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We investigate the fine and spin structure of ultralong-range Rydberg molecules exposed to a homogeneous magnetic field. Each molecule consists of a $^{87}$Rb Rydberg atom whose outer electron interacts via spin-dependent $s$- and p-wave…

Atomic Physics · Physics 2018-05-02 Frederic Hummel , Christian Fey , Peter Schmelcher

The interaction between a Rydberg electron and a neutral atom situated inside its extended orbit is described via contact interactions for each atom-electron scattering channel. In ultracold environments, these interactions lead to…

Atomic Physics · Physics 2017-05-10 Matthew T Eiles , Chris H Greene

The level structure of negative-ions near the electron detachment limit dictates the low-energy scattering of an electron with the parent neutral atom. We demonstrate that a single ultracold atom bound inside a Rydberg orbit forming an…

We calculate vibrational spectra of ultralong-range Cs(32p) Rydberg molecules which form in an ultracold gas of Cs atoms. We account for the partial-wave scattering of the Rydberg electrons from the ground Cs perturber atoms by including…

We unravel some peculiar properties of ultralong-range Rydberg molecules formed by an $s$-state $^{87}$Rb Rydberg atom and a corresponding ground-state atom whose electronic orbitals are spherically symmetric and therefore should not be…

Atomic Physics · Physics 2019-02-06 Frederic Hummel , Christian Fey , Peter Schmelcher

We have performed high resolution photoassociation spectroscopy of rubidium ultra long-range Rydberg molecules in the vicinity of the 25$P$ state. Due to the hyperfine interaction in the ground state perturber atom, the emerging mixed…

Atomic Physics · Physics 2017-08-24 Thomas Niederprüm , Oliver Thomas , Tanita Eichert , Herwig Ott

We present high-resolution spectroscopy of Rb$_\text{2}$ ultralong-range Rydberg molecules bound by mixed singlet-triplet electron-neutral atom scattering. The mixing of the scattering channels is a consequence of the hyperfine interaction…

We observe long-range $^{85}$Rb and $^{87}$Rb (24$D$+5$S_{1/2}$) Rydberg molecules for eight different spin couplings, with binding energies up to 440~MHz and sub-percent relative uncertainty. Isotopic effects of the molecular binding…

Atomic Physics · Physics 2020-01-15 Jamie L. MacLennan , Yun-Jhih Chen , Georg Raithel

Scattering of electrons from chiral spin textures such as the skyrmions is an emerging research area due to its richness in topological quantum transport, which is significant for spintronic devices. We study the dynamical process of…

Mesoscale and Nanoscale Physics · Physics 2026-03-03 Hareram Swain , Arijit Mandal , S. Satpathy , B. R. K. Nanda

We observe the formation of long-range Cs$_2$ Rydberg molecules consisting of a Rydberg and a ground-state atom by photoassociation spectroscopy in an ultracold Cs gas near 6s$_{1/2}$($F$=3,4)$\rightarrow$np$_{3/2}$ resonances (n=26-34).…

Atomic Physics · Physics 2015-06-23 Heiner Saßmannshausen , Frédéric Merkt , Johannes Deiglmayr

We report the observation of spin-singlet ultra-long range Rydberg butterfly molecules consisting of a ground-state atom bound to a Rydberg atom by $P$-wave scattering of $^{87}$Rb Rydberg electrons from $^{87}$Rb(5s) atoms. A three-photon…

Rydberg atoms in optical lattices and tweezers is now a well established platform for simulating quantum spin systems. However, the role of the atoms' spatial wavefunction has not been examined in detail experimentally. Here, we show a…

Optically trapped Rydberg atoms are a suitable platform to explore quantum many-body physics mediated by long-range atom--atom interactions that can be engineered through externally applied light fields. However, this approach is limited to…

We review ultralong-range Rydberg molecules (ULRM), which are bound states between a Rydberg atom and one or more ground-state atoms with bond lengths on the order of thousands of Bohr radii. The binding originates from multiple…

Atomic Physics · Physics 2020-03-18 Christian Fey , Frederic Hummel , Peter Schmelcher

We propose a novel experimental method to extend the investigation of ion-atom collisions from the so far studied cold, essentially classical regime to the ultracold, quantum regime. Key aspect of this method is the use of Rydberg molecules…

Atomic Physics · Physics 2018-04-18 T. Schmid , C. Veit , N. Zuber , R. Löw , T. Pfau , M. Tarana , M. Tomza

The properties and behaviour of a Ring Rydberg Composite are explicated. This system consists of a ring of ground state atoms centered on a Rydberg atom, whose electron elastically scatters off the ground state atoms. We transform the…

Atomic Physics · Physics 2020-02-19 Matthew T. Eiles , Andrew L. Hunter , Jan M. Rost

A fascinating aspect of Rydberg atoms is their ability to form huge but very weakly bound molecules with a ground state atom, only held together by a scattering process between the latter and the Rydberg electron. Beyond the usual way of…

Atomic Physics · Physics 2012-07-31 Andrej Junginger , Jörg Main , Günter Wunner

We quantify the effect of the spin-orbit interaction on the Rydberg-like series of image state electrons at the (111) and (001) surface of Ir, Pt and Au. Using relativistic multiple-scattering methods we find Rashba-like dispersions with…

Materials Science · Physics 2007-05-23 J R McLaughlan , E M Llewellyn-Samuel , S Crampin

Ultralong-range Rydberg molecules, composed of an excited Rydberg atom and a ground-state atom, are characterized by large bond lengths, dipole moments, sensitivity to external fields, and an unusual binding mechanism based on low-energy…

Atomic Physics · Physics 2025-05-13 Agata Wojciechowska , Michał Tomza , Matthew T. Eiles

Nature creates electrons with two values of the spin projection quantum number. In certain applications, it is important to filter electrons with one spin projection from the rest. Such filtering is not trivial, since spin-dependent…

Mesoscale and Nanoscale Physics · Physics 2020-10-13 Areg Ghazaryan , Mikhail Lemeshko , Artem G. Volosniev
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