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Methods to efficiently determine the relative stability of polymorphs of organic crystals are highly desired in crystal structure predictions (CSPs). Current methodologies include use of static lattice phonons, quasi-harmonic approximation…

Materials Science · Physics 2020-06-08 Nathan S. Abraham , Michael R. Shirts

We introduce a new framework for the low-energy nuclear structure calculations, which describes the single-particle wave function as a superposition of localized Gaussians. It is a hybrid of the Hartree-Fock and antisymmetrized molecular…

Nuclear Theory · Physics 2024-08-01 Masaaki Kimura , Yasutaka Taniguchi

Gaussian wavepackets are a popular tool for semiclassical analyses of classically chaotic systems. We demonstrate that they are extremely powerful in the semiquantal analysis of such systems, too, where their dynamics can be recast in an…

chao-dyn · Physics 2009-10-22 Arjendu K. Pattanayak , William C. Schieve

The GW approximation of many-body perturbation theory is an accurate method for computing electron addition and removal energies of molecules and solids. In a canonical implementation, however, its computational cost is $O(N^4)$ in the…

Chemical Physics · Physics 2021-04-21 Jan Wilhelm , Dorothea Golze , Leopold Talirz , Jürg Hutter , Carlo A. Pignedoli

Thermal broadening of the quasi-particle peak in the spectral function is an important physical feature in many statistical systems, but it is difficult to calculate. To tackle this problem, we propose the $H$-expanded basis within the…

Strongly Correlated Electrons · Physics 2025-02-21 Hu-Wei Jia , Wen-Jun Liu , Yue-Hong Wu , Kou-Han Ma , Lei Wang , Ning-Hua Tong

An analytical approximation for the eigenvalues of $\mathcal{PT}$ symmetric Hamiltonian $\mathsf{H} = -d^{2}/dx^{2} - (\mathrm{i}x)^{\epsilon+2}$, $\epsilon > -1$ is developed via simple basis sets of harmonic-oscillator wave functions with…

Quantum Physics · Physics 2017-11-08 O. D. Skoromnik , I. D. Feranchuk

At high temperature the infrared modes of a weakly coupled quantum field theory can be treated nonperturbatively in real time using the classical field approximation. We use this to introduce a nonperturbative approach to the calculation of…

High Energy Physics - Phenomenology · Physics 2009-11-07 Gert Aarts

We study different quantum one dimensional systems with noncanonical commutation rule $[x,p]=i\hbar (1+sH),$ where $H$ is the one particle Hamiltonian and $s$ is a parameter. This is carried-out using semiclassical arguments and the surmise…

Quantum Physics · Physics 2007-05-23 J. C. Flores , S. Montecinos

We present an approximation scheme for the calculation of the principal excitation energies and transition moments of finite many-body systems. The scheme is derived from a first order approximation to the self energy of a recently proposed…

Chemical Physics · Physics 2009-10-30 Joachim Brand , Lorenz S. Cederbaum

Accurately simulating the atmospheric turbulence behaviour is always challenging. The well-known FFT based method falls short in correctly predicting both the low and high frequency behaviours. Sub-harmonic compensation aids in…

Instrumentation and Methods for Astrophysics · Physics 2022-08-15 Sorabh Chhabra , Jyotirmay Paul , A. N. Ramaprakash , Avinash Surendran

Semiclassical quantization is exact only for the so called \emph{solvable} potentials, such as the harmonic oscillator. In the \emph{nonsolvable} case the semiclassical phase, given by a series in $\hbar$, yields more or less approximate…

Quantum Physics · Physics 2007-05-23 A. Matzkin

Bifurcations of classical orbits introduce divergences into semiclassical spectra which have to be smoothed with the help of uniform approximations. We develop a technique to extract individual energy levels from semiclassical spectra…

Chaotic Dynamics · Physics 2009-11-07 T. Bartsch , J. Main , G. Wunner

We analyze quantitatively the accuracy of eigenfunction and eigenvalue calculations in the frame work of WKB and instanton semiclassical methods. We show that to estimate the accuracy it is enough to compare two linearly independent (with…

Other Condensed Matter · Physics 2007-05-23 V. A. Benderskii , E. V. Vetoshkin , E. I. Kats

Using quasi-Newton methods in stochastic optimization is not a trivial task given the difficulty of extracting curvature information from the noisy gradients. Moreover, pre-conditioning noisy gradient observations tend to amplify the noise.…

Optimization and Control · Mathematics 2024-04-02 Andre Carlon , Luis Espath , Raul Tempone

The calculation of minimum energy paths for transitions such as atomic and/or spin re-arrangements is an important task in many contexts and can often be used to determine the mechanism and rate of transitions. An important challenge is to…

Chemical Physics · Physics 2017-03-31 Olli-Pekka Koistinen , Emile Maras , Aki Vehtari , Hannes Jónsson

The frozen Gaussian approximation, proposed in [Lu and Yang, [15]], is an efficient computational tool for high frequency wave propagation. We continue in this paper the development of frozen Gaussian approximation. The frozen Gaussian…

Numerical Analysis · Mathematics 2011-08-01 Jianfeng Lu , Xu Yang

This work brings together two powerful concepts in Gaussian processes: the variational approach to sparse approximation and the spectral representation of Gaussian processes. This gives rise to an approximation that inherits the benefits of…

Machine Learning · Statistics 2017-11-09 James Hensman , Nicolas Durrande , Arno Solin

Inspired by the quantum computing algorithms for Linear Algebra problems [HHL,TaShma] we study how the simulation on a classical computer of this type of "Phase Estimation algorithms" performs when we apply it to solve the Eigen-Problem of…

Data Structures and Algorithms · Computer Science 2017-04-07 Michael Ben-Or , Lior Eldar

The frozen Gaussian approximation provides a highly efficient computational method for high frequency wave propagation. The derivation of the method is based on asymptotic analysis. In this paper, for general linear strictly hyperbolic…

Numerical Analysis · Mathematics 2010-12-23 Jianfeng Lu , Xu Yang

We present a new approximation technique for quantum field theory. The standard one-loop result is used as a seed for a recursive formula that gives a sequence of improved Gaussian approximations for the generating functional. In a…

High Energy Physics - Theory · Physics 2011-08-08 Antun Balaz , Aleksandar Belic , Aleksandar Bogojevic