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Thermal management is extremely important for designing high-performance devices. The lattice thermal conductivity of materials is strongly dependent on the structural defects at different length scales, particularly point defects like…

Materials Science · Physics 2021-02-24 Yandong Sun , Yanguang Zhou , Ming Hu , G. Jeffrey Snyder , Ben Xu , Wei Liu

Strain engineering is critical to the performance enhancement of electronic and thermoelectric devices because of its influence on the material thermal conductivity. However, current experiments cannot probe the detailed physics of the…

Materials Science · Physics 2021-01-27 Yandong Sun , Yanguang Zhou , Ramya Gurunathan , Jin-Yu Zhang , Ming Hu , Wei Liu , Ben Xu , G. Jeffrey Snyder

The major obstacle in the design of materials with low lattice thermal conductivity is the difficulty in efficiently scattering phonons across the entire frequency spectrum. Using first principles calculations, we show that driving PbTe…

Materials Science · Physics 2019-03-26 Ronan M. Murphy , Éamonn D. Murray , Stephen Fahy , Ivana Savić

Understanding the microscopic processes affecting the bulk thermal conductivity is crucial to develop more efficient thermoelectric materials. PbTe is currently one of the leading thermoelectric materials, largely thanks to its low thermal…

Materials Science · Physics 2011-06-07 O. Delaire , J. Ma , K. Marty , A. F. May , M. A. McGuire , M. -H. Du , D. J. Singh , A. Podlesnyak , G. Ehlers , M. Lumsden , B. C. Sales

We present an \emph{ab-initio} study that identifies the main electron-phonon scattering channels in $n$-type PbTe. We develop an electronic transport model based on the Boltzmann transport equation within the transport relaxation time…

Mesoscale and Nanoscale Physics · Physics 2018-11-14 Jiang Cao , Jose D. Querales-Flores , Aoife R. Murphy , Stephen Fahy , Ivana Savić

First-principles calculations of thermal transport in homogeneous materials have reached remarkable predicting power. Modeling deterministically phonon transport in nanostructures, however, poses novel challenges; notably, it entails…

Materials Science · Physics 2021-06-08 Giuseppe Romano

We report first principles calculations of the phonon dispersions of PbTe both for its observed structure and under compression. At the experimental lattice parameter we find a near instability of the optic branch at the zone center, in…

Materials Science · Physics 2008-10-27 Jiming An , Alaska Subedi , David J. Singh

Nanoscale defects such as dislocations, have a significant impact on the phonon thermal transport properties in non-metallic materials. To unravel these effects, understanding of defect phonon modes is essential. Herein, at the atomic…

Nanostructured semiconducting materials are promising candidates for thermoelectrics due to their potential to suppress phonon transport while preserving electrical properties. Modeling phonon-boundary scattering in complex geometries is…

Materials Science · Physics 2017-10-02 Giuseppe Romano , Alexie M. Kolpak

The relaxation of a spatially sinusoidal temperature perturbation in a dielectric crystal at a temperature comparable to or higher than the Debye temperature is investigated theoretically. We assume that most phonons contributing to the…

Materials Science · Physics 2011-12-12 A. A. Maznev , Jeremy A. Johnson , Keith A. Nelson

In this study, we systematically investigate the thermal and electronic transport properties of two-dimensional PbSe/PbTe monolayer heterostructure by combining first-principles calculations, Boltzmann transport theory, and machine learning…

Materials Science · Physics 2026-02-27 Ruihao Tan , Kaiwang Zhang , Yue-Wen Fang

We report finite-volume simulations of the phonon Boltzmann transport equation (BTE) for heat conduction across the heterogeneous interfaces in SiGe superlattices. The diffuse mismatch model incorporating phonon dispersion and polarization…

Mesoscale and Nanoscale Physics · Physics 2010-05-17 Dhruv Singh , Jayathi Y. Murthy , Timothy S. Fisher

We develop a computational framework, based on the Boltzmann transport equation, with the ability to compute the thermal transport in nanostructured materials of any geometry using as the only input the bulk thermal conductivity…

Mesoscale and Nanoscale Physics · Physics 2014-10-20 Giuseppe Romano , Jeffrey C. Grossman

Prior experimental studies showed that nanowires are promising structures for improving the thermoelectric performance of practical thermoelectric materials due to the strongly induced phonon-boundary scattering. However, few studies…

Mesoscale and Nanoscale Physics · Physics 2017-09-13 Lei Ma , Riguo Mei , Mengmeng Liu , Xuxin Zhao , Qixing Wu , Hongyuan Sun

IV-VI materials are some of the most efficient bulk thermoelectric materials due to their proximity to soft-mode phase transitions, which leads to low lattice thermal conductivity. It has been shown that the lattice thermal conductivity of…

Materials Science · Physics 2021-07-21 Jiang Cao , Đorđe Dangić , José D. Querales-Flores , Stephen Fahy , Ivana Savić

The electronic, phonon and thermoelectric transport properties of (PbTe)2 layer are systematically investigated by using first-principles pseudopotential method and Boltzmann transport equation. Our calculations demonstrate that there is a…

Materials Science · Physics 2020-03-04 Caiyu Sheng , Dengdong Fan , Huijun Liu

We present a detailed study of the charge transport, optical reflectivity, and thermal transport properties of n-type PbSe crystals. A strong scattering, mobility-limiting mechanism was revealed to be at play at temperatures above 500 K.…

The phonon Boltzmann transport equation (BTE) is a powerful tool for studying non-diffusive thermal transport. Here, we develop a new universal variational approach to solving the BTE that enables extraction of phonon mean free path (MFP)…

Mesoscale and Nanoscale Physics · Physics 2016-04-13 Vazrik Chiloyan , Lingping Zeng , Samuel Huberman , Alexei A. Maznev , Keith A. Nelson , Gang Chen

Phonon size effects induce ballistic transport in nanomaterials, challenging Fourier's law. Nondiffusive heat transport is captured by the Peierls-Boltzmann transport equation (BTE), commonly solved under the relaxation time approximation…

Mesoscale and Nanoscale Physics · Physics 2020-03-10 Giuseppe Romano

PbTe crystals have a soft transverse optical phonon mode in the terahertz frequency range, which is known to efficiently decay into heat-carrying acoustic phonons, resulting in anomalously low thermal conductivity. Here, we studied this…

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