Related papers: Topological extension of the isomorph theory based…
This paper is the fourth in a series devoted to identifying and explaining the properties of strongly correlating liquids, i.e., liquids where virial and potential energy correlate better than 90% in their thermal equilibrium fluctuations…
Voronoi tessellations of scale-invariant fractal sets are characterized by topological and metrical properties that are significantly different from those of natural cellular structures. As an example we analyze Voronoi diagrams of…
A fluid particle changes its dynamics from diffusive to oscillatory as the system density increases up to the melting density. Hence, the notion of the Frenkel line was introduced to demarcate the fluid region into rigid and nonrigid liquid…
Isomorphs are curves in the thermodynamic phase diagram of invariant excess entropy, structure, and dynamics, while pseudoisomorphs are curves of invariant structure and dynamics, but not of the excess entropy. The latter curves have been…
A calculation of the transverse sound velocity as a function of excess entropy is presented for several simple fluids, including the Lennard-Jones, Yukawa, one-component plasma, inverse-power law (soft sphere) and hard sphere models. A…
In this paper, we mainly revisit a nice theory for topological entropy of weakly equivalent flows, which was originally investigated by Ohno in 1980. We will develop a new approach, being more straightforward and elementary than the…
The previous paper [Veldhorst et al., J. Chem. Phys. 141, 054904 (2014)] demonstrated that the isomorph theory explains the scaling properties of a liquid of flexible chains consisting of ten Lennard-Jones particles connected by rigid…
Computer simulations show that liquids of molecules with harmonic intramolecular bonds may have "pseudoisomorphic" lines of approximately invariant dynamics in the thermodynamic phase diagram. We demonstrate that these lines can be…
We study nontrivial entropy invariants in the class of parabolic flows on homogeneous spaces, quasi-unipotent flows. We show that topological complexity (ie, slow entropy) can be computed directly from the Jordan block structure of the…
The isomorph theory provides an explanation for the so-called power law density scaling which has been observed in many molecular and polymeric glass formers, both experimentally and in simulations. Power law density scaling (relaxation…
Compressing or cooling a fluid typically enhances its static interparticle correlations. However, there are notable exceptions. Isothermal compression can reduce the translational order of fluids that exhibit anomalous waterlike trends in…
We consider equilibrium statistics for high Reynolds number isotropic turbulence in an incompressible flow driven by steady forcing at the largest scale. Motivated by shell model observations, we develop a similarity theory for the inertial…
The statistical-mechanical study of the equilibrium properties of fluids, starting from the knowledge of the interparticle interaction potential, is essential to understand the role that microscopic interaction between individual particles…
This paper generalizes isomorph theory to systems that are not in thermal equilibrium. The systems are assumed to be R-simple, i.e., have a potential energy that as a function of all particle coordinates $\textbf{R}$ obeys the…
A thermodynamic framework for asymptotic inference is developed in which sample size and parameter variance define a state space. Within this description, Shannon information plays the role of entropy, and an integrating factor organizes…
In this paper, we investigate the asymptotic stability of finite-dimensional stochastic integrable Hamiltonian systems via information entropy. Specifically, we establish the asymptotic vanishing of Shannon entropy difference (with…
We propose a unified scaling theory of entanglement entropy in the confinements of finite bond dimensions, dynamics and system sizes. Within the theory, the finite-entanglement scaling introduced recently is generalized to the dynamics…
Measure-theoretic and topological entropy are classical invariants in the theory of dynamical systems. There are several recently developed entropy type invariants for systems of sub-exponential growth: sequence entropy, slow entropy,…
Entropy is a quantity for counting physical degrees of freedom in a system. At a finite temperature, one can use thermal entropy to study thermodynamical properties. At zero temperature, entanglement entropy is expected to provide a…
Entropy is critically examined as a fundamental concept in contemporary science and informatics. Although the typical Shannon entropy provides a proper framework for describing the canonical ensemble, it fails to represent adequately the…