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We propose a hybrid approach which employs the dynamical mean-field theory (DMFT) self-energy for the correlated, typically rather localized orbitals and a conventional density functional theory (DFT) exchange-correlation potential for the…

Strongly Correlated Electrons · Physics 2021-06-16 Sumanta Bhandary , Karsten Held

We study the spin-crossover molecule Fe(phen)$_2$(NCS)$_2$ using density functional theory (DFT) plus dynamical mean-field theory, which allows access to observables not attainable with traditional quantum chemical or electronic structure…

Materials Science · Physics 2015-06-30 Jia Chen , Andrew Millis , Chris Marianetti

A quantitative and predictive theory of quantum light-matter interactions in ultra thin materials involves several fundamental challenges. Any realistic model must simultaneously account for the ultra-confined plasmonic modes and their…

Normally, understanding the temperature dependent transport properties of strongly correlated electron systems remains challenging task due to complex electronic structure and its variations (around E$_{F}$) with temperature. Here, we…

Strongly Correlated Electrons · Physics 2017-03-21 Saurabh Singh , Devendra Kumar , Sudhir K. Pandey

Density-functional studies of the electronic structures and exchange interaction parameters have been performed for a series of ferromagnetic full Heusler alloys of general formula Co$_2$MnZ (Z = Ga, Si, Ge, Sn), Rh$_2$MnZ (Z = Ge, Sn, Pb),…

Materials Science · Physics 2009-11-10 Yasemin Kurtulus , Richard Dronskowski , German Samolyuk , Vladimir P. Antropov

The stochastic density functional theory (DFT) [Phys. Rev. Lett. 111, 106402 (2013)] is a valuable linear scaling approach to Kohn-Sham DFT that does not rely on the sparsity of the density matrix. Linear (and often sub-linear) scaling is…

Chemical Physics · Physics 2019-02-20 Ming Chen , Roi Baer , Daniel Neuhauser , Eran Rabani

Effects of Coulomb correlation on LaOFeAs electronic structure have been investigated by LDA+DMFT(QMC) method. The calculation results show that LaOFeAs is in the regime of intermediate correlation strength with significant part of the…

Strongly Correlated Electrons · Physics 2009-11-13 A. O. Shorikov , M. A. Korotin , S. V. Streltsov , S. L. Skornyakov , D. M. Korotin , V. I. Anisimov

There has been a high demand in rectifying the band gap under-estimation problem in density functional theory (DFT), while keeping the computational load at the same level as local density approximation. DFT-1/2 and shell DFT-1/2 are useful…

Materials Science · Physics 2025-07-08 Shengxin Yang , Jiangzhen Shi , Kan-Hao Xue , Jun-Hui Yuan , Xiangshui Miao

Density functional theory calculations within the generalized gradient approximation are employed to study the ground state of Co2FeAl. Various magnetic configurations are considered to find out its most stable phase. The ferromagnetic…

Strongly Correlated Electrons · Physics 2020-06-25 Aquil Ahmad , S. K. Srivastava , A. K. Das

Density-functional theory with extended Hubbard functionals (DFT+$U$+$V$) provides a robust framework to accurately describe complex materials containing transition-metal or rare-earth elements. It does so by mitigating self-interaction…

Materials Science · Physics 2025-01-30 Martin Uhrin , Austin Zadoks , Luca Binci , Nicola Marzari , Iurii Timrov

A density functional theory (DFT) approach to computing transition metal oxide heat of formation without adjustable parameters is presented. Different degrees of $d$-electron localization in oxides are treated within the DFT+$U$ approach…

Materials Science · Physics 2022-04-01 Johannes Voss

Several methods have been developed to improve the predictions of density functional theory (DFT) in the case of strongly correlated electron systems. Out of these approaches, DFT+$U$, which corresponds to a static treatment of the local…

Strongly Correlated Electrons · Physics 2025-04-01 Alberto Carta , Iurii Timrov , Peter Mlkvik , Alexander Hampel , Claude Ederer

The journey of theoretical study on semiconductors is reviewed in a non-conventional way. We have started with the basic introduction of Hartree-Fock method and introduce the fundamentals of Density Functional Theory (DFT). From the oldest…

Materials Science · Physics 2021-05-04 Sujoy Datta , Debnarayan Jana

The electronic band structure-controlled ultrafast demagnetization mechanism in Co2FexMn1-xSi Heusler alloy is underpinned by systematic variation of composition. We find the spin-flip scattering rate controlled by spin density of states at…

Materials Science · Physics 2020-07-01 Santanu Pan , Takeshi Seki , Koki Takanashi , Anjan Barman

First-principles density functional theory (DFT) is employed to investigate the interactions of CO2 gas molecules with pristine and lithium-functionalized germanene. It is discovered that although a single CO2 molecule is weakly physisorbed…

Mesoscale and Nanoscale Physics · Physics 2017-05-17 S. M. Aghaei , M. M. Monshi , I. Torres , I. Calizo

We propose and investigate the properties of a digital ferromagnetic heterostructure (DFH) consisting of a $\delta$-doped layer of Mn in Si, using \textit{ab initio} electronic-structure methods. We find that (i) ferromagnetic order of the…

Materials Science · Physics 2009-11-11 M. C. Qian , C. Y. Fong , Kai Liu , Warren E. Pickett , J. E. Pask , L. H. Yang

We investigate the structural, electronic and magnetic properties of the full Heusler compounds Mn$_2$YSn (Y = Mo, Nb, Zr) by first-principles density functional theory using the generalized gradient approximation. It is found that the…

Materials Science · Physics 2021-03-30 S. Zeffane , M. Sayah , F. Dahmane , M. Mokhtari , L. Zekri , R. Khenata , N. Zekri

In this paper, we have presented the density functional theory (DFT) based calculations performed within the first-principles pseudopotential method to investigate the physical properties of the newly discovered superconductor LaRu2As2 for…

Materials Science · Physics 2017-04-05 M. A. Hadi , M. S. Ali , S. H. Naqib , A. K. M. A. Islam

In approximate density functional theory (DFT), the self-interaction error is an electron delocalization anomaly associated with underestimated insulating gaps. It exhibits a predominantly quadratic energy-density curve that is amenable to…

Chemical Physics · Physics 2016-12-21 Glenn Moynihan , Gilberto Teobaldi , David D. O'Regan

Novel low-band-gap copolymer oligomers are proposed on the basis of density functional theory (DFT) quantum chemical calculations of photophysical properties. These molecules have an electron donor-accepter (D-A) architecture involving…

Chemical Physics · Physics 2017-08-18 Tarek Mestiri , Ala Aldin M. H. M. Darghouth , Mark E. Casida , Kamel Alimi