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Polymeric ionic liquids are emerging polyelectrolyte materials for modern electrochemical applications. In this paper, we propose a self-consistent field theory of the polymeric ionic liquid on a charged conductive electrode. Taking into…

Soft Condensed Matter · Physics 2022-02-02 Yury A. Budkov , Nikolai N. Kalikin , Andrei L. Kolesnikov

Finding new ionic conductors that enable significant advancements in the development of energy-storage devices is a challenging goal of current material science. Aside of material classes as ionic liquids or amorphous ion conductors, the…

Materials Science · Physics 2015-09-02 K. Geirhos , P. Lunkenheimer , M. Michl , D. Reuter , A. Loidl

When transistor gate insulators have nanometer-scale equivalent oxide thickness (EOT), the gate capacitance ($C_\textrm{G}$) becomes smaller than the oxide capacitance ($C_\textrm{ox}$) due to the quantum capacitance and charge centroid…

Mesoscale and Nanoscale Physics · Physics 2023-02-15 Robert K. A. Bennett , Eric Pop

Diamond and many newly emerged semiconductor materials show outstanding optical and magnetic properties. However, they cannot be as efficiently doped as silicon or gallium arsenide, which limits their practical applicability. Here, we…

Applied Physics · Physics 2019-04-29 Igor A. Khramtsov , Dmitry Yu. Fedyanin

Local control of superconducting circuits by high-impedance electrical gates offers potential advantages in superconducting logic, quantum processing units, and cryoelectronics. Recent experiments have reported gate-controlled supercurrent…

Superconductivity · Physics 2025-10-20 François Joint , Kazi Rafsanjani Amin , Ivo Cools , Simone Gasparinetti

The periodic spatial modulation potential arising from the zig-zag distribution of ions at large gate voltage in an ionic liquid gated device may enable functionalities in a similar way as nanopatterning and moir\'e engineering. However,…

Mesoscale and Nanoscale Physics · Physics 2025-04-28 Qiao Chen , Chengyu Yan , Changshuai Lan , Qiyang Song , Yi Yan , Shun Wang

A theory is constructed for dense ionic solutions near charged planar walls that is valid for strong inter-ionic correlations. This theory predicts a fluctuation-induced, first-order transition and spontaneous charge density ordering at the…

Mesoscale and Nanoscale Physics · Physics 2016-06-24 David T. Limmer

A Poisson-Boltzmann approach is used to determine the double-layer integral and differential capacitances in a finite-length situation for an electrolytic cell. By means of simple analytical calculations, it is shown how these quantities…

Statistical Mechanics · Physics 2012-04-03 Roberta Rarumy Ribeiro de Almeida , Luiz Roberto Evangelista , Giovanni Barbero

The distribution of electric fields within the electrochemical double layer depends on both the electrode and electrolyte in complex ways. These fields strongly influence chemical dynamics in the electrode-electrolyte interface, but cannot…

Pseudocapacitors are energy-storage devices characterized by fast and reversible redox reactions that enable them to store large amounts of electrical energy at high rates. We simulate the response of pseudocapacitive electrodes under…

Materials Science · Physics 2017-05-19 Nathan Keilbart , Yasuaki Okada , Aion Feehan , Shinichi Higai , Ismaila Dabo

Silicon is one of the most promising anode materials for Lithium-ion batteries. Silicon endures volume changes upon cycling, which leads to subsequent pulverization and capacity fading. These drawbacks lead to a poor lifespan and hamper the…

Materials Science · Physics 2022-12-23 Mariam Ezzedine , Fatme Jardali , Ileana Florea , Mihai-robert Zamfir , Costel-sorin Cojocaru

Supercapacitors store energy via the formation of an electric double layer, which generates a strong electric field at the electrode-electrolyte interface. Unlike conventional metallic electrodes, graphene-derived materials suffer from a…

Materials Science · Physics 2015-03-12 Maxwell D. Radin , Tadashi Ogitsu , Minoru Otani , Juergen Biener , Brandon C. Wood

Most attempts to produce a scalable quantum information processing platform based on ion traps have focused on the shuttling of ions in segmented traps. We show that an architecture based on an array of microtraps with fast gates will…

We introduce a silicon metal-oxide-semiconductor quantum dot architecture based on a single polysilicon gate stack. The elementary structure consists of two enhancement gates separated spatially by a gap, one gate forming a reservoir and…

Mesoscale and Nanoscale Physics · Physics 2019-03-07 S. Rochette , M. Rudolph , A. -M. Roy , M. Curry , G. Ten Eyck , R. Manginell , J. Wendt , T. Pluym , S. M. Carr , D. Ward , M. P. Lilly , M. S. Carroll , M. Pioro-Ladrière

To improve the understanding of the relation between electrode curvature and energy storage mechanisms, a systematic investigation of the correlation between convex and concave electrode surfaces and the differential capacitance of an…

Computational Physics · Physics 2020-03-04 Jannes Seebeck , Peter Schiffels , Sabine Schweizer , Jörg-Rüdiger Hill , Robert Horst Meißner

We use surface enhanced Raman spectroscopy (SERS) in studying functionalized Au nanoparticles (AuNPs) when incorporated in active-carbon (A-C) based super-capacitor cells. We observe a resonance-like enhancement in the graphitic line…

Mesoscale and Nanoscale Physics · Physics 2023-09-18 H. Grebel , Y. Zhang

Many electrical applications of quantum dots rely on capacitively coupled gates; therefore, to make reliable devices we need those gate capacitances to be predictable and reproducible. We demonstrate in silicon nanowire quantum dots that…

Mesoscale and Nanoscale Physics · Physics 2015-06-05 Ted Thorbeck , Akira Fujiwara , Neil M. Zimmerman

Supercapacitors are electric devices able to deliver a large power, enabling their use e.g. for the recovery of breaking energy in cars. This is achieved by using two carbon electrodes and an electrolyte solution or a pure ionic liquid…

Chemical Physics · Physics 2018-11-26 Céline Merlet , Clarisse Péan , Mathieu Salanne , Benjamin Rotenberg

Superconducting diodes are a recently-discovered quantum analogueue of classical diodes. The superconducting diode effect relies on the breaking of both time-reversal and inversion symmetry. As a result, the critical current of a…

Located at crystal voids, interstitial anion electrons (IAEs) have diverse topologies, which may be tuned to achieve new properties. Elucidating the role of IAEs in electron-phonon coupling (EPC), and using it to design new electride…

Superconductivity · Physics 2023-03-29 Xiaohua Zhang , Yansun Yao , Shicong Ding , Aitor Bergara , Fei Li , Yong Liu , Xiang-Feng Zhou , Guochun Yang
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