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In this paper we study the problem of the global existence (in time) of weak, entropic solutions to a system of three hyperbolic conservation laws, in one space dimension, for large initial data. The system models the dynamics of phase…

Analysis of PDEs · Mathematics 2015-09-10 Debora Amadori , Paolo Baiti , Andrea Corli , Edda Dal Santo

The theory of entropy production in nonequilibrium, Hamiltonian systems, previously described for steady states using partitions of phase space, is here extended to time dependent systems relaxing to equilibrium. We illustrate the main…

Chaotic Dynamics · Physics 2009-10-31 T. Gilbert , J. R. Dorfman , P. Gaspard

Multicomponent phase separation is a routine occurrence in both living and synthetic systems. Thermodynamics provides a straightforward path to determine the phase boundaries that characterize these transitions for systems at equilibrium.…

Statistical Mechanics · Physics 2025-12-08 Yu-Jen Chiu , Daniel Evans , Ahmad K. Omar

The limit of small entropy production is reached in relaxing systems long after preparation, and in stationary driven systems in the limit of small driving power. Surprisingly, for extended systems this limit is not in general the…

Condensed Matter · Physics 2009-10-31 Leticia F. Cugliandolo , Jorge Kurchan

Differences in activities in colloidal particles are sufficient to drive phase separation between active and passive (or less active) particles, even if they have only excluded volume interactions. In this paper, we study the phase…

Soft Condensed Matter · Physics 2020-05-27 Efe Ilker , Jean-François Joanny

Nonequilibrium phase transitions are routinely observed in both natural and synthetic systems. The ubiquity of these transitions highlights the conspicuous absence of a general theory of phase coexistence that is broadly applicable to both…

Statistical Mechanics · Physics 2023-05-30 Ahmad K. Omar , Hyeongjoo Row , Stewart A. Mallory , John F. Brady

A non-isothermal phase field model that captures both displacive and diffusive phase transformations in a unified framework is presented. The model is developed in a formal thermodynamic setting, which provides guidance on admissible…

Materials Science · Physics 2011-12-02 Mirko Maraldi , Garth N. Wells , Luisa Molari

We distinguish a mechanical representation of the world in terms of point masses with positions and momenta and the chemical representation of the world in terms of populations of different individuals, each with intrinsic stochasticity,…

Statistical Mechanics · Physics 2019-05-07 Hong Qian

In the present paper we consider a partial differential system describing a phase-field model with temperature dependent constraint for the order parameter. The system consists of an energy balance equation with a fairly general nonlinear…

Analysis of PDEs · Mathematics 2021-10-01 Chen Bin , Sergey A. Timoshin

The stochastic entropy generated during the evolution of a system interacting with an environment may be separated into three components, but only two of these have a non-negative mean. The third component of entropy production is…

Statistical Mechanics · Physics 2013-05-30 Ian J. Ford , Richard E. Spinney

In this work, with the help of fractional calculus, it is shown a time dependence of entropy more general than the well known Pesin relation is derived. Here the equiprobability postulate is not assumed, the system dynamic in the phase…

Statistical Mechanics · Physics 2021-05-07 O. Sotolongo-Costa , I. Rodríguez-Vargas

Investigation of simple far-from-equilibrium systems exhibiting phase separation leads to the conclusion that phase coexistence is not well defined in this context. This is because the properties of the coexisting nonequilibrium systems…

Statistical Mechanics · Physics 2016-02-11 Ronald Dickman

This paper is concerned with a non-isothermal Cahn-Hilliard model based on a microforce balance. The model was derived by A. Miranville and G. Schimperna starting from the two fundamental laws of Thermodynamics, following M. Gurtin's…

Analysis of PDEs · Mathematics 2020-04-07 Alice Marveggio , Giulio Schimperna

The dynamics of multicomponent gas mixtures with vanishing barycentric velocity is described by Maxwell-Stefan equations with mass diffusion and heat conduction. The equations consist of the mass and energy balances, coupled to an algebraic…

Analysis of PDEs · Mathematics 2023-04-03 Stefanos Georgiadis , Ansgar Jüngel

Here we study a nonlinear thermoelasticity hyperbolic-parabolic system describing the balance of momentum and internal energy of a heat-conducting elastic body, preserving the positivity of temperature. So far, no global existence results…

Analysis of PDEs · Mathematics 2023-12-20 Tomasz Cieślak , Boris Muha , Srđan Trifunović

We consider a diffuse interface model that describes the macro- and micro-phase separation processes of a polymer mixture. The resulting system consists of a Cahn-Hilliard equation and a Cahn-Hilliard-Oono type equation endowed with the…

Analysis of PDEs · Mathematics 2024-05-01 Bohan Ouyang

We consider a differential model describing nonisothermal fast phase separation processes taking place in a three-dimensional bounded domain. This model consists of a viscous Cahn-Hilliard equation characterized by the presence of an…

Analysis of PDEs · Mathematics 2007-05-23 Maurizio Grasselli , Hana Petzeltova , Giulio Schimperna

We consider a class of Cahn-Hilliard equation that models phase separation process of binary mixtures involving nontrivial boundary interactions in a bounded domain with non-permeable wall. The system is characterized by certain dynamic…

Analysis of PDEs · Mathematics 2023-07-28 Takeshi Fukao , Hao Wu

The most complicated phenomena of equilibrium statistics, phase separations and transitions of various order and critical phenomena, can clearly and sharply be seen even for small systems in the topology of the curvature of the…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

This paper presents a thermodynamically consistent model for multicomponent electrolyte solutions. The first part of this paper derives the general governing equations for nonequilibrium systems within the theory of nonequilibrium…

Analysis of PDEs · Mathematics 2016-05-25 Matthias Herz , Peter Knabner