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We analytically tackle opto-vibronic interactions in molecular systems driven by either classical or quantum light fields. In particular, we examine a simple model of molecules with two relevant electronic levels, characterized by potential…

Quantum Physics · Physics 2024-02-28 Q. Zhang , M. Asjad , M. Reitz , C. Sommer , B. Gurlek , C. Genes

We study nonlinear interactions in a strongly driven optomechanical cavity, in regimes where the interactions give rise to resonant scattering between optomechanical polaritons and are thus strongly enhanced. We use a Keldysh formulation…

Quantum Physics · Physics 2015-06-30 Marc-Antoine Lemonde , Aashish A. Clerk

Nonlinear optical effects provide a natural way of light manipulation and interaction, and form the foundation of applied photonics -- from high-speed signal processing and telecommunication, to ultra-high bandwidth interconnects and…

Optics · Physics 2017-05-30 Andrei Rogov , Evgenii Narimanov

Nonlinear optical phenomena are generally governed by geometry in matter systems, as they depend on the spatial arrangement of atoms within materials or molecules. Metasurfaces, through precisely designed geometries on a subwavelength…

Strong coupling between various kinds of material excitations and optical modes has recently shown potential to modify chemical reaction rates in both excited and ground states. The ground-state modification in chemical reaction rates has…

A theoretical framework is presented for the computation of rovibrational polaritonic states of a molecule in a lossless infrared (IR) microcavity. In the proposed approach the quantum treatment of the rotational and vibrational motion of…

Chemical Physics · Physics 2023-10-30 Tamás Szidarovszky

The realization of exciton-polaritons -- hybrid excitations of semiconductor quantum well excitons and cavity photons -- has been of great technological and scientific significance. In particular, the short-range collisional interaction…

Quantum Gases · Physics 2018-07-17 Valentin Walther , Robert Johne , Thomas Pohl

Chemical reactions and energy transport phenomena have been experimentally reported to be significantly affected by strong light-matter interactions and vibrational polariton formation. These quasiparticles exhibit nontrivial transport…

Chemical Physics · Physics 2023-07-21 Enes Suyabatmaz , Raphael F. Ribeiro

The interaction of quantum light with matter like that inside a cavity is known to give rise to mixed light-matter states called polaritons. We discuss the impact of rotation of the cavity on the polaritons. It is shown that the number of…

Quantum Physics · Physics 2021-03-04 Lorenz S. Cederbaum

Gas-phase molecules are a promising platform through which to elucidate the mechanisms of action and scope of polaritons for optical control of chemistry. Polaritons arise from the strong coupling of a dipole-allowed molecular transition…

Chemical Physics · Physics 2024-08-20 Jane C. Nelson , Marissa L. Weichman

We derive the transition rates, dephasing rates, and Lamb shifts for a system consisting of many molecules collectively coupled to a resonant cavity mode. Using a variational polaron master equation, we show that strong vibrational…

Quantum Physics · Physics 2024-07-24 Dominic M Rouse , Erik M Gauger , Brendon W Lovett

Polaritonic chemistry offers the possibility of modifying molecular properties and even influencing chemical reactivity through strong coupling between vibrational transitions and confined light modes in optical cavities. Despite…

Chemical Physics · Physics 2025-05-16 Thomas Schnappinger , Markus Kowalewski

Nonlinear processes lie at the heart of many technologies such as frequency converters and entangled photon sources. Historically, observation and manipulation of these processes, for instance through nanostructures, has been limited to…

The future fibre optic communications network will rely on photons as carriers of information, which may be stored in intensity, polarization or phase of light. However, processing of such optical information usually relies on electronics.…

Recent experiments have observed that the chemical and photophysical properties of molecules can be modified inside an optical Fabry-Perot microcavity under collective vibrational strong coupling (VSC) conditions, and such modification is…

Mesoscale and Nanoscale Physics · Physics 2021-03-09 Tao E. Li , Abraham Nitzan , Joseph E. Subotnik

Manipulating intensity, phase and polarization of the electromagnetic fields on ultrafast timescales is essential for all-optical switching, optical information processing and development of novel time-variant media. Noble metal based…

Optics · Physics 2024-11-26 Jingyi Wu , Anton Yu. Bykov , Anastasiia Zaleska , Anatoly V. Zayats

Controlling light polarization is one of the most essential routines in modern optical technology. Since the demonstration of optical pulse shaping by spatial light modulators and its potential in controlling the quantum reaction pathways,…

Coherent light-matter interactions have recently extended their applications to the ultrafast control of magnetization in solids. An important but unrealized technique is the manipulation of magnetization vector motion to make it follow an…

Light is extensively used to steer the motion of atoms in free space, enabling cooling and trapping of matter waves through ponderomotive forces and Doppler-mediated photon scattering. Likewise, light interaction with free electrons has…

Light-matter interaction not only plays an instrumental role in characterizing materials' properties via various spectroscopic techniques but also provides a general strategy to manipulate material properties via the design of novel…

Chemical Physics · Physics 2023-08-30 Braden M. Weight , Xinyang Li , Yu Zhang