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Graphene-based electric power generation that converts mechanical energy of flow of ionic droplets over the device surface into electricity has emerged as promising candidate for a blue-energy network. Yet the lack of a microscopic…

Single nanopores have attracted much scientific interest due to their versatile applications. The majority of experiments have been performed with nanopores being in contact with the same electrolyte on both sides of the membrane, while…

Chemical Physics · Physics 2018-12-11 Yinghua Qiu , Zuzanna S. Siwy , Meni Wanunu

The rectification of electro-osmotic flows is important in micro/nano fluidics applications such as micro-pumps and energy conversion devices. Here, we propose a simple electro-osmotic diode in which colloidal particles are contained…

Mesoscale and Nanoscale Physics · Physics 2021-10-04 Shihori Koyama , Daisuke Inoue , Akihisa Okada , Hiroaki Yoshida

We show that sustainably harvesting 'blue' energy from the spontaneous mixing process of fresh and salty water can be boosted by varying the water temperature during a capacitive mixing process. Our modified Poisson-Boltzmann calculations…

Statistical Mechanics · Physics 2015-01-09 Mathijs Janssen , Andreas Härtel , René van Roij

Future generations of photoelectrodes for solar fuel generation must employ inexpensive, earth-abundant absorber materials in order to provide a large-scale source of clean energy. These materials tend to have poor electrical transport…

Materials Science · Physics 2011-08-17 I. Thomann , B. A. Pinaud , Z. Chen , B. M. Clemens , T. F. Jaramillo , Mark. L. Brongersma

Theoretical modeling of electroosmosis through conducting (ideally polarizable) nanochannels is reported. Based on the theory of induced charge electrokinetics, a novel nanofluidic system which possesses both adjustable ion selective…

Fluid Dynamics · Physics 2015-07-23 Cunlu Zhao , Chun Yang

Electroosmotic pumping of fluid through a nanopore that traverses an insulating membrane is considered. The density of surface charge on the membrane is assumed uniform, and sufficiently low for the Poisson-Boltzmann equation to be…

Fluid Dynamics · Physics 2014-05-15 M. Mao , J. D. Sherwood , S. Ghosal

In this paper we report the theory describing the electro-osmotic flow in charged nanopores with constant radius and charge density driven by alternating current. We solve the ion and solution transport in unsteady conditions as described…

Chemical Physics · Physics 2018-10-17 J. Catalano , P. M. Biesheuvel

Electrical conductivity is an inherent property of a hydrophobic porous media (HPM) and has critical applications. This research aims to provide a solution for predicting the electrical conductivity of nanoscale HPM with heterogeneous pore…

Soft Condensed Matter · Physics 2021-05-31 Zhongliang Chen , Xiaohu Dong , Zhangxin Chen , Marc-Olivier Coppens

Continuum simulation is employed to study ion transport and fluid flow through a nanopore in a solid-state membrane under an applied potential drop. Results show the existence of concentration polarization layers on the surfaces of the…

Fluid Dynamics · Physics 2015-06-16 Mao Mao , Sandip Ghosal , Guohui Hu

The design and development of inexpensive highly efficient electrocatalysts for hydrogen production, underpins several emerging clean-energy technologies. In this work, for the first time, molybdenum disulfide (MoS2) nanodots have been…

Materials Science · Physics 2015-07-02 John Benson , Meixian Li , Shuangbao Wang , Peng Wang , Pagona Papakonstantinou

The optimal functioning of nanopore-based biosensing tools necessitates rapid polymer capture from the ion reservoir. We identify an ionic correlation-induced transport mechanism that provides this condition without the chemical…

Soft Condensed Matter · Physics 2018-05-10 Sahin Buyukdagli

A huge amount of entropy is produced at places where fresh water and seawater mix, for example at river mouths. This mixing process is a potentially enormous source of sustainable energy, provided it is harnessed properly, for instance by a…

Statistical Mechanics · Physics 2015-05-20 N. Boon , R. van Roij

Electroosmotic flow (EOF) through nanoporous membranes has broad applications in micro- and nanofluidic systems, particularly in biomedical diagnostics and chemical analysis. The use of short nanopores enables high fluid flux, and the…

Chemical Physics · Physics 2025-12-08 Chao Zhang , Xiaomei Zhang , Hongwen Zhang , Zekun Gong , Xiuhua Ren , Mengnan Guo , Yinghua Qiu

Partitioning and transport of water and small solutes into and through nanopores is important to a variety of chemical and biological processes and applications. Here we study the partitioning of positive ions of increasing size into the…

Chemical Physics · Physics 2007-05-23 Lu Yang , Shekhar Garde

Understanding over-limiting current (faster than diffusion) is a long-standing challenge in electrochemistry with applications in desalination and energy storage. Known mechanisms involve either chemical or hydrodynamic instabilities in…

Chemical Physics · Physics 2017-06-27 Ji-Hyung Han , Edwin Khoo , Peng Bai , Martin Z. Bazant

Current approaches for electric power generation from nanoscale conducting or semi-conducting layers in contact with moving aqueous droplets are promising as they show efficiencies of around 30 percent, yet, even the most successful ones…

Traditionally, ion-selectivity in nanopores and nanoporous membranes is understood to be a consequence of Debye overlap, in which the Debye screening length is comparable to the nanopore radius somewhere along the length of the nanopore(s).…

Soft Condensed Matter · Physics 2020-08-05 Anthony R. Poggioli , Alessandro Siria , Lyderic Bocquet

Electric-field-driven electrolyte transport through nanoporous membranes is important for applications including osmotic power generation, sensing and iontronics. We derive an analytical equation in the Debye--H\"uckel regime and a…

Soft Condensed Matter · Physics 2026-05-01 Holly C. M. Baldock , David M. Huang

In this work, we develop an extended uniform potential (UP) model for a membrane nanopore by including two different charging mechanisms of the pore walls, namely by electronic charge and by chemical charge. These two charging mechanisms…

Chemical Physics · Physics 2019-12-25 L. Zhang , P. M. Biesheuvel , I. I. Ryzhkov