or more stable phases, or "stages," driven by competing intra-layer and inter-layer forces. While these structures…

Chemical Physics · Physics 2017-06-27 Raymond B. Smith , Edwin Khoo , Martin Z. Bazant

Experimental realization of graphene-based stadium-shaped quantum dots (QDs) have been few and incompatible with scanned probe microscopy. Yet, direct visualization of electronic states within these QDs is crucial for determining the…

The structure, and electrical, mechanical and optical properties of few-layer graphene (FLG) synthesized by chemical vapor deposition (CVD) on a Ni coated substrate were studied. Atomic resolution transmission electron microscope (TEM)…

Mesoscale and Nanoscale Physics · Physics 2010-01-18 Hye Jin Park , Jannik Meyer , Siegmar Roth , Viera Skakalova

Graphene monolayer is a material with zero band gap, because of which its applications in optoelectronics are limited. The question arises, can we modify the optoelectronic properties of graphene by doping it with other atoms? Synthesis of…

Materials Science · Physics 2026-03-18 Samayita Das , Alok Shukla

Chemical, mechanical, thermal and/or electronic properties of bulk or low-dimensional materials can be engineered by introducing structural defects to form novel functionalities. When using particles irradiation, these defects can be…

Materials Science · Physics 2022-02-07 L. Basta , A. Moscardini , S. Veronesi , F. Bianco