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Constructing atom-resolved states from low-resolution data is of practical importance in many areas of science and engineering. This problem is addressed in this paper in the context of multiscale factorization methods for molecular…

Computational Physics · Physics 2016-04-14 Andrew Abi Mansour , Peter J. Ortoleva

In this paper we propose a model for open Markov chains that can be interpreted as a system of non-interacting particles evolving according to the rules of a Markov chain. The number of particles in the system is not constant, because we…

Probability · Mathematics 2019-01-23 R. Salgado-Garcia

The quantum master equation obtained from two different thermodynamic arguments is seriously nonlinear. We argue that, for quantum systems, nonlinearity occurs naturally in the step from reversible to irreversible equations and we analyze…

Quantum Physics · Physics 2018-03-09 Hans Christian Öttinger

We consider filtering for a hidden Markov model that evolves with multiple time scales in the hidden states. In particular, we consider the case where one of the states is a scaled Ornstein-Uhlenbeck process with fast reversion to a…

Probability · Mathematics 2012-10-15 Andrew Papanicolaou

We extend ring-polymer molecular dynamics (RPMD) to allow for the direct simulation of general, electronically non-adiabatic chemical processes. The kinetically constrained (KC) RPMD method uses the imaginary-time path-integral…

Statistical Mechanics · Physics 2014-03-05 Artur R. Menzeleev , Franziska Bell , Thomas F. Miller

The aims of this paper are to propose, construct and analyse microscopic kinetic models for the emergence of long chains of RNA from monomeric beta-D-ribonucleotide precursors in prebiotic circumstances. Our theory starts out from similar…

adap-org · Physics 2007-05-23 Jonathan A. D. Wattis , Peter V. Coveney

The adoption of detailed mechanisms for chemical kinetics often poses two types of severe challenges: First, the number of degrees of freedom is large; and second, the dynamics is characterized by widely disparate time scales. As a result,…

Dynamical Systems · Mathematics 2025-10-01 Eliodoro Chiavazzo , C. William Gear , Carmeline J. Dsilva , Neta Rabin , Ioannis G. Kevrekidis

We study quasi-stationary distributions and quasi-limiting behavior of Markov chains in general reducible state spaces with absorption. We propose a set of assumptions dealing with particular situations where the state space can be…

Probability · Mathematics 2026-01-14 Nicolas Champagnat , Denis Villemonais

The reversible reactions A+A<=>C and A+B<=>C are investigated. From the exact Langevin equations describing our model, we set up a systematic approximation scheme to compute the approach of the density of C particles to its equilibrium…

Statistical Mechanics · Physics 2009-10-31 Pierre-Antoine Rey , John Cardy

In this work, we explore the dynamics of active entangled chains using molecular dynamics simulations of a modified Kremer-Grest model. The active chains are diluted in a mesh of very long passive linear chains, to avoid constraint release…

Soft Condensed Matter · Physics 2022-11-01 Andres R. Tejedor , Raquel Carracedo , Jorge Ramírez

Based on the wormlike chain model, a coarse-grained description of the nonlinear dynamics of a weakly bending semiflexible polymer is developed. By means of a multiple scale perturbation analysis, a length-scale separation inherent to the…

Soft Condensed Matter · Physics 2007-12-04 Oskar Hallatschek , Erwin Frey , Klaus Kroy

In this paper, we examine how to build coarse-grain transport models consistently from the kinetic to fluid regimes. The internal energy of the gas particles is described through a state-to-state approach. A kinetic equation allows us to…

Fluid Dynamics · Physics 2021-03-15 Erik Torres , Georgios Bellas-Chatzigeorgis , Thierry E. Magin

We introduce the notion of order of magnitude reversibility (OM-reversibility) in Markov chains that are parametrized by a positive parameter $\ep$. OM-reversibility is a weaker condition than reversibility, and requires only the knowledge…

Probability · Mathematics 2011-10-26 Badal Joshi

Motivated by the study of reversal behaviour of myxobacteria, in this article we are interested in a kinetic model for reversal dynamics, in which particles with directions close to be opposite undergo binary collision resulting in…

Analysis of PDEs · Mathematics 2023-05-22 Amic Frouvelle , Laura Kanzler , Christian Schmeiser

We study reversible polymerization of rings. In this stochastic process, two monomers bond and as a consequence, two disjoint rings may merge into a compound ring, or, a single ring may split into two fragment rings. This…

Statistical Mechanics · Physics 2011-06-03 E. Ben-Naim , P. L. Krapivsky

We analyse the dynamics of metastable Markovian open quantum systems by unravelling their average dynamics into stochastic trajectories. We use quantum reset processes as examples to illustrate metastable phenomenology, including a simple…

Quantum Physics · Physics 2024-04-08 Calum A. Brown , Katarzyna Macieszczak , Robert L. Jack

We propose a Bayesian nonparametric mixture model for the reconstruction and prediction from observed time series data, of discretized stochastic dynamical systems, based on Markov Chain Monte Carlo methods (MCMC). Our results can be used…

Applications · Statistics 2017-10-03 Christos Merkatas , Konstantinos Kaloudis , Spyridon J. Hatjispyros

Constrained molecular dynamics(CoMD) model, previously introduced for nuclear dynamics, has been extended to the atomic structure and collision calculations. Quantum effects corresponding to the Pauli and Heisenberg principle are enforced…

Atomic Physics · Physics 2007-05-23 Sachie Kimura , Aldo Bonasera

We study an one{dimensional quasilinear system proposed by J. Tello and M. Winkler [19] which models the population dynamics of two competing species attracted by the same chemical. The kinetics terms of the interacting species are chosen…

Analysis of PDEs · Mathematics 2016-11-25 Jia Hu , Qi Wang , Jingyue Yang , Lu Zhang

The competition between reptation and Rouse Dynamics is incorporated in the Rubinstein-Duke model for polymer motion by extending it with sideways motions, which cross barriers and create or annihilate hernias. Using the Density-Matrix…

Statistical Mechanics · Physics 2009-11-13 Andrzej Drzewinski , J. M. J. van Leeuwen