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The Kohn-Sham orbital kinetic energy density $\tau_\sigma(\vec{r}) = \sum_{i} w_{i\sigma} \big|\nabla \psi_{i\sigma}(\vec{r}) \big|^2$ is one fundamental quantity for constructing meta-generalized gradient approximations (meta-GGA) for use…

Materials Science · Physics 2015-06-23 Lin-Hui Ye

The modified Becke-Johnson meta-GGA potential of density functional theory has been shown to be the best exchange-correlation potential to determine band gaps of crystalline solids. However, it cannot be consistently used for the electronic…

Mesoscale and Nanoscale Physics · Physics 2020-04-02 Tomáš Rauch , Miguel A. L. Marques , Silvana Botti

We report a series of calculations testing the predictions of the Tran-Blaha functional for the electronic structure and magnetic properties of condensed systems. We find a general improvement in the properties of semiconducting and…

Materials Science · Physics 2010-11-08 David J. Singh

In this work we use density functional theory (DFT) to investigate the influence of semi-local exchange and correlation effects on the electronic and optical properties of zinc oxide. We find that the inclusion of such effects using the…

Materials Science · Physics 2019-05-01 R. M. V. S. Almeida , A. L. da Rosa , J. S. de Almeida

Mejia-Rodriguez and Trickey recently proposed a procedure for removing the explicit dependence of meta-GGA exchange-correlation energy functionals $E_{\rm xc}$ on the kinetic energy density $\tau$. We present a simple modification to this…

Materials Science · Physics 2024-04-22 Pietro Bonfà , Sangeeta Sharma , John Kay Dewhurst

We have investigated the electronic structures of various potentially half-metallic Heusler compounds with the Tran-Blaha modified Becke-Johnson (TB-mBJLDA) potential within the density functional theory. The half-metallic gaps are…

Materials Science · Physics 2013-05-30 Markus Meinert

The Becke-Johnson exchange potential [J. Chem. Phys. 124, 221101 (2006)] has been successfully used in electronic structure calculations within density-functional theory. However, in its original form the potential may dramatically fail in…

Materials Science · Physics 2010-01-28 E. Rasanen , S. Pittalis , C. Proetto

We test local and semi-local density functionals for the electronic exchange for a variety of systems including atoms, molecules, and atomic chains. In particular, we focus on a recent universal extension of the Becke-Johnson exchange…

Materials Science · Physics 2010-11-01 Micael J. T. Oliveira , Esa Räsänen , Stefano Pittalis , Miguel A. L. Marques

We investigate fundamental properties of meta-generalized-gradient approximations (meta-GGAs) to the exchange-correlation energy functional, which have an implicit density dependence via the Kohn-Sham kinetic-energy density. To this…

Chemical Physics · Physics 2014-12-10 F. G. Eich , Maria Hellgren

We present a plane-wave ultrasoft pseudopotential implementation of first-principle molecular dynamics, which is well suited to model large molecular systems containing transition metal centers. We describe an efficient strategy for…

Materials Science · Physics 2007-05-23 P. Giannozzi , F. De Angelis , R. Car

We report a series of electronic structure calculations for CrN using different exchange correlation potentials: PBE, LDA+$U$, the Tran-Blaha modified Becke-Johnson, and hybrid functionals. In every case, our calculations show that the…

Strongly Correlated Electrons · Physics 2012-06-21 A. S. Botana , F. Tran , V. Pardo , D. Baldomir , P. Blaha

The modified Becke-Johnson exchange potential combined with local-density approximation correlation (mBJLDA) has recently attracted interest because it provides highly improved band gaps at a very low computational cost. In this work we…

Materials Science · Physics 2022-04-04 Hazem Abu-Farsakh , Abdallah Qteish

We extend the Becke-Johnson approximation [J. Chem. Phys. 124, 221101 (2006)] of the exchange potential to two dimensions. We prove and demonstrate that a direct extension of the underlying formalism may lead to divergent behavior of the…

Strongly Correlated Electrons · Physics 2010-04-08 S. Pittalis , E. Rasanen , C. R. Proetto

An asymptotic corrected exchange hole potential analogous to Becke-Roussel [A. D. Becke and M. R. Roussel, Phys. Rev. A 39, 3761 (1989)] is constructed by modeling the exchange hole using the generalized coordinate transformation based on…

Materials Science · Physics 2017-07-05 Subrata Jana , Hemanadhan Myneni , Prasanjit Samal

We systematically investigate the topological band structures of half-Heusler compounds using first-principles calculations. The modified Becke-Johnson exchange potential together with local density approximation for the correlation…

Materials Science · Physics 2011-01-28 Wanxiang Feng , Di Xiao , Ying Zhang , Yugui Yao

The structural and electronic properties of new structural cubic (GaN)$_1$/(ZnO)$_1$ superlattice have been investigated using two different theoretical techniques: the full potential-linearized augmented plane wave (FP-LAPW) method and the…

Materials Science · Physics 2013-04-30 M. R. Boufatah , A. E. Merad

We develop numerical methods to calculate electron dynamics in crystalline solids in real-time time-dependent density functional theory employing exchange-correlation potentials which reproduce band gap energies of dielectrics; a meta…

Materials Science · Physics 2016-01-07 Shunsuke A. Sato , Yasutaka Taniguchi , Yasushi Shinohara , Kazuhiro Yabana

We investigate the electron-boson spectral density function, $I^2\chi(\omega,T)$, of CuO$_2$ plane in underdoped Bi$_2$Sr$_2$CaCu$_2$O$_{8+\delta}$ (Bi-2212) and underdoped YBa$_2$Cu$_3$O$_{6.50}$ (Y-123) using the Eliashberg formalism. We…

Superconductivity · Physics 2015-05-27 Jungseek Hwang

We analyze the methodology and the performance of subsystem density functional theory (DFT) with meta-generalized gradient approximation (meta-GGA) exchange-correlation functionals for non-bonded systems. Meta-GGA functionals depend on the…

Other Condensed Matter · Physics 2015-05-05 S. Śmiga , E. Fabiano , S. Laricchia , L. A. Constantin , F. Della Sala

The increasing use of high-throughput density-functional theory (DFT) calculations in the computational design and optimization of materials requires the availability of a comprehensive set of soft and transferable pseudopotentials. Here we…

Materials Science · Physics 2013-12-10 Kevin F. Garrity , Joseph W. Bennett , Karin M. Rabe , David Vanderbilt
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