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Metal-air batteries are among the most promising next-generation energy storage devices. Relying on abundant materials and offering high energy densities, potential applications lie in the fields of electro-mobility, portable electronics,…

Chemical Physics · Physics 2017-06-15 Johannes Stamm , Alberto Varzi , Arnulf Latz , Birger Horstmann

Nickel/zinc (Ni/Zn) technology is a promising post-lithium battery type for stationary applications with respect to aspects such as safety, environmental compatibility and resource availability. Although this battery type has been known for…

Attaining high reversibility of electrodes and electrolyte is essential for the longevity of secondary batteries. Rechargeable zinc-air batteries (RZABs), however, encounter drastic irreversible changes in the zinc anodes and air cathodes…

Materials Science · Physics 2023-08-10 Zhibin Yi , Liangyu Li , Cheuk Kai Chan , Yaxin Tang , Zhouguang Lu , Chunyi Zhi , Qing Chen , Guangfu Luo

Liquid metal batteries (LMBs) are a promising alternative for large-scale stationary energy storage for renewable applications. Using high-abundance electrode materials such as Sodium and Zinc is highly desirable due to their low cost and…

Materials Science · Physics 2023-06-09 Omar E. Godinez-Brizuela , Carolina Duczek , Norbert Weber , Kristian E. Einarsrud

This paper presents a combined theoretical and experimental investigation of aqueous near-neutral electrolytes based on chloride salts for rechargeable zinc-air batteries (ZABs). The resilience of near-neutral chloride electrolytes in air…

Zinc-based batteries offer good volumetric energy densities and are compatible with environmentally friendly aqueous electrolytes. Zinc-ion batteries (ZIBs) rely on a lithium-ion-like Zn$^{2+}$-shuttle, which enables higher roundtrip…

Chemical Physics · Physics 2023-12-11 Niklas J. Herrmann , Holger Euchner , Axel Groß , Birger Horstmann

This study presents a comprehensive Multiphysics model for zinc-ion batteries (ZIBs), incorporating electrochemical aspects. The model integrates the mass transport of Zn2+ ions, charge transfer, and solid diffusion to predict performance…

Materials Science · Physics 2025-05-06 Roya Rajabi , Shichen Sun , Booker Wu , Jamil Khan , Kevin Huang

Aqueous zinc-air batteries (ZABs) are a low-cost, safe, and sustainable technology for stationary energy storage. ZABs with pH-buffered near-neutral electrolytes have the potential for longer lifetime compared to traditional alkaline ZABs…

Zinc-ion batteries are promising alternatives to lithium-ion batteries, offering advantages in safety, cost, and environmental impact. However, their performance is often limited by the functioning of the zinc anode. This study employs…

Materials Science · Physics 2025-03-31 Xinxin Hu , Shivam Dangwal , Xucheng Wang , Fan Zhang , Haijuan Kong , Jun Li , Kaveh Edalati

Higher energy density and longer lifetime are the requirements for next-generation lithium-ion batteries. A promising anode material is silicon, which offers high specific capacity, but its significant volume change during lithiation and…

Silicon (Si) anodes attract a lot of research attention for their potential to enable high energy density lithium-ion batteries (LIBs). Many studies focus on nanostructured Si anodes to counteract deterioration. In this work, we model LIBs…

Chemical Physics · Physics 2024-04-23 Franziska Kilchert , Max Schammer , Arnulf Latz , Birger Horstmann

In this article, we derive a general form of local volume-averaging theory and apply it to a model of zinc-air conversion batteries. Volume-averaging techniques are frequently used for the macroscopic description of micro-porous electrodes.…

Chemical Physics · Physics 2020-04-03 Tobias Schmitt , Arnulf Latz , Birger Horstmann

This paper presents the current state of mathematical modelling of the electrochemical behaviour of lithium-ion batteries as they are charged and discharged. It reviews the models developed by Newman and co-workers, both in the cases of…

Chemical Physics · Physics 2020-02-04 Giles W Richardson , Jamie M Foster , Rahifa Ranom , Colin P Please , Angel M Ramos

Next-generation lithium-ion batteries with silicon anodes have positive characteristics due to higher energy densities compared to state-of-the-art graphite anodes. However, the large volume expansion of silicon anodes can cause high…

Numerical Analysis · Mathematics 2024-04-03 R. Schoof , G. F. Castelli , W. Dörfler

In recent years there has been a major interest in developing all solid state batteries, for the sake of safety (issues due to toxic and flammable organic liquid electrolytes are well known) as well as of high energy density…

Materials Science · Physics 2021-05-07 L. Cabras , V. Oancea , A. Salvadori

The conversion of heat into current can be obtained by a process with two stages. In the first one, the heat is used for distilling a solution and obtaining two flows with different concentrations. In the second stage, the two flows are…

Chemical Physics · Physics 2014-03-18 M. Marino , L. Misuri , A. Carati , D. Brogioli

The demand for lithium ion batteries (LIBs) on the market has gradually risen, with production increasing every year. To meet industrial needs, the development of digital twins designed to optimize LIB manufacturing processes is essential.…

Efficient energy storage systems are crucial to address the intermittency of renewable energy sources. As multivalent batteries, Zn-ion batteries (ZIBs), while inherently low voltage, offer a promising low cost alternative to Li-ion…

Materials Science · Physics 2025-04-17 Roberta Pascazio , Qian Chen , Haoming Howard Li , Aaron D. Kaplan , Kristin A. Persson

In this article, a novel implementation of a widely used pseudo-two-dimensional (P2D) model for lithium-ion battery simulation is presented with a transmission line circuit structure. This implementation represents an interplay between…

Chemical Physics · Physics 2021-11-03 Zeyang Geng , Siyang Wang , Matthew J. Lacey , Daniel Brandell , Torbjörn Thiringer

Silicon-containing lithium-ion batteries can exhibit capacity gain early in life, which makes forecasting future cell behavior difficult. We have observed these anomalous trends even in conditions where known mechanisms, such as overhang…

Chemical Physics · Physics 2026-02-17 Marco-Tulio F. Rodrigues , Charles McDaniel , Stephen E. Trask , Daniel P. Abraham
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