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The temperature dependence of the phonon spectrum in the superconducting transition metal dichalcogenide 2H-NbS$_2$ is measured by diffuse and inelastic x-ray scattering. A deep, wide and strongly temperature dependent softening, of the two…

Interplay of superconductivity and density wave orders has been at the forefront of research of correlated electronic phases for a long time. 2H-NbSe$_2$ is considered to be a prototype system for studying this interplay, where the balance…

Strongly Correlated Electrons · Physics 2024-10-04 Asish K. Kundu , Anil Rajapitamahuni , Elio Vescovo , Ilya I. Klimovskikh , Helmuth Berger , Tonica Valla

We employ ab-initio electronic structure calculations to investigate the charge-density waves and periodic lattice distortions in bilayer 2H-NbSe$_2$. We demonstrate that the vertical stacking can give rise to a variety of patterns that may…

Strongly Correlated Electrons · Physics 2024-11-08 Fabrizio Cossu , Dhani Nafday , Krisztian Palotás , Mehdi Biderang , Heung-Sik Kim , Alireza Akbari , Igor Di Marco

Contradictory experiments have been reported about the dimensionality effect on the charge-density-wave transition in 2H NbSe$_2$. While scanning tunnelling experiments on single layers grown by molecular beam epitaxy measure a…

Mesoscale and Nanoscale Physics · Physics 2020-09-02 Raffaello Bianco , Lorenzo Monacelli , Matteo Calandra , Francesco Mauri , Ion Errea

In bulk samples and few layer flakes, the transition metal dichalcogenides NbS$_2$ and NbSe$_2$ assume the H polytype structure with trigonal prismatic coordination of the Nb atom. Recently, however, single and few layers of 1T-NbSe$_2$…

Strongly Correlated Electrons · Physics 2019-05-27 Cesare Tresca , Matteo Calandra

We investigate the charge density wave (CDW) instability in single and double layers, as well as in the bulk 2H-NbSe$_{2}$. We demonstrate that the density functional theory correctly describes the metallic CDW state in the bulk…

Materials Science · Physics 2015-05-14 Matteo Calandra , I. I. Mazin , Francesco Mauri

Competition between collective states like charge density wave and superconductivity is played out in some of the transition metal dichalcogenides unencumbered by the spin degrees of freedom. Although 2H-NbSe$_2$ has received much less…

Strongly Correlated Electrons · Physics 2015-04-21 S. Koley , N. Mohanta , A. Taraphder

We report on the epitaxial growth of single layer NbS$_2$ on Au(111) and determine both its crystalline and electronic structure by a combination of low-energy electron diffraction, scanning tunnelling microscopy and angle-resolved…

Using ab initio methods based on density functional theory, the electronic and magnetic structure of layered hexagonal NbSe$_{2}$ is studied. In the case of single-layer NbSe$_{2}$ it is found that, for all the functionals considered, the…

Materials Science · Physics 2020-05-14 Simon Divilov , Wen Wan , Paul Dreher , Miguel M. Ugeda , Félix Ynduráin

We employ {\it{ab-initio}} calculations to investigate the charge density waves in single-layer NbSe$_2$, and we explore how they are affected by transition metal atoms. Our calculations reproduce the observed orthorhombic phase in…

We develop in detail a model of the charge order in NbSe$_2$ deriving from a strong electron-phonon coupling dependent on the ingoing and outgoing electron momenta as well as the electronic orbitals scattered between. Including both…

Strongly Correlated Electrons · Physics 2018-08-07 Felix Flicker , Jasper van Wezel

We investigate electronic instabilities in 2H-TaS\textsubscript{2} and a self-intercalated variant, 2H$^\dagger$-Ta\textsubscript{1+$\delta$}S\textsubscript{2}. In conventional samples, which we determine to be slightly hole-doped, spectral…

VSe$_2$ is a layered compound that has attracted great attention due to its proximity to a ferromagnetic state that is quenched by the presence of a charge density wave (CDW) phase. In the monolayer limit, unrelated experiments have…

Materials Science · Physics 2023-04-18 Adolfo O. Fumega , Josu Diego , V. Pardo , S. Blanco-Canosa , Ion Errea

Charge-density-wave (CDW) instability and pressure-induced superconductivity in bulk 1T-NbS2 are predicted theoretically by first-principles calculations. We reveal a CDW instability towards the formation of a stable commensurate CDW order,…

Strongly Correlated Electrons · Physics 2020-10-20 Wei Wang , Bosen Wang , Zhibin Gao , Gang Tang , Wen Lei , Xiaojun Zheng , Huan Li , Xing Ming , Carmine Autieri

Two-dimensional (2D) atomic materials possess very different properties from their bulk counterparts. While changes in the single-particle electronic properties have been extensively investigated, modifications in the many-body collective…

Materials Science · Physics 2015-12-18 Xiaoxiang Xi , Liang Zhao , Zefang Wang , Helmuth Berger , László Forró , Jie Shan , Kin Fai Mak

Two-dimensional (2D) materials have become a fertile playground for the exploration and manipulation of novel collective electronic states. Recent experiments have unveiled a variety of robust 2D orders in highly-crystalline materials…

Recent STM experiments reveal niobium diselenide to support domains of striped (1Q) charge order side-by-side with its better-known triangular (3Q) phase, suggesting that small variations in local strain may induce a quantum phase…

Strongly Correlated Electrons · Physics 2015-11-18 Felix Flicker , Jasper van Wezel

Two-dimensional materials constitute a promising platform for developing nanoscale devices and systems. Their physical properties can be very different from those of the corresponding three-dimensional materials because of extreme quantum…

Mesoscale and Nanoscale Physics · Physics 2018-05-15 P. Chen , Woei Wu Pai , Y. -H. Chan , A. Takayama , C. -Z. Xu , A. Karn , S. Hasegawa , M. Y. Chou , S. -K. Mo , A. -V. Fedorov , T. -C. Chiang

Ultra-thin 2D materials have shown complete paradigm shift of understanding of physical and electronic properties because of confinement effects, symmetry breaking and novel phenomena at nanoscale. Bulk 2H-TaS2 undergoes an incommensurate…

Mesoscale and Nanoscale Physics · Physics 2023-07-18 Divya Rawat , Aksa Thomas , Ajay Soni

In this work we explore the phase diagram of the binary Nb-S system from ambient pressures up to 250 GPa using $ab$ $initio$ evolutionary crystal structure prediction. We find several new stable compositions and phases, especially in the…

Materials Science · Physics 2021-01-13 Roman Lucrezi , Christoph Heil
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