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Thin films made of deformable micro- and nano-units, such as biological membranes, polymer interfaces, and particle-laden liquid surfaces, exhibit a complex behavior during drying, with consequences for various applications like wound…

We study the thermodynamics of binary mixtures with the volume fraction of the minority component less than the amount required to form a flat interface and show that the surface tension dominated equilibrium phase of the mixture forms a…

Soft Condensed Matter · Physics 2023-03-07 Subhadip Biswas , Biswaroop Mukherjee , Buddhapriya Chakrabarti

We combine small angle scattering experiments and simulations to investigate the internal structure and interactions of composite Poly(N-isopropylacrylamide)-Poly(ethylene glycol) (PNIPAM-PEG) microgels. At low temperatures the…

Ionic microgel particles in a good solvent swell to an equilibrium size determined by a balance of electrostatic and elastic forces. When crowded, ionic microgels deswell owing to a redistribution of microions inside and outside the…

Soft Condensed Matter · Physics 2020-01-08 Mariano E. Brito , Alan R. Denton , Gerhard Nägele

We present simulation results addressing the dynamics of a colloidal system with attractive interactions close to gelation. Our interaction also has a soft, long range repulsive barrier which suppresses liquid-gas type phase separation at…

Soft Condensed Matter · Physics 2007-05-23 Antonio M. Puertas , Matthias Fuchs , Michael E. Cates

Interactions between colloidal particles have hitherto usually been fixed by the suspension composition. Recent experimental developments now enable the control of interactions \emph{in-situ}. Here we use Brownian dynamics simulations to…

Soft Condensed Matter · Physics 2017-02-08 C. Patrick Royall , Alex Malins

Accurate interaction potentials between microscopic components such as colloidal particles or cells are crucial to understanding a range of processes, including colloidal crystallization, bacterial colony formation, and cancer metastasis.…

Thermo-responsive hydrogels are a promising material for creating controllable actuators for use in micro-scale devices, since they expand and contract significantly (absorbing or expelling fluid) in response to relatively small temperature…

Soft Condensed Matter · Physics 2022-08-18 Matthew D. Butler , Thomas D. Montenegro-Johnson

The transport properties of colloidal particles in active liquids have been studied extensively. It has led to a deeper understanding of the interactions between passive and active particles. However, the phase behavior of colloidal…

Soft Condensed Matter · Physics 2023-01-30 Pragya Kushwaha , Vivek Semwal , Sayan Maity , Shraddha Mishra , Vijayakumar Chikkadi

We demonstrate that the configurational temperature formalism can be derived from the classical hypervirial theorem, and introduce a hierarchy of hyperconfigurational temperature definitions, which are particularly well suited for…

Soft Condensed Matter · Physics 2009-11-10 Yilong Han , David G. grier

This is an integrated experimental and theoretical study of the dynamics and rheology of self-crosslinked, slightly charged, temperature responsive soft Poly(N-isopropylacrylamide) (pNIPAM) microgels over a wide range of concentration and…

Soft Condensed Matter · Physics 2021-03-04 Gaurav Chaudhary , Ashesh Ghosh , Jin Gu Kang , Paul V. Braun , Randy H. Ewoldt , Kenneth S. Schweizer

Thermo-responsive microgel particles can exhibit a drastic volume shrinkage upon increasing the solvent temperature. Recently we found that the spreading of poly(N-isopropylacrylamide)(PNiPAm) microgels at a liquid interface under the…

Lateral microsegregation in a monolayer of a binary mixture of particles or macromolecules is studied by MD simulations in a generic model with the interacting potentials inspired by effective interactions in biological or soft-matter…

Soft Condensed Matter · Physics 2025-05-26 M. Litniewski , W. T. Gozdz nd A. Ciach

Colloidal gels are a prototypical example of a heterogeneous network solid whose complex properties are governed by thermally-activated dynamics. In this Letter we experimentally establish the connection between the intermittent dynamics of…

Soft Condensed Matter · Physics 2017-05-10 Jan Maarten van Doorn , Jochem Bronkhorst , Ruben Higler , Ties van de Laar , Joris Sprakel

Molecular dynamics simulations are performed to study spatially heterogeneous dynamics in a model of viscous silica above and below the critical temperature of the mode coupling theory, $T_{MCT}$. Specifically, we follow the evolution of…

Soft Condensed Matter · Physics 2009-11-10 M. Vogel , S. C. Glotzer

We use direct numerical simulations to investigate the interaction between the temperature field of a fluid and the temperature of small particles suspended in the flow, employing both one and two-way thermal coupling, in a statistically…

Fluid Dynamics · Physics 2020-01-08 Maurizio Carbone , Andrew D. Bragg , Michele Iovieno

A hydrodynamic mechanism of interactions of colloidal particles is considered. The mechanism is based on the assumption of tiny background flows in the experimental cells during measurements by Grier at al. [1-6]. Both trivial (shear flow)…

Soft Condensed Matter · Physics 2007-05-23 Yuri O. Popov

The study of the interactions of living adherent cells with mechanically stable (visco)elastic materials enables understanding and exploiting physiological phenomena mediated by cell-extracellular communication. However, insight on the…

Equilibrium properties of hydrogen-helium mixtures under conditions similar to the interior of giant gas planets are studied by means of first principle density functional molecular dynamics simulations. We investigate the molecular and…

Other Condensed Matter · Physics 2009-07-09 Jan Vorberger , I. Tamblyn , B. Militzer , S. A. Bonev

Using a simplified microstructural picture we show that interactions between thermosenstive microgel particles can be described by a polymer brush like corona decorating the dense core. The softness of the potential is set by the relative…

Soft Condensed Matter · Physics 2010-03-29 Frank Scheffold , Pedro Diaz-Leyva , Mathias Reufer , Nasser Ben Braham , Iseult Lynch , James L. Harden