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We show how to increase the capacitance of super-capacitors by modifying the otherwise passive separator layer and turn it into an active diode-like structure. We demonstrate 15% capacitance increase for a diode-like separators without a…

Chemical Physics · Physics 2018-08-21 Tazima S. Chowdhury , Haim Grebel

In order to make a densely packed assembly of undoped semiconductor nanocrystals conductive, it is usually gated by a room temperature ionic liquid. The ionic liquid enters the pores of the super-crystal assembly under the influence of an…

Mesoscale and Nanoscale Physics · Physics 2011-12-15 Tianran Chen , Brian Skinner , B. I. Shklovskii

Nanoporous carbon-based supercapacitors store electricity through adsorption of ions from the electrolyte at the surface of the electrodes. Room temperature ionic liquids, which show the largest ion concentrations among organic liquid…

We study the electrode polarization behaviour of different Na-Ca-phosphosilicate glasses by measuring the differential capacitance between blocking Pt electrodes. At low applied dc bias voltages, we detect a linear capacitance regime with…

Disordered Systems and Neural Networks · Physics 2009-11-11 C. R. Mariappan , T. P. Heins , B. Roling

Capacitors are typically connected together in one of two configurations: either in series, or in parallel. Here we study a capacitor-within-capacitor (CWC). Simulations and experiments indicate that the overall capacitance of the…

General Physics · Physics 2019-07-09 Haim Grebel

Electronic logic gates are the basic building blocks of every computing and micro controlling system. Logic gates are made of switches, such as diodes and transistors. Ion-selective, ionic switches may emulate electronic switches [1-8]. If…

Chemical Physics · Physics 2017-10-11 Haim Grebel

In this work we theoretically study the differential capacitance of an aqueous electrolyte in contact with a planar electrode, using classical Density Functional Theory, and show how this measurable quantity can be used as a probe to better…

Soft Condensed Matter · Physics 2021-09-16 Peter Cats , René van Roij

In the recent experiments [Chmiola et al, Science 313, 1760 (2006); Largeot et al, J. Am. Chem. Soc. 130, 2730 (2008)] an anomalous increase of the capacitance with a decrease of the pore size of a carbon-based porous electric double-layer…

Soft Condensed Matter · Physics 2015-03-17 S. Kondrat , A. Kornyshev

A new type of a capacitor with a very high volumetric capacitance is proposed. It is based upon the known phenomenon of a sharp increase of the dielectric constant of the metal-insulator composite in the vicinity of the percolation…

Mesoscale and Nanoscale Physics · Physics 2015-05-27 A. L. Efros

Due to the importance of using supercapacitors in electronic storage devices, improving their efficiency is one of the topics that has attracted the attention of many researchers. Choosing the proper electrolyte for supercapacitors is one…

Computational Physics · Physics 2023-01-04 Nasrin Eyvazi , Davood Abbaszadeh , Morad Biagooi , SeyedEhsan Nedaaee Oskoee

This article presents the implementation of on-chip iontronic circuits via small-scale integration of multiple ionic logic gates made of bi-polar polyelectrolyte diodes. These ionic circuits are analogous to solid-state electronic circuits,…

Fluid Dynamics · Physics 2022-11-24 Barak Sabbagh , Noa Edri Fraiman , Alex Fish , Gilad Yossifon

For a capacitor made of a semiconducting carbon nanotube (CNT) suspended above a metallic gate, Coulomb correlations between individual electrons can lead to a capacitance that is much larger than the geometric capacitance. We argue that…

Strongly Correlated Electrons · Physics 2015-04-22 Han Fu , B. I. Shklovskii , Brian Skinner

We report the operation of a field-effect transistor based on a single InAs nanowire gated by an ionic liquid. Liquid gating yields very efficient carrier modulation with a transconductance value thirty time larger than standard back gating…

Impressive progress in the control of atomically thin crystals is now enabling the realization of gated structures in which two electrodes are separated by atomic scale distances. The electrical capacitance of these structures is determined…

Mesoscale and Nanoscale Physics · Physics 2021-10-18 Christophe Berthod , Haijing Zhang , Alberto F. Morpurgo , Thierry Giamarchi

Nanopores made with low dimensional semiconducting materials, such as carbon nanotubes and graphene slit pores, are used in supercapacitors. In theories and simulations of their operation, it is often assumed that such pores screen ion-ion…

Materials Science · Physics 2017-01-24 Alpha A. Lee , Dominic Vella , Alain Goriely

Understanding the electrodes' surface morphology influence on the ions' distribution is essential for designing the supercapacitors with enhanced energy density characteristics. We develop a model for the structure of electrolytes near the…

Statistical Mechanics · Physics 2021-06-30 Timur Aslyamov , Konstantin Sinkov , Iskander Akhatov

Quantum dots (QDs), embedded in supercapacitors (S-C) cells exhibited capacitance amplification that peaked at certain QD concentration. More than 2.5 peak amplification was demonstrated with cyclic voltammetry (C-V) at a scan rate of 0.1…

Chemical Physics · Physics 2025-08-25 H. Grebel

Silicon-containing lithium-ion batteries can exhibit capacity gain early in life, which makes forecasting future cell behavior difficult. We have observed these anomalous trends even in conditions where known mechanisms, such as overhang…

Chemical Physics · Physics 2026-02-17 Marco-Tulio F. Rodrigues , Charles McDaniel , Stephen E. Trask , Daniel P. Abraham

Using molecular dynamics simulations with recently developed importance sampling methods, we show that the differential capacitance of a model ionic liquid based double-layer capacitor exhibits an anomalous dependence on the applied…

The capacitance and differential conductance of MBE-grown AlGaAs/GaAs p-i-n diodes are investigated. In these diodes, the p-doped layer, an adjacent intrinsic spacer, and a central barrier are made of AlGaAs. Capacitance oscillations and…

Mesoscale and Nanoscale Physics · Physics 2025-04-29 Miranda Leigh Davis , Simon Parolo , Sandro Agostini , Christian Reichl , Werner Dietsche , Werner Wegscheider
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