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Identifying heterogeneous structures in glasses --- such as localized soft spots --- and understanding structure-dynamics relations in these systems remain major scientific challenges. Here we derive an exact expression for the local…

Soft Condensed Matter · Physics 2017-08-16 Jacques Zylberg , Edan Lerner , Yohai Bar-Sinai , Eran Bouchbinder

Here we introduce a variation of the trap model of glasses based on softness, a local structural variable identified by machine learning, in supercooled liquids. Softness is a particle-based quantity that reflects the local structural…

Soft Condensed Matter · Physics 2024-03-29 Sean A. Ridout , Indrajit Tah , Andrea J. Liu

Data-driven approaches to inferring the local structures responsible for plasticity in amorphous materials have made substantial contributions to our understanding of the failure, flow, and rearrangement dynamics of supercooled fluids. Some…

Soft Condensed Matter · Physics 2023-08-22 Tomilola M. Obadiya , Daniel M. Sussman

We image local structural rearrangements in soft colloidal glasses under small periodic perturbations induced by thermal cycling. Local structural entropy $S_{2}$ positively correlates with observed rearrangements in colloidal glasses. The…

Soft Condensed Matter · Physics 2016-06-13 Xiunan Yang , Rui Liu , Mingcheng Yang , Wei-Hua Wang , Ke Chen

By considering the low-frequency vibrational modes of amorphous solids, Manning and Liu [Phys. Rev. Lett. 107, 108302 (2011)] showed that a population of "soft spots" can be identified that are intimately related to plasticity at zero…

Soft Condensed Matter · Physics 2014-04-08 Samuel S. Schoenholz , Andrea J. Liu , Robert A. Riggleman , Joerg Rottler

Experimentally resolving atomic-scale structural changes of a deformed glass remains challenging owing to the disordered nature of glass structure. Here, we show that the structural anisotropy emerges as a general hallmark for different…

The dynamical glass transition is typically taken to be the temperature at which a glassy liquid is no longer able to equilibrate on experimental timescales. Consequently, the physical properties of these systems just above or below the…

Soft Condensed Matter · Physics 2017-03-08 Samuel S. Schoenholz , Ekin D. Cubuk , Efthimios Kaxiras , Andrea J. Liu

Machine learning techniques have been used to quantify the relationship between local structural features and variations in local dynamical activity in disordered glass-forming materials. To date these methods have been applied to an array…

Soft Condensed Matter · Physics 2021-01-07 Indrajit Tah , Tristan A. Sharp , Andrea J. Liu , Daniel M. Sussman

We examine the structural relaxation of glassy materials at finite temperatures, considering the effect of activated rearrangements and long-range elastic interactions. Our three-dimensional mesoscopic relaxation model shows how the…

Soft Condensed Matter · Physics 2023-12-20 Gieberth Rodriguez-Lopez , Kirsten Martens , Ezequiel E. Ferrero

It has been a long-standing materials science challenge to establish structure-property relations in amorphous solids. Here we introduce a rotation-variant local structure representation that enables different predictions for different…

Materials Science · Physics 2022-03-15 Zhao Fan , Evan Ma

The plasticity of amorphous solids undergoing shear is characterized by quasi-localized rearrangements of particles. While many models of plasticity exist, the precise relationship between plastic dynamics and the structure of a particle's…

Soft Condensed Matter · Physics 2024-06-12 Jason W. Rocks , Sean A. Ridout , Andrea J. Liu

We explore the relationship between a machine-learned structural quantity (softness) and excess entropy in simulations of supercooled liquids. Excess entropy is known to scale well the dynamical properties of liquids, but this…

Soft Condensed Matter · Physics 2023-06-07 Ian R. Graham , Paulo E. Arratia , Robert A. Riggleman

We calculated a four-point correlation function G_4(k,r;t) and the corresponding structure factor S_4(k,q;t) for a model glass-forming binary mixture. These functions measure the spatial correlations of the relaxation of different…

Statistical Mechanics · Physics 2015-06-25 Elijah Flenner , Grzegorz Szamel

The hardness of materials plays an important role in material design. There are numerous experimental methods to measure the hardness of materials, but theoretical prediction of hardness is challenging. By investigating the correlation…

Materials Science · Physics 2024-12-24 Faridun N. Jalolov , Alexander G. Kvashnin

Amorphous solids lack long-range order. Therefore identifying structural defects -- akin to dislocations in crystalline solids -- that carry plastic flow in these systems remains a daunting challenge. By comparing many different structural…

Amorphous silica density at ambient pressure is known to depend on thermal history (through the quenching rate) but also, at room temperature, on the maximum pressure applied in the past. Here we show that beyond density, a mechanical…

Other Condensed Matter · Physics 2009-05-15 Cindy Linn Rountree , Damien Vandembroucq , Mehdi Talamali , Elisabeth Bouchaud , Stéphane Roux

We study theoretically and numerically a family of multi-point dynamic susceptibilities that quantify the strength and characteristic lengthscales of dynamic heterogeneities in glass-forming materials. We use general theoretical arguments…

In amorphous solids subject to shear or thermal excitation, so-called structural indicators have been developed that predict locations of future plasticity or particle rearrangements. An open question is whether similar tools can be used in…

Soft Condensed Matter · Physics 2022-01-31 Julia A. Giannini , Ethan M. Stanifer , M. Lisa Manning

Dynamical four-point susceptibilities measure the extent of spatial correlations in the dynamics of glass forming systems. We show how these susceptibilities depend on the length scales that necessarily form part of their definition. The…

Statistical Mechanics · Physics 2007-05-23 David Chandler , Juan P. Garrahan , Robert L. Jack , Lutz Maibaum , Albert C. Pan

We connect the configurational entropy of a liquid to the geometrical properties of its local energy landscape, using a high-temperature expansion. It is proposed that correlations between local structures arises from their overlap and,…

Soft Condensed Matter · Physics 2016-08-24 Pierre Ronceray , Peter Harrowell
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