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The ideal gas law of physics and chemistry says that PV = nRT. This law is a statement of the relationship between four variables (P, V, n, and T) that reflect properties of a quantity of gas in a container. The law enables us to make…
The equations of state for an ideal generalized gas, like an ideal quantum gas, are expressed in terms of power laws of the temperature. The reduction of an ideal generalized gas to an ideal classical case occurs when the characteristic…
There is a long-standing question as to whether and to what extent it is possible to describe nonequilibrium systems in stationary states in terms of global thermodynamic functions. The positive answers have been obtained only for…
The thermodynamical properties of interacting Bose atoms in a harmonic potential are studied within the mean-field approximation. For weak interactions, the quantum statistics is equivalent to an ideal gas in an effective mean-field…
We show that for any liquid or solid with strong correlation between its $NVT$ virial and potential-energy equilibrium fluctuations, the temperature is a product of a function of excess entropy per particle and a function of density,…
We develop a model for the thermodynamics and evaporation dynamics of aerosol droplets of a liquid such as water, surrounded by the gas. When the temperature and the chemical potential (or equivalently the humidity) are such that the vapour…
For a gas confined in a container, particle-wall interactions produce modifications to the partition function involving the average surface density of gas particles. While such correlations have a vanishing effect in the thermodynamic…
From sand piles to electrons in metals, one of the greatest challenges in modern physics is to understand the behavior of an ensemble of strongly interacting particles. A class of quantum many-body systems such as neutron matter and cold…
Starting from a formulation for the $dS$ element that includes movement, and considering the variation of the entropy Lorentz invariant, we found the relativistic transformations for thermodynamic systems that satisfy the three laws of…
Compressible flow varies from ideal-gas behavior at high pressures where molecular interactions become important. Density is described through a cubic equation of state while enthalpy and sound speed are functions of both temperature and…
We derive here, from first principles, the energy-momentum densities of a perfect fluid, in the form of an ideal molecular gas, in an inertial frame where the fluid possesses a bulk motion. We begin from the simple expressions for the…
Condensed matter is thermodynamically unstable in a vacuum. That is what thermodynamics tells us through the relation showing that condensed matter at temperatures above absolute zero always has non-zero vapour pressure. This instability…
No bootstrap assumption is needed to derive the exponential growth of the Hagedorn hadron mass spectrum: It is a consequence of the second law applied to a relativistic gas, and the relativistic equivalence between inertial mass and its…
Thermodynamics of power means applies to an ideal quantum gas which may be nonextensive. Transition to an ideal classical gas occurs when the empirical temperature exponents of the internal energy and absolute temperature coalesce. Limiting…
I develop simple thermodynamic relations for a collection of noninteracting classical particles confined in a harmonic trap. The volume of such a trap is not a good thermodynamic variable, so conventional expressions of the first law of…
Studying the thermodynamics of the systems produced in ultra-relativistic heavy-ion collisions is crucial in understanding the QCD phase diagram. Recently, a new avenue has opened regarding the implications of large initial angular momentum…
Previous approaches of emergent thermalization for condensed matter based on typical wavefunctions are extended to generate an intrinsically quantum theory of gases. Gases are fundamentally quantum objects at all temperatures, by virtue of…
We show that when the thermal wavelength is comparable to the spatial size of a system, thermodynamic observables like Pressure and Volume have quantum fluctuations that cannot be ignored. They are now represented by operators; conventional…
Numerical heat and mass transfer analysis of a configuration where a cool liquid hydrocarbon is suddenly introduced to a hotter gas at supercritical pressure shows that a well-defined phase equilibrium can be established before substantial…
The purpose of this note is to see to what extent ideal gas laws can be obtained from simple Newtonian mechanics, specifically elastic collisions. We present simple one-dimensional situations that seem to validate the laws. The first…